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Pt: Ba+2H2O -> Ba(OH)2+H2 (1)
Ba(OH)2+CuSO4 ->Cu(OH)2 \(\downarrow\) +BaSO4 \(\downarrow\)(2)
Ba(OH)2+(NH4)2SO4 ->BaSO4 \(\downarrow\)+2NH3+2H2O (3)
Cu(OH)2\(\underrightarrow{t^0}\)CuO+H2O (4)
BaSO4 \(\underrightarrow{t^0}\) ko xảy ra phản ứng
Theo (1) ta có \(n_{H_2}=n_{Ba\left(OH\right)_2}=n_{Ba}=\frac{27,4}{137}=0,2\left(mol\right)\)
\(n_{\left(NH_4\right)_2SO_4}=\frac{1,32\cdot500}{132\cdot100}=0,05\left(mol\right)\)
\(n_{CuSO_4}=\frac{2\cdot500}{100\cdot160}=0,0625\left(mol\right)\)
Ta thấy: \(n_{Ba\left(OH\right)_2}>n_{\left(NH_4\right)_2SO_4}+n_{CuSO4\:}\) nên Ba(OH)2 dư và 2 muối đều phản ứng hết
Theo (2) ta có: \(n_{Ba\left(OH\right)_2}=n_{Cu\left(OH\right)_2}=n_{BaSO_4}=n_{CuSO_4}=0,0625\left(mol\right)\)
Theo (3) ta có: \(n_{Ba\left(OH\right)_2}=n_{BaSO_4}=n_{\left(NH_4\right)_2SO_4}=0,05\left(mol\right)\)
và \(n_{NH_3}=2n_{\left(NH_4\right)_2SO_4}=0,05\cdot2=0,1\left(mol\right)\)
\(\Rightarrow n_{Ba\left(OH_2\right)}\text{dư}=0,2-\left(0,05+0,0625\right)=0,0875\left(mol\right)\)
a)\(V_{A\left(ĐKTC\right)}=V_{H_2}+V_{NH_3}=\left(0,2+0,1\right)\cdot22,4=6,72\left(l\right)\)
b)Theo (4) ta có: \(n_{CuO}=n_{Cu\left(OH\right)_2}=0,0625\left(mol\right)\)
\(m_{\text{chất rắn}}=m_{BaSO_4}+m_{CuO}=\left(0,0625+0,05\right)\cdot233+0,0625\cdot80=31,2125\left(g\right)\)
mCuSO4= 12,8(g) ->nCuSO4=0,2(mol)
nNa=0,04(mol)
pthh: Na + H2O -> NaOH + 1/2 H2
-> nNaOH= 0,04(mol); nH2=0,02(mol)
=> V(A,đktc)=V(H2,đktc)=0,02.22,4=0,448(l)
2 NaOH + CuSO4 -> Cu(OH)2 + Na2SO4
Ta có: 0,04/2 < 0,2/1
=> CuSO4 dư, NaOH hết, tính theo nNaOH
=> nCu(OH)2=nCuSO4(p.ứ)=nNa2SO4=nNaOH/2=0,02(mol)
=> m(B)=mCu(OH)2=0,02.98=1,96(g)
b) mddC=mddCuSO4 + mNaOH - mCu(OH)2= 400+ 0,04.40- 1,96= 399,64(g)
mCuSO4(dư)= 0,18 x 160=28,8(g)
mNa2SO4=0,02.142= 2,84(g)
=> C%ddCuSO4(dư)= (28,8/399,64).100=7,206%
C%ddNa2SO4=(2,84/399,64).100=0,711%
a/
\(n_{Na_2O}=\dfrac{9,3}{62}=0,15\left(mol\right)\)
\(Na_2O+H_2O\rightarrow2NaOH\)
0,15 0,3 (mol)
\(m_{NaOH}=0,3.40=12\left(g\right)\)
\(m_A=90,7+9,3=100\left(g\right)\)
\(C\%_{NaOH}=\dfrac{12}{100}.100\%=12\%\)
b/
m\(_{FeSO_4}=\dfrac{16.200}{100}=32\left(g\right)\)
\(\rightarrow m_{FeSO_4}=\dfrac{32}{152}=\dfrac{4}{19}\left(mol\right)\)
\(2NaOH+FeSO_4\rightarrow Na_2SO_4+Fe\left(OH\right)_2\downarrow\)
bđ: 0,3 \(\dfrac{4}{19}\) 0 0 (mol)
pư: 0,3 0,15 0,15 0,15 (mol)
dư: 0 \(\dfrac{23}{380}\) (mol)
\(m_{Fe\left(OH\right)_2}=0,15.90=13,5\left(g\right)\)
\(m_C=100+200-13,5=286,5\left(g\right)\)
\(m_{Na_2SO_4}=0,15.142=21,3\left(g\right)\)
\(\rightarrow C\%_{Na_2SO_4}=\dfrac{21,3}{286,5}.100\%\approx7,4\%\)
\(m_{FeSO_4\left(dư\right)}=\dfrac{23}{380}.152=9,2\left(g\right)\)
\(\rightarrow C\%_{FeSO_4\left(dư\right)}=\dfrac{9,2}{286,5}.100\%\approx3,2\%\)
nNa = 6.9 : 23 = 0.3 mol
4Na + O2 ->2 Na2O
mol : 0.3 -> 0.15
Na2O + H2O -> 2NaOH
mol : 0.15 -> 0.3
mdd = 0.15 x 62 + 140.7 = 150g
C% NaOH = 0.3x40: 150 x 100% = 8%
nCuSO4=0,5.0,4=0,2 mol
CuSO4 +2NaOH=> Cu(OH)2+Na2SO4
0,2 mol =>0,2 mol
Cu(OH)2=> CuO+H2O
0,2 mol =>0,2 mol
kết tủa A là Cu(OH)2 m=98.0,2=19,6g
cr B là CuO m=0,2.80=16g
a)
CTHH: FexOy
\(n_{Fe_xO_y}=\dfrac{16}{56x+16y}\left(mol\right)\)
PTHH: FexOy + yCO --to--> xFe + yCO2
\(\dfrac{16}{56x+16y}\)--------->\(\dfrac{16x}{56x+16y}\)
=> \(\dfrac{16x}{56x+16y}.56=16-4,8=11,2\)
=> \(\dfrac{x}{y}=\dfrac{2}{3}\Rightarrow Fe_2O_3\)
\(n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\)
PTHH: Fe2O3 + 3CO --to--> 2Fe + 3CO2
0,1------>0,3--------------->0,3
Ca(OH)2 + CO2 --> CaCO3 + H2O
0,3----->0,3
=> \(m_{CaCO_3}=0,3.100=30\left(g\right)\)
b) nCO (thực tế) = 0,3.110% = 0,33(mol)
=> VCO = 0,33.22,4 = 7,392(l)
