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\(a,m_{Na_2CO_3}=\dfrac{500.20}{100}=100\left(g\right)\\ \rightarrow n_{Na_2CO_3}=\dfrac{100}{106}=\dfrac{50}{53}\left(mol\right)\)
PTHH: \(Na_2CO_3+2CH_3COOH\rightarrow2CH_3COONa+CO_2\uparrow+H_2O\)
\(\dfrac{50}{53}\)------->\(\dfrac{100}{53}\)--------------->\(\dfrac{100}{53}\)-------------->\(\dfrac{50}{53}\)
\(b,m_{axit}=\dfrac{100}{53}.60=\dfrac{6000}{53}\left(g\right)\\ c,m_{dd}=500+400-\dfrac{50}{53}.44=\dfrac{45500}{53}\left(g\right)\\ m_{CH_3COONa}=\dfrac{100}{53}.82=\dfrac{8200}{53}\left(g\right)\\ \rightarrow C\%_{CH_3COONa}=\dfrac{\dfrac{8200}{23}}{\dfrac{45500}{23}}.100\%=18,02\%\)
\(n_{Fe_2O_3}=\dfrac{8}{160}=0,05\left(mol\right)\)
PTHH: Fe2O3 + 3H2SO4 --> Fe2(SO4)3 + 3H2O
______0,05------>0,15--------->0,05
=> mH2SO4 = 0,15.98 = 14,7(g)
=> \(C\%\left(H_2SO_4\right)=\dfrac{14,7}{100}.100\%=14,7\%\)
\(C\%\left(Fe_2\left(SO_4\right)_3\right)=\dfrac{0,05.400}{8+100}.100\%=18,52\%\)
PTHH: Fe2(SO4)3 + 6NaOH --> 2Fe(OH)3\(\downarrow\) + 3Na2SO4
________0,05----------------------->0,1
=> mFe(OH)3 = 0,1.107=10,7(g)
a)mH2SO4=\(\dfrac{200.7,3\text{%}}{100\%}\)=14,6g
nHCl=\(\dfrac{14,6}{36,5}\)=0,4(mol)
PTHH:
NaOH+ HCl→ NaCl+ H2O
1 1 1 1
0,4 0,4 0,4 (mol)
⇒mNaOH=0,4.40=16(g)
Nồng độ % của dd NaOH cần dùng là:
C%NaOH=\(\dfrac{16}{200}\) .100%=8%
b)Ta có:mdd spứ=mdd trc pứ=400g
mNaCl=0,4.58,5=23,4g
Nồng độ % dd muối tạo thành sau pứ là:
C%dd NaCl=\(\dfrac{23,4}{400}\) .100%=5,85%
a)
$Na_2O + H_2SO_4 \to Na_2SO_4 + H_2O$
b)
Theo PTHH :
$n_{Na_2SO_4} = n_{Na_2O} = \dfrac{12,4}{62} = 0,2(mol)$
$m_{dd\ sau\ pư} = 12,4 + 200 = 212,4(gam)$
$\Rightarrow C\%_{Na_2SO_4} = \dfrac{0,2.142}{212,4}.100\% = 13,37\%$
a)\(Na_2O+H_2SO_4\rightarrow Na_2SO+H_2O\)
0,2 → 0,2 →0,2
b)\(M_{dd}\) pư là:\(M_{Na_2O}+m_{H_2SO_4}\)
\(=12,4+200=212,4\left(g\right)\)
\(C\%_{Na_2SO_4}=\dfrac{0,2.142.100\%}{212,4}=13,4\left(\%\right)\)
a. Ta có: \(n_{Fe_3O_4}=\dfrac{23,2}{232}=0,1\left(mol\right)\)
Ta lại có: \(C_{\%_{HCl}}=\dfrac{m_{ct_{HCl}}}{100}.100\%=7,3\%\)
=> mHCl = 7,3(g)
=> \(n_{HCl}=\dfrac{7,3}{36,5}=0,2\left(mol\right)\)
PTHH:
Fe3O4 + 8HCl ---> FeCl2 + 2FeCl3 + 4H2O
1 ---> 8
0,1 ---> 0,2
=> \(\dfrac{0,1}{1}>\dfrac{0,2}{8}\)
Vậy Fe3O4 dư
=> mdư = 23,2 - 7,3 = 15,9 (g)
b. Theo PT: \(n_{FeCl_2}=\dfrac{1}{8}.n_{HCl}=\dfrac{1}{8}.0,2=0,025\left(mol\right)\)
=> \(m_{FeCl_2}=0,025.127=3,175\left(g\right)\)
Theo PT: \(n_{FeCl_3}=\dfrac{1}{4}.n_{HCl}=\dfrac{1}{4}.0,2=0,05\left(mol\right)\)
=> \(m_{FeCl_3}=0,05.162,5=8,125\left(g\right)\)
=> \(m_{muối}=8,125+3,175=11,3\left(g\right)\)
c. Ta có: mdung dịch sau PỨ = \(23,2+100=123,2\left(g\right)\)
Theo PT: \(n_{H_2O}=\dfrac{1}{2}.n_{HCl}=\dfrac{1}{2}.0,2=0,1\left(mol\right)\)
=> \(m_{H_2O}=0,1.18=1,8\left(g\right)\)
mcác chất sau PỨ = 1,8 + 11,3 = 13,1(g)
=> \(C_{\%_{sauPỨ}}=\dfrac{13,1}{123,2}.100\%=10,63\%\)
\(a.MgO+2HCl\rightarrow MgCl_2+H_2O\)
\(b.n_{MgO}=\dfrac{16}{40}=0,04mol\)
\(\rightarrow n_{HCl}=0,04.2=0,08mol\)
\(C_{M_{HCl}}=\dfrac{0,08}{0,15}=0,53M\)
\(c.m_{MgCl_2}=0,04.95=3,8g\)
PTHH: 2CH3COOH+Na2CO3→2CH3COONa+CO2+H2O
Ta có:
nCO2=3,36/22,4=0,15mol
=> nCH3COOH=2nCO2=0,3mol
=> VCH3COOH=0,3/0,5=0,6l
=> nCH3COONa=2nCO2=0,3mol
=> mCH3COONa=0,3.82=24,6g
nNa2CO3 = nCO2 = 0,15mol
=> C%Na2CO3 = (0,15.106)/300.100%=5,3%
a) \(n_{CH_3COOH}=\dfrac{120.20\%}{60}=0,4\left(mol\right)\)
\(n_{Na_2CO_3}=\dfrac{53.30\%}{106}=0,15\left(mol\right)\)
PTHH: Na2CO3 + 2CH3COOH --> 2CH3COONa + CO2 + H2O
Xét tỉ lệ: \(\dfrac{0,15}{1}< \dfrac{0,4}{2}\) => Na2CO3 hết, CH3COOH dư
PTHH: Na2CO3 + 2CH3COOH --> 2CH3COONa + CO2 + H2O
0,15-------->0,3-------------->0,3------->0,15
=> \(m_{CH_3COONa}=0,3.82=24,6\left(g\right)\)
b) mdd sau pư = 120 + 53 - 0,15.44 = 166,4 (g)
=> \(C\%=\dfrac{24,6}{166,4}.100\%=14,78\text{%}\)