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a, \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
b, \(n_{Br_2}=\dfrac{16}{160}=0,1\left(mol\right)\)
\(n_{C_2H_4}=n_{Br_2}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,1.22,4}{3,36}.100\%\approx66,67\%\\\%V_{CH_4}\approx33,33\%\end{matrix}\right.\)
\(n_{Br_2}=\dfrac{8}{160}=0.05\left(mol\right)\)
\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
\(0.05......0.05\)
\(V_{C_2H_4}=0.05\cdot22.4=1.12\left(l\right)\)
\(V_{CH_4}=20-1.12=18.88\left(l\right)\left(mol\right)\)
\(\%V_{C_2H_4}=\dfrac{1.12}{20}\cdot100\%=5.6\%\)
\(\%V_{CH_4}=100-5.6=94.4\%\)
a, Ta có: \(n_{CH_4}+n_{C_2H_4}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\left(1\right)\)
\(16n_{CH_4}+28n_{C_2H_4}=3\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{CH_4}=0,1\left(mol\right)\\n_{C_2H_4}=0,05\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{CH_4}=\dfrac{0,1.16}{3}.100\%\approx53,33\%\\\%m_{C_2H_4}\approx46,67\%\end{matrix}\right.\)
- Ở cùng điều kiện nhiệt độ và áp suất, % số mol cũng là %V.
\(\Rightarrow\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,1}{0,15}.100\%\approx66,67\%\\\%V_{C_2H_4}\approx33,33\%\end{matrix}\right.\)
b, PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
Có: m tăng = mC2H4 = 0,05.28 = 1,4 (g)
a) \(n_{hh}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
Gọi \(\left\{{}\begin{matrix}n_{CH_4}=a\left(mol\right)\\n_{C_2H_4}=b\left(mol\right)\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}a+b=0,15\\16a+28b=3\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,05\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,1}{0,15}.100\%=66,67\%\\\%V_{C_2H_4}=100\%-66,67\%=33,33\%\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{CH_4}=\dfrac{0,1.16}{3}.100\%=53,33\%\\\%m_{C_2H_4}=100\%-53,33\%=46,67\%\end{matrix}\right.\)
b) \(m=m_{C_2H_4}=0,05.28=1,4\left(g\right)\)
mtăng = mC2H4 = 2,8 (g)
=> \(n_{C_2H_4}=\dfrac{2,8}{28}=0,1\left(mol\right)\)
=> VC2H4 = 0,1.22,4 = 2,24 (l)
=> VCH4 = 4,48 - 2,24 = 2,24 (l)
a.\(m_{tăng}=m_{C_2H_4}=2,8g\)
\(V_{khí.thoát.ra}=V_{CH_4}+V_{CO_2}\)
\(n_{C_2H_4}=\dfrac{2,8}{28}=0,1mol\)
\(C_2H_4+3O_2\rightarrow\left(t^o\right)2CO_2+2H_2O\)
0,1 0,2 ( mol )
\(m_{H_2O\left(thu.được\right)}=0,2.18=3,6g\)
\(\Rightarrow m_{H_2O\left(pứCH_4\right)}=7,2-3,6=3,6g\)
\(n_{H_2O}=\dfrac{3,6}{18}=0,2mol\)
\(CH_4+2O_2\rightarrow\left(t^o\right)CO_2+2H_2O\)
0,1 0,2 ( mol )
\(\Rightarrow V_{CH_4}=0,1.22,4=2,24l\)
\(\Rightarrow V_{CO_2}=3,36-2,24=1,12l\)
\(\Rightarrow V_{C_2H_4}=0,1.22,4=2,24l\)
\(\rightarrow\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{2,24}{2,24+1,12+2,24}.100=40\%\\\%V_{CO_2}=\dfrac{1,12}{2,24+1,12+2,24}.100=20\%\\\%V_{C_2H_4}=100\%-40\%-20\%=40\%\end{matrix}\right.\)
b.\(\rightarrow\left\{{}\begin{matrix}m_{CH_4}=0,1.16=1,6g\\m_{CO_2}=0,05.44=2,2g\\m_{C_2H_4}=0,1.28=2,8g\end{matrix}\right.\)
\(\Rightarrow m_{hh}=1,6+2,2+2,8=6,6g\)
c.\(m_{PE}=28.n_{C_2H_4}.H\%=28.0,1.80\%=2,24g\)
\(a,Gọi\left\{{}\begin{matrix}n_{CH_4}=a\left(mol\right)\\n_{C_2H_4}=b\left(mol\right)\\n_{C_2H_2}=c\left(mol\right)\end{matrix}\right.\\ n_{hhkhí}=0,4\left(mol\right)\\ n_{CO_2}=\dfrac{15,68}{22,4}=0,7\left(mol\right)\\ n_{Br_2}=\dfrac{64}{160}=0,4\left(mol\right)\\ PTHH:C_2H_4+Br_2\rightarrow C_2H_4Br_2\\ Mol:a\rightarrow a\\ C_2H_2+2Br_2\rightarrow C_2H_2Br_4\\ Mol:b\rightarrow2b\\ CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\\ Mol:a\rightarrow2a\rightarrow a\)
\(C_2H_4+3O_2\underrightarrow{t^o}2CO_2+2H_2O\\ Mol:b\rightarrow3b\rightarrow2b\\ 2C_2H_2+5O_2\underrightarrow{t^o}4CO_2+2H_2O\\ Mol:c\rightarrow2,5c\rightarrow2c\\ Hệ.pt\left\{{}\begin{matrix}a+b+c=0,4\\b+2c=0,4\\a+2b+2c=0,7\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,1\left(mol\right)\\b=0,2\left(mol\right)\\c=0,1\left(mol\right)\end{matrix}\right.\)
\(\%V_{CH_4}=\%V_{C_2H_2}=\dfrac{0,1}{0,4}=25\%\\ \%V_{C_2H_4}=\dfrac{0,2}{0,4}=50\%\)
\(m_{CH_4}=0,1.16=1,6\left(g\right)\\ m_{C_2H_4}=28.0,2=5,6\left(g\right)\\ m_{C_2H_2}=0,1.26=2,6\left(g\right)\\ \%m_{CH_4}=\dfrac{1,6}{1,6+5,6+2,6}=16,32\%\\ \%m_{C_2H_4}=\dfrac{5,6}{1,6+5,6+2,6}=57,14\%\\ \%m_{C_2H_2}=100\%-16,32\%-57,14\%=26,54\%\)
\(b,PTHH:C_2H_5OH\rightarrow C_2H_4+H_2O\\ Mol:0,2\leftarrow0,2\\ m_{C_2H_5OH}=0,2.46=9,2\left(g\right)\)
Dài quá!!!
CH4+2O2-to>CO2+2H2O
x-----------------------------2x
C2H2+\(\dfrac{5}{2}\)O2-to>2CO2+H2O
y-----------------------------------y
=>\(\left\{{}\begin{matrix}x+y=\dfrac{3,36}{22,4}\\2x+y=\dfrac{4,5}{18}\end{matrix}\right.\)
=>\(\left\{{}\begin{matrix}x=0,1\\y=0,05\end{matrix}\right.\)
=>%VCH4=\(\dfrac{0,1.22,4}{3,36}\).100=66,67%
=>%VC2H2=100-66,67%=33,33%
b)
C2H2+2Br2->C2H2Br4
0,05-----0,1 mol
=>m Br2=0,1.160=16g
1.
Al4C3 + 12H2O -> 4Al(OH)3 + 3CH4
khối lượng Al4C3 thực là 14,4 - 30%.14,4 = 10,08(g)
nAl4C3 = 0,07 (mol) -> nCH4 = 0,21 (mol)
-> VCH4 = 0,21 . 22,4 = 4,704 (l)
2. Gọi x, y lần lượt là số mol của C2H2 và C2H4 trong 5,6 lít hỗn hợp.
C2H2 + 2Br2 → C2H2Br4
x
C2H4 + Br2 → C2H2Br2
y
Ta có: x + y = 5,6/22,4 = 0,25
dd Br2 nặng thêm = mC2H2 + mC2H2 = 26x + 28y = 6,8
-> x = 0,1 mol; y = 0,15 mol
Vậy: VC2H2 = 0,1.22,4 = 2,24 (l)
VC2H2 = 0,15. 22,4 = 3,36 (l)
Ta có: m dd Br2 tăng = mC2H4 = 2,8 (g)
\(\Rightarrow n_{C_2H_4}=\dfrac{2,8}{28}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,1.22,4}{3,36}.100\%\approx66,67\%\\\%V_{CH_4}\approx33,33\%\end{matrix}\right.\)
Có: \(n_{CH_4}=\dfrac{3,36}{22,4}-0,1=0,05\left(mol\right)\)
⇒ m hh = mCH4 + mC2H4 = 0,05.16 + 0,1.28 = 3,6 (g)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{CH_4}=\dfrac{0,05.16}{3,6}.100\%\approx22,22\%\\\%m_{C_2H_4}\approx77,78\%\end{matrix}\right.\)