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\(n_{Fe}=\dfrac{11,2}{56}=0,2mol\)
\(n_{HCl}=2,5.0,2=0,5mol\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
0,2 < 0,5 ( mol )
0,2 0,4 0,2 0,2 ( mol )
Chất dư là HCl
\(m_{HCl\left(dư\right)}=\left(0,5-0,4\right).36,5=3,65g\)
\(V_{H_2}=0,2.22,4=4,48l\)
\(C_{M_{FeCl_2}}=\dfrac{0,2}{0,2}=1M\)
`n_[Fe]=[11,2]/56=0,2(mol)`
`n_[HCl]=0,3.2=0,6(mol)`
`Fe + 2HCl -> FeCl_2 + H_2 \uparrow`
`0,2` `0,4` `0,2` `0,2` `(mol)`
`a)` Ta có:`[0,2]/1 < [0,6]/2`
`=>HCl` dư
`=>V_[H_2]=0,2.22,4=4,48(l)`
`b)HCl` còn dư sau p/ứ
`=>m_[HCl(dư)]=(0,6-0,4).36,5=7,3(g)`
`c)C_[M_[FeCl_2]]=[0,2]/[0,3]~~0,67(M)`
`C_[M_[HCl(dư)]=[0,6-0,4]/[0,3]~~0,67(M)`
\(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\)
\(n_{HCl}=0,3.2=0,6\left(mol\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
0,2 < 0,6 ( mol )
0,2 0,4 0,2 0,2 ( mol )
\(V_{H_2}=0,2.22,4=4,48\left(l\right)\)
Chất dư là HCl
\(m_{HCl\left(dư\right)}=\left(0,6-0,4\right).36,5=7,3\left(g\right)\)
\(C_{M_{FeCl_2}}=\dfrac{0,2}{0,3}=0,66\left(M\right)\)
\(C_{M_{HCl\left(dư\right)}}=\dfrac{0,2}{0,3}=0,66\left(M\right)\)
1.
nAl=\(\dfrac{5,4}{27}\)=0,2 mol
mHCl=\(\dfrac{175.14,6}{100}\)=25,55g
nHCl=\(\dfrac{25,55}{36,5}\)=0,7
2Al + 6HCl → 2AlCl3 + 3H2↑
n trước pứ 0,2 0,7
n pứ 0,2 →0,6 → 0,2 → 0,3 mol
n sau pứ hết dư 0,1
Sau pứ HCl dư.
mHCl (dư)= 36,5.0,1=3,65g
mcác chất sau pư= 5,4 +175 - 0,3.2= 179,8g
mAlCl3= 133,5.0,2=26,7g
C%ddHCl (dư)= \(\dfrac{3,65.100}{179,8}=2,03%\)%
C%ddAlCl3 = \(\dfrac{26,7.100}{179,8}\)= 14,85%
2.
200ml= 0,2l
mMg= \(\dfrac{4,2}{24}=0,175mol\)
Mg + 2HCl → MgCl2 + H2↑
0,175→ 0,35 → 0,175→0,175 mol
a) VH2= 0,175.22,4=3,92l.
b)C%dHCl= \(\dfrac{0,35}{0,2}=1,75\)M
a) PTHH: \(BaCO_3+2HCl\rightarrow BaCl_2+H_2O+CO_2\uparrow\)
Ta có: \(\left\{{}\begin{matrix}n_{BaCO_3}=\dfrac{68,95}{197}=0,35\left(mol\right)\\n_{HCl}=0,25\cdot3,2=0,8\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,35}{1}< \dfrac{0,8}{2}\) \(\Rightarrow\) Axit còn dư
\(\Rightarrow n_{HCl\left(dư\right)}=0,8-0,35\cdot2=0,1\left(mol\right)\) \(\Rightarrow m_{HCl\left(dư\right)}=0,1\cdot36,5=3,65\left(g\right)\)
b+c) Theo PTHH: \(\left\{{}\begin{matrix}n_{CO_2}=n_{BaCl_2}=0,35\left(mol\right)\\n_{HCl\left(dư\right)}=0,1\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{CO_2}=0,35\cdot22,4=7,84\left(l\right)\\C_{M_{BaCl_2}}=\dfrac{0,35}{0,25}=1,4\left(M\right)\\C_{M_{HCl\left(dư\right)}}=\dfrac{0,1}{0,25}=0,4\left(M\right)\end{matrix}\right.\)
\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
\(n_{HCl}=0,1.1=0,1\left(mol\right)\)
PTHH :
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
Trc p/u: 0,1 0,1
p/u : 0,05 0,1 0,05 0,05
Sau p/u : 0,05 0 0,05 0,05
-> Fe dư sau p/u
a) \(m_{H_2}=0,05.2=0,1\left(g\right)\)
b) sau p/ư Fe dư
\(m_{Fedư}=0,05.2,8\left(g\right)\)
c) \(m_{FeCl_2}=0,05.\left(56+35,5.2\right)=6,35\left(g\right)\)
PTHH: \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\uparrow\)
a) Ta có: \(\left\{{}\begin{matrix}n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\\n_{H_2SO_4}=\dfrac{200\cdot4,9\%}{98}=0,1\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) Cả 2 chất p/ứ hết
b+c) Theo PTHH: \(n_{ZnSO_4}=n_{H_2}=n_{Zn}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}m_{ZnSO_4}=0,1\cdot161=16,1\left(g\right)\\m_{H_2}=0,1\cdot2=0,2\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd}=m_{Zn}+m_{ddH_2SO_4}-m_{H_2}=206,3\left(g\right)\)
\(\Rightarrow C\%_{ZnSO_4}=\dfrac{16,1}{206,3}\cdot100\%\approx7,8\%\)
a, \(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\)
\(n_{H_2SO_4}=0,2.2=0,4\left(mol\right)\)
PT: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
Xét tỉ lệ: \(\dfrac{0,2}{1}< \dfrac{0,4}{1}\), ta được H2SO4 dư.
Theo PT: \(n_{H_2}=n_{Fe}=0,2\left(mol\right)\Rightarrow V_{H_2}=0,2.22,4=4,48\left(l\right)\)
b, - H2SO4 dư.
\(n_{H_2SO_4\left(pư\right)}=n_{Fe}=0,2\left(mol\right)\Rightarrow n_{H_2SO_4\left(dư\right)}=0,4-0,2=0,2\left(mol\right)\)
\(\Rightarrow m_{H_2SO_4\left(dư\right)}=0,2.98=19,6\left(g\right)\)
c, \(C_{M_{H_2SO_4\left(dư\right)}}=\dfrac{0,2}{0,2}=1\left(M\right)\)
Theo PT: \(n_{FeSO_4}=n_{Fe}=0,2\left(mol\right)\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,2}{0,2}=1\left(M\right)\)
\(a,n_{HCl}=0,1.1=0,1\left(mol\right)\\ n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
PTHH: Fe + 2HCl ---> FeCl2 + H2
LTL: \(0,1>\dfrac{0,1}{2}\) => Fe dư
Theo pthh: \(n_{H_2}=n_{FeCl_2}=n_{Fe\left(pư\right)}=\dfrac{1}{2}n_{HCl}=\dfrac{1}{2}.0,1=0,05\left(mol\right)\)
=> VH2 = 0,05.22,4 = 1,12 (l)
b, Chất dư là Fe
mFe (dư) = (0,1 - 0,05).56 = 2,8 (g)
c, \(C_{M\left(FeCl_2\right)}=\dfrac{0,05}{0,1}=0,5M\)
a. \(nFe=\dfrac{11,2}{56}=0,2\left(mol\right)\)
\(mHCl=\dfrac{200.9,125}{100}=18,25\left(g\right)\)
\(nHCl=\dfrac{18,25}{36,5}=0,5\left(mol\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
1 2 1 1 (mol)
0,2 0,4 0,2 0,2
LTL : \(\dfrac{0,2}{1}< \dfrac{0,5}{2}\)
=> Fe đủ , HCl dư
mHCl ( dư ) = 0,1 . 36,5 = 3,65(g)
b.
mFeCl2 = 0,2 . 127 = 25,4 (g)
mH2 = 0,2 . 2 = 0,4 (g)
mdd = mFe + mdd HCl + mFeCl2 - mH2
mdd = 11,2 + 200 + 25,4 - 0,4 = 236,2(g)
\(C\%_{ddHCl}=\dfrac{3,65.100}{236,2}=1,55\%\)
\(C\%_{FeCl_2}=\dfrac{25,4.100}{236,2}=10,75\%\)
\(C\%_{H_2}=\dfrac{0,4.100}{236,2}=0,17\%\)
C%H2 ??