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PTHH: \(Mg+H_2SO_4\rightarrow MgSO_4+H_2\uparrow\)
a_______a________a______a (mol)
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)
b_______\(\dfrac{3}{2}\)b_________\(\dfrac{1}{2}\)b_____\(\dfrac{3}{2}\)b (mol)
a) Ta lập HPT: \(\left\{{}\begin{matrix}24a+27b=8,25\\a+\dfrac{3}{2}b=\dfrac{2,24}{22,4}=0,1\end{matrix}\right.\) \(\Leftrightarrow\) Hệ có nghiệm âm
*Bạn xem lại đề !!!
a, \(Mg+H_2SO_4\rightarrow MgSO_4+H_2\)
\(MgO+H_2SO_4\rightarrow MgSO_4+H_2O\)
b, \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
Theo PT: \(n_{Mg}=n_{H_2}=0,1\left(mol\right)\Rightarrow m_{Mg}=0,1.24=2,4\left(g\right)\)
\(\Rightarrow m_{MgO}=4,4-2,4=2\left(g\right)\)
c, \(n_{MgO}=\dfrac{2}{40}=0,05\left(mol\right)\)
Theo PT: \(n_{H_2SO_4}=n_{Mg}+n_{MgO}=0,15\left(mol\right)\)
\(\Rightarrow m_{H_2SO_4}=0,15.98=14,7\left(g\right)\)
\(\Rightarrow m_{ddH_2SO_4}=\dfrac{14,7}{19,6\%}=75\left(g\right)\)
\(n_{H2}=\dfrac{0,672}{22,4}=0,03\left(mol\right)\)
Pt : \(Mg+2HCl\rightarrow MgCl_2+H_2|\)
1 2 1 1
0,03 0,06 0,03 0,03
\(MgO+2HCl\rightarrow MgCl_2+H_2O|\)
1 2 1 1
0,03 0,06 0,03
a) \(n_{Mg}=\dfrac{0,03.1}{1}=0,03\left(mol\right)\)
\(m_{Mg}=0,03.24=0,72\left(g\right)\)
\(m_{MgO}=1,92-0,72=1,2\left(g\right)\)
b) Có : \(m_{MgO}=1,2\left(g\right)\)
\(n_{MgO}=\dfrac{1,12}{40}=0,03\left(mol\right)\)
\(n_{HCl\left(tổng\right)}=0,06+0,06=0,12\left(mol\right)\)
400ml = 0,4l
\(C_{M_{ddHCl}}=\dfrac{0,12}{0,4}=0,3\left(l\right)\)
c) \(n_{MgCl2\left(tổng\right)}=0,03+0,03=0,06\left(mol\right)\)
\(C_{M_{MgCl2}}=\dfrac{0,06}{0,4}=0,15\left(M\right)\)
Chúc bạn học tốt
a,\(n_{H_2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)
PTHH: Mg + 2HCl → MgCl2 + H2
Mol: 0,05 0,1 0,05 0,05
PTHH: MgO + 2HCl → MgCl2 + H2O
Mol: 0,1 0,2 0,1
⇒ mMg = 0,05.24 = 1,2 (g)
mMgO = 5,2 - 1,2 = 4 (g)
b,\(n_{MgO}=\dfrac{4}{40}=0,1\left(mol\right)\)
⇒ nHCl đã dùng = 0,1+0,2 = 0,3 (mol)
\(C_{M_{ddHCl}}=\dfrac{0,3}{0,5}=0,6\left(l\right)\)
c,\(C_{M_{MgCl_2}}=\dfrac{0,05+0,1}{0,6}=0,25M\)
\(n_{Na_2CO_3}=\dfrac{360.21,2\%}{100\%.106}=0,72(mol)\\ n_{H_2SO_4}=2,5.0,2=0,5(mol)\\ PTHH:Na_2CO_3+H_2SO_4\to Na_2SO_4+H_2O+CO_2\uparrow\\ a,\text {Vì }\dfrac{n_{Na_2CO_3}}{1}>\dfrac{n_{H_2SO_4}}{1} \text {nên }Na_2CO_3\text { dư}\\ \Rightarrow n_{CO_2}=n_{H_2SO_4}=0,5(mol)\\ \Rightarrow V_{CO_2}=0,5.22,4=11,2(l)\\\)
\(b,A:Na_2SO_4\\ n_{Na_2SO_4}=n_{H_2SO_4}=0,5(mol)\\ m_{dd_{H_2SO_4}}=200.1,1=220(g);V_{dd_{Na_2CO_3}}=\dfrac{360}{1,2}=300(ml)=0,3(l)\\ \Rightarrow C\%_{Na_2SO_4}=\dfrac{0,5.142}{360+200-0,5.44}.100\%=13,2\%\\ C_{M_{Na_2SO_4}}=\dfrac{0,5}{0,3+0,2}=1M\)
Mg + H2SO4 \(\rightarrow\) MgSO4 + H2
x x x x
MgO + H2SO4 \(\rightarrow\) MgSO4 + H2O
y y y y
a, m hỗn hợp=4g \(\Rightarrow24x+40y=4\) (1)
n H2 = 2,24:22,4=0,1(mol)\(\Rightarrow\) x=0,1
\(\Rightarrow\)y=0,04
m Mg = 0,1x24=2,4(g)
%m Mg = 2,4 : 4 x 100% = 60%
%m MgO = 100% - 60% = 40%
b, n H2SO4 = x+y=0,1 + 0,04 =0,14(mol)
m H2SO4=0,14x98=13,72(g)
mdd H2SO4= 13,72x100:20=68,6(g)
Vdd H2SO4 = 68,6:1,2=57,2(ml)=0,0572(l)
n MgSO4 = x+y=0,1 + 0,04 = 0,14(mol)
Cm MgSO4 = 0,14 : 0,0572 = 2,45(M)
m MgSO4 = 0,14 x 120 = 16,8 (g)
mdd thu đc sau pư
= m hỗn hợp + mdd H2SO4 - m H2
= 4 + 68,6 - 0,1x2
= 72,4(g)
C% MgSO4 = 16,8 : 72,4 x 100% = 23,2%