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a, \(Na_2SO_3+H_2SO_4\rightarrow Na_2SO_4+SO_2+H_2O\)
\(K_2SO_3+H_2SO_4\rightarrow K_2SO_4+SO_2+H_2O\)
Ta có: \(n_{SO_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
Theo PT: \(n_{H_2SO_4}=n_{SO_2}=0,3\left(mol\right)\)
\(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,3.98}{20\%}=147\left(g\right)\)
b, Ta có: 126nNa2SO3 + 158nK2SO3 = 44,2 (1)
Theo PT: \(n_{SO_2}=n_{Na_2SO_3}+n_{K_2SO_3}=0,3\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{Na_2SO_3}=0,1\left(mol\right)\\n_{K_2SO_3}=0,2\left(mol\right)\end{matrix}\right.\)
Có: m dd sau pư = 44,2 + 147 - 0,3.64 = 172 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{Na_2SO_3}=\dfrac{0,1.126}{172}.100\%\approx7,33\%\\C\%_{K_2SO_3}=\dfrac{0,2.158}{172}.100\%\approx18,37\%\end{matrix}\right.\)
c, \(n_{Ba\left(OH\right)_2}=0,5.1=0,5\left(mol\right)\)
\(\Rightarrow\dfrac{n_{SO_2}}{n_{Ba\left(OH\right)_2}}=0,6< 1\) → Pư tạo BaSO3.
PT: \(SO_2+Ba\left(OH\right)_2\rightarrow BaSO_3+H_2O\)
\(n_{BaSO_3}=n_{SO_2}=0,3\left(mol\right)\Rightarrow m_{BaSO_3}=0,3.217=65,1\left(g\right)\)
a. PTHH: Zn + H2SO4 ---> ZnSO4 + H2↑
b. Ta có: \(C_{M_{H_2SO_4}}=\dfrac{n_{H_2SO_4}}{200:1000}=1,5M\)
=> \(n_{H_2SO_4}=0,3\left(mol\right)\)
Ta lại có: \(n_{Zn}=\dfrac{16,25}{65}=0,25\left(mol\right)\)
Ta thấy: \(\dfrac{0,3}{1}>\dfrac{0,25}{1}\)
Vậy H2SO4 dư.
Theo PT: \(n_{H_2}=n_{Zn}=0,25\left(mol\right)\)
=> \(V_{H_2}=0,25.22,4=5,6\left(lít\right)\)
c. Theo PT: \(n_{ZnSO_4}=n_{Zn}=0,25\left(mol\right)\)
=> \(m_{ZnSO_4}=0,25.161=40,25\left(g\right)\)
d. Ta có: \(V_{dd_{ZnSO_4}}=0,2\left(lít\right)\)
=> \(C_{M_{ZnSO_4}}=\dfrac{0,25}{0,2}=1,25M\)
Ta có: \(n_{Mg}=\dfrac{9,6}{24}=0,4\left(mol\right)\)
a. PTHH: Mg + H2SO4 ---> MgSO4 + H2↑
Theo PT: \(n_{H_2}=n_{Mg}=0,4\left(mol\right)\)
=> \(V_{H_2}=0,4.22,4=8,96\left(lít\right)\)
b. Theo PT: \(n_{H_2SO_4}=n_{Mg}=0,4\left(mol\right)\)
=> \(m_{H_2SO_4}=0,4.98=39,2\left(g\right)\)
Ta có: \(C_{\%_{H_2SO_4}}=\dfrac{39,2}{m_{dd_{H_2SO_4}}}.100\%=10\%\)
=> \(m_{dd_{H_2SO_4}}=392\left(g\right)\)
c. Ta có: \(m_{H_2}=0,4.2=0,8\left(g\right)\)
=> \(m_{dd_{MgSO_4}}=9,6+392-0,8=400,8\left(g\right)\)
Theo PT: \(n_{MgSO_4}=n_{Mg}=0,4\left(mol\right)\)
=> \(m_{MgSO_4}=0,4.120=48\left(g\right)\)
=> \(C_{\%_{MgSO_4}}=\dfrac{48}{400,8}.100\%=11,98\%\)
a)
$n_{Al} = 0,3(mol)$
$2Al + 3H_2SO_4 \to Al_2(SO_4)_3 + 3H_2$
Theo PTHH :
$n_{H_2SO_4} = \dfrac{3}{2}n_{Al} = 0,45(mol)$
$m_{dd\ H_2SO_4} = \dfrac{0,45.98}{12,25\%} = 360(gam)$
b)
$n_{H_2} = n_{H_2SO_4} = 0,45(mol)$
$V_{H_2} = 0,45.22,4 = 10,08(lít)$
c)
$n_{Al_2(SO_4)_3} = 0,15(mol)$
$m_{dd\ sau\ pư} = 8,1 + 360 - 0,45.2 = 367,2(gam)$
$C\%_{Al_2(SO_4)_3} = \dfrac{0,15.342}{367,2}.100\% = 14\%$
\(n_{FeCl_3}=\dfrac{48,75}{162,5}=0,3(mol)\\ 3NaOH+FeCl_3\to Fe(OH)_3\downarrow+3NaCl\\ \Rightarrow n_{Fe(OH)_3}=0,3(mol);n_{NaOH}=n_{NaCl}=0,9(mol)\\ a,m_{Fe(OH)_3}=0,3.107=32,1(g)\\ b,m_{dd_{NaOH}}=\dfrac{0,9.40}{10\%}=360(g)\\ c,C\%_{NaCl}=\dfrac{0,9.58,5}{360+48,75-32,1}.100\%=13,98\%\\ \)
\(d,2Fe(OH)_3+3H_2SO_4\to Fe_2(SO_4)_3+6H_2O\\ \Rightarrow n_{H_2SO_4}=0,45(mol)\\ \Rightarrow m_{dd_{H_2SO_4}}=\dfrac{0,45.98}{20\%}=220,5(g)\\ \Rightarrow V_{dd_{H_2SO_4}}=\dfrac{220,5}{1,14}=193,42(ml)\)
Ta có: \(n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
PT: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
a, \(n_{Al}=\dfrac{2}{3}n_{H_2}=\dfrac{1}{6}\left(mol\right)\Rightarrow m_{Al}=\dfrac{1}{6}.27=4,5\left(g\right)\)
b, \(n_{H_2SO_4}=n_{H_2}=0,25\left(mol\right)\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,25}{0,2}=1,25\left(M\right)\)
c, \(n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{3}n_{H_2}=\dfrac{1}{12}\left(mol\right)\)
\(\Rightarrow m_{Al_2\left(SO_4\right)_3}=\dfrac{1}{12}.342=28,5\left(g\right)\)
PTHH: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)
Ta có: \(\left\{{}\begin{matrix}n_{Al}=\dfrac{4,05}{27}=0,15\left(mol\right)\\n_{H_2SO_4}=\dfrac{294\cdot10\%}{98}=0,3\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,15}{2}< \dfrac{0,3}{3}\) \(\Rightarrow\) Axit còn dư
\(\Rightarrow\left\{{}\begin{matrix}n_{Al_2\left(SO_4\right)_3}=0,075\left(mol\right)=n_{H_2SO_4\left(dư\right)}\\n_{H_2}=0,225\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,225\cdot22,4=5,04\left(l\right)\\m_{Al_2\left(SO_4\right)_3}=0,075\cdot342=25,65\left(g\right)\\m_{H_2SO_4\left(dư\right)}=0,075\cdot98=7,35\left(g\right)\\m_{H_2}=0,225\cdot2=0,45\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd}=m_{Al}+m_{ddH_2SO_4}-m_{H_2}=297,6\left(g\right)\)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{Al_2\left(SO_4\right)_3}=\dfrac{25,65}{297,6}\cdot100\%\approx8,62\%\\C\%_{H_2SO_4\left(dư\right)}=\dfrac{7,35}{297,6}\cdot100\%\approx4,47\%\end{matrix}\right.\)
nFe = 11.2/56 = 0.2 (mol)
Fe + H2SO4 => FeSO4 + H2
0.2____0.2_______0.2___0.2
mH2SO4 = 0.2*98 = 19.6 (g)
mdd H2SO4 = 19.6*100/10 = 196 (g)
m dd sau phản ứng = 11.2 + 196 - 0.4 = 206.8 (g)
mFeSO4 = 0.2*152 = 30.4 (g)
C% FeSO4 = 30.4/206.8 * 100% = 14.7%
Vdd H2SO4 = mdd H2SO4 / D = 196 / 1.14 = 171.9 (ml)
CM FeSO4 = 0.2 / 0.1719 = 1.16 M
