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theo bài ra ta có :
mCuO = 20g => nCuO = 0,25mol
mHCl = 18,25 g => nHCl = 0,5mol
pthh:
CuO + 2HCl -> CuCl2 + H2O
1mol.....2mol.......1mol.......1mol
0,25mol..0,5mol...0,25mol....0,25mol
theo pt ta có nCuO = \(\dfrac{1}{2}\)nHCl = nCuCl2 = nH2O = 0,25mol
=> mCuCl2 = nCuCl2 . MCuCl2 = 0,25 . 135 = 33,75 g
=> mH2O = nH2O . MH2O = 0,25.18 = 4,5 g
Ta có: nCuO = m / M = 20/ (64+16) = 20/80=0,25 (mol)
CuO → Cu →O
⇔ 0,25 → 0,25 →0,25 (mol)
=> mCu = 0,25 * 64 =16 (g)
mO = 0,25 * 16 = 4 (g)
Tương tự ta có : nHCl = 18,25 / 36,5 =0,5(mol)
HCl → H → Cl
<=>0,5 → 0,5 → 0,5 (mol)
=>mH =0,5 * 1=0,5(g)
mCl = 0,5 *35,5 =17,75 (g)
\(n_{Ca}=\dfrac{8}{40}=0,2mol\\ 2Ca+O_2\xrightarrow[]{t^0}2CaO\\ n_{CaO}=n_{Ca}=0,2mol\\ n_{HCl}=\dfrac{18,25}{36,5}=0,5mol\\ CaO+2HCl\rightarrow CaCl_2+H_2O\\ \Rightarrow\dfrac{0,2}{1}< \dfrac{0,5}{2}\Rightarrow HCl.dư\\ n_{CaCl_2}=n_{CaO}=0,2mol\\ n_{HCl}=2n_{CaO}=0,4mol\\ m_{CaCl_2}=0,2.111=22,2g\\ m_{HCl.dư}=\left(0,5-0,4\right).36,5=3,65g\)
\(n_{CuO}=\frac{20}{80}=0,25\left(mol\right)\)
\(n_{HCl}=\frac{36,5}{36,5}=0,1\left(mol\right)\)
\(PTHH:CuO+2HCl\rightarrow CuCl_2+H_2O\)
Ban đầu: 0,25_____0,1
Phản ứng: 0,05____0,1_____0,05___________(mol)
Dư:_____0,2
Lập tỉ lệ: \(\frac{0,25}{1}>\frac{0,1}{2}\left(0,25>0,05\right)\)
\(m_{CuCl_2}=0,05.135=6,75\left(g\right)\)
\(m_{H_2O}=0,05.18=0,9\left(g\right)\)
Lượng dư HCl nữa em
36,5/36,5 sao ra 0,1 hay dị em?
\(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\\ n_{HCl}=\dfrac{109,5.20\%}{36,5}=0,6\left(mol\right)\\ PTHH:Zn+2HCl\rightarrow ZnCl_2+H_2\\ Vì:\dfrac{0,2}{1}< \dfrac{0,6}{2}\Rightarrow HCldư\\ n_{H_2}=n_{ZnCl_2}=n_{Zn}=0,2\left(mol\right)\\ n_{HCl\left(dư\right)}=0,6-0,2.2=0,2\left(mol\right)\\ a,V_{H_2\left(đktc\right)}=0,2.22,4=4,48\left(l\right)\\ b,m_{ZnCl_2}=136.0,2=27,2\left(g\right)\\ c,m_{ddsau}=13+109,5-0,2.2=122,1\left(g\right)\\ C\%_{ddZnCl_2}=\dfrac{27,2}{122,1}.100\approx22,277\%\\ C\%_{ddHCl\left(dư\right)}=\dfrac{0,2.36,5}{122,1}.100\approx5,979\%\)
Zn + 2HCl -> ZnCl2 + H2
a, nZn = 13/65= 0,2(mol)
mHCl= 109,5.20%/100%=21.9(g)
nHCl=21,9/36,5=0,6(mol)
Theo PT nHCl = 2nZn= 2.0,2= 0,4(mol)<0,6(mol)
=> HCl pư dư, Zn pư hết
Theo PT: nH2= nZn =0,2(mol)
VH2=0,2.22,4=4,48(l)
b, Theo PT: nZnCl2=nZn=0,2(mol)
mZnCl2= 0,2.136=27,2(g)
c, mdd sau pư= 13+109,5-0,2.2=122,1(g)
C%dd ZnCl2=27,2.100%/122,1=22,28%
nHCl dư= 0,6-0,4=0,2(mol)
mHcl
\(n_{Zn}=\dfrac{8,125}{65}=0,125\left(mol\right)\\ m_{HCl}=\dfrac{100.18,25}{100}=18,25\left(g\right)\\
n_{HCl}=\dfrac{18,25}{36,5}=0,5\\ pthh:Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
0,125 0,125 (mol )
\(\Rightarrow V_{H_2}=0,125.22,4=2,8\left(l\right)\\
\)
\(C\%=\dfrac{8,125}{8,125+18,25}.100\%=30,8\%\)
Bài 18:
Ta có: \(n_{Zn}=\dfrac{8,125}{65}=0,125\left(mol\right)\)
\(m_{HCl}=100.18,25\%=18,25\left(g\right)\Rightarrow n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\)
a, PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
b, Xét tỉ lệ: \(\dfrac{0,125}{1}< \dfrac{0,5}{2}\), ta được HCl dư.
Theo PT: \(n_{H_2}=n_{Zn}=0,125\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,125.22,4=2,8\left(g\right)\)
\(m_{H_2}=0,125.2=0,25\left(g\right)\)
c, Theo PT: \(\left\{{}\begin{matrix}n_{ZnCl_2}=n_{Zn}=0,125\left(mol\right)\\n_{HCl\left(pư\right)}=2n_{Zn}=0,25\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{HCl\left(dư\right)}=0,25\left(mol\right)\)
Có: m dd sau pư = 8,125 + 100 - 0,25 = 107,875 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{ZnCl_2}=\dfrac{0,125.136}{107,875}.100\%\approx15,76\%\\C\%_{HCl\left(dư\right)}=\dfrac{0,25.36,5}{107,875}.100\%\approx8,46\%\end{matrix}\right.\)
Bạn tham khảo nhé!
\(a.Zn+2HCl\rightarrow ZnCl_2+H_2\\ n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right);n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\\ LTL:\dfrac{0,2}{1}< \dfrac{0,5}{2}\Rightarrow HCldư\\ n_{HCl\left(pứ\right)}=2n_{Zn}=0,4\left(mol\right)\\\Rightarrow m_{HCl\left(dư\right)}=\left(0,5-0,4\right).36,5=3,65\left(g\right)\\ b.n_{ZnCl_2}=n_{Zn}=0,2\left(mol\right)\\ \Rightarrow m_{ZnCl_2}=0,2.136=27,2\left(g\right)\\ c.n_{H_2}=n_{Zn}=0,2\left(mol\right)\\ \Rightarrow V_{H_2}=0,2.22,4,=4,48\left(l\right)\\ d.3H_2+Fe_2O_3-^{t^o}\rightarrow2Fe+3H_2O \\ n_{Fe_2O_3}=\dfrac{19,2}{160}=0,12\left(mol\right)\\ LTL:\dfrac{0,2}{3}< \dfrac{0,12}{1}\Rightarrow Fe_2O_3dưsauphảnứng\\ \Rightarrow n_{Fe}=\dfrac{2}{3}n_{H_2}=\dfrac{2}{15}\left(mol\right)\\ \Rightarrow m_{Fe}=\dfrac{2}{15}.56=7,467\left(g\right)\)
a) n\(Zn\)=\(\dfrac{m}{M}\)=\(\dfrac{13}{65}\)=0,2(mol)
n\(HCl\)=\(\dfrac{m}{M}\)=\(\dfrac{18,25}{36,5}=\)0,5(mol)
PTHH : Zn + 2HCl->ZnCl\(2\) + H\(2\)
0,2 0,5
Lập tỉ lệ mol : \(^{\dfrac{0,2}{1}}\)<\(\dfrac{0,5}{2}\)
n\(Zn\) hết , n\(HCl\) dư
-->Tính theo số mol hết
Zn + 2HCl->ZnCl\(2\) + H\(2\)
0,2 -> 0,4 0,2 0,2
n\(HCl\) dư= n\(HCl\)(đề) - n\(HCl\)(pt)= 0,5 - 0,4 = 0,1(mol)
m\(HCl\) dư= 0,1.36,5 = 3,65(g)
b) m\(ZnCl2\) = n.M= 0,2.136= 27,2 (g)
c)V\(H2\)=n.22,4=0,2.22,4=4,48(l)
d) n\(Fe\)\(2\)O\(3\)=\(\dfrac{m}{M}\)=\(\dfrac{19,2}{160}\)=0,12 (mol)
3H2 +Fe2O3 → 2Fe + 3H2O
0,2 0,12
Lập tỉ lệ mol: \(\dfrac{0,2}{3}\)<\(\dfrac{0,12}{1}\)
nH2 hết .Tính theo số mol hết
\(HCl\)
3H2 +Fe2O3 → 2Fe + 3H2O
0,2-> 0,2
m\(Fe\)=n.M= 0,2.56= 11,2(g)
\(n_{Zn}=\dfrac{19,5}{65}=0,3\left(mol\right)\)
\(m_{HCl}=\dfrac{150.18,25}{100}=27,375\left(g\right)\)
\(n_{HCl}=\dfrac{27,375}{36,5}=0,75\left(mol\right)\)
PTHH :
\(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
trc p/u : 0,3 0,75
p/u: 0,3 0,6 0,3 0,3
sau p/u : 0 0,15 0,3 0,3
---> Sau p/ư HCl dư
\(a,V_{H_2}=0,3.22,4=6,72\left(l\right)\)
\(b,m_{ddHCl}=0,6.36,5=21,9\left(g\right)\)
\(c,m_{ZnCl_2}=0,3.136=40,8\left(g\right)\)
\(m_{ddZnCl_2}=19,5+150-\left(0,3.2\right)=168,9\left(g\right)\)
\(C\%=\dfrac{40,8}{168,9}.100\%\approx24,16\%\)
Tk
2Ca + O2 -> 2CaO (1)
CaO + 2HCl -> CaCl2 + H2O (2)
nCa=0,4(mol)
nHCl=0,5(mol)
Từ 1:
nCaO=nCa=0,4(mol)
Vì 0,4>0,52=0,250,4>0,52=0,25 nên sau PƯ 2 thì CaO dư 0,15 mol
Từ 2:
nCaCl2=1212nHCl=0,25(mol)
mCaCl2=111.0,25=27,75(g)
mCaO=56.0,15=8,4(g)
\(PTHH:CuO+2HCl\rightarrow CuCl_2+H_2O\)
+ \(\dfrac{n_{CuO\left(bđ\right)}}{n_{CuO\left(PTHH\right)}}=\dfrac{0,25}{1}=0,25\)
+ \(\dfrac{n_{HCl\left(bđ\right)}}{n_{HCl\left(PTHH\right)}}=\dfrac{0,5}{2}=0,25\)
=> pư trên vừa đủ
=> \(m_{CuCl_2}=0,25.135=33,75g\)