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\(n_{hh}=\dfrac{5.6}{22.4}=0.25\left(mol\right)\)
\(m_{Br_2}=200\cdot\dfrac{20}{100}=40\left(g\right)\)
\(n_{Br_2}=\dfrac{40}{160}=0.25\left(mol\right)\)
\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
\(0.25........0.25..........0.25\)
\(\)\(n_{C_2H_4}=n_{hh}=0.25\left(mol\right)\)
=> Sai đề
PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
Ta có: \(n_{C_2H_4}+n_{C_2H_2}=\dfrac{56}{22,4}=2,5\left(mol\right)\left(1\right)\)
Theo PT: \(n_{Br_2}=n_{C_2H_4}+2n_{C_2H_2}=\dfrac{480}{160}=3\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{C_2H_4}=2\left(mol\right)\\n_{C_2H_2}=0,5\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{2.22,4}{56}.100\%=80\%\\\%V_{C_2H_2}=100-80=20\%\end{matrix}\right.\)
a) \(m_{tăng}=m_{C_2H_4}=0,84\left(g\right)\)
=> \(n_{C_2H_4}=\dfrac{0,84}{28}=0,03\left(mol\right)\)
Gọi số mol CH4, H2 trong 3360 ml A là a, b
=> \(a+b=\dfrac{3,36}{22,4}-0,03=0,12\left(mol\right)\) (1)
Gọi số mol CH4, H2 trong 0,7 lít hh là ak, bk
=> ak + bk + 0,03k = \(\dfrac{0,7}{22,4}=0,03125\) (2)
Và 16ak + 2bk + 0,84k = 0,4875 (3)
(1)(2)(3) => \(\left\{{}\begin{matrix}a=0,09\left(mol\right)\\b=0,03\left(mol\right)\\k=\dfrac{5}{24}\end{matrix}\right.\)
\(\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,03}{0,15}.100\%=20\%\\\%V_{CH_4}=\dfrac{0,09}{0,15}.100\%=60\%\\\%V_{H_2}=\dfrac{0,03}{0,15}.100\%=20\%\end{matrix}\right.\)
b)
\(n_{C_2H_4}=\dfrac{1,68}{22,4}.20\%=0,015\left(mol\right)\)
\(n_{CH_4}=\dfrac{1,68}{22,4}.60\%=0,045\left(mol\right)\)
\(n_{H_2}=\dfrac{1,68}{22,4}.20\%=0,015\left(mol\right)\)
Bảo toàn C: \(n_{CO_2}=0,075\left(mol\right)\)
Bảo toàn H: \(n_{H_2O}=0,135\left(mol\right)\)
\(n_{Ca\left(OH\right)_2}=0,05.1=0,05\left(mol\right)\)
\(m_{ddCa\left(OH\right)_2}=1000.1,025=1025\left(g\right)\)
PTHH: Ca(OH)2 + CO2 --> CaCO3 + H2O
0,05---->0,05----->0,05
CaCO3 + CO2 + H2O --> Ca(HCO3)2
0,025<--0,025------------>0,025
\(m_{CaCO_3}=\left(0,05-0,025\right).100=2,5\left(g\right)\)
mdd sau pư = 1025 + 0,075.44 + 0,135.18 - 2,5 = 1028,23 (g)
\(C\%_{Ca\left(HCO_3\right)_2}=\dfrac{0,025.162}{1028,23}.100\%=0,3939\%\)
$Zn + H_2SO_4 \to ZnSO_4 + H_2$
$n_{Zn} = n_{H_2} = \dfrac{1,12}{22,4} = 0,05(mol)$
$\%m_{Zn} = \dfrac{0,05.65}{5,25}.100\% = 61,9\%$
$\%m_{Cu} =1 00\% -61,9\% = 38,1\%$
Pthh:
\(Zn+H2SO4->ZnSO\text{4+H2}\)
\(nZn=nH2=\dfrac{1,12}{22,4}=0,05mol\)
\(=>mZn=0,05.65=3,25g\)\(=>\%mZn=\dfrac{3,25}{5,25}.100\%=62\%\)
\(=>\%mCu=100-62=38\%\)
PTHH: \(K_2O+2HCl\rightarrow2KCl+H_2O\)
\(K_2SO_3+2HCl\rightarrow2KCl+SO_2\uparrow+H_2O\)
a) Ta có: \(\left\{{}\begin{matrix}n_{HCl}=\dfrac{200\cdot14,6\%}{36,5}=0,8\left(mol\right)\\n_{SO_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}n_{K_2SO_3}=0,3\left(mol\right)\\n_{K_2O}=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{K_2O}=\dfrac{0,1\cdot94}{0,1\cdot94+0,3\cdot158}\cdot100\%\approx16,55\%\\\%m_{K_2SO_3}=83,45\%\end{matrix}\right.\)
b) Theo các PTHH: \(n_{KCl}=0,8\left(mol\right)\) \(\Rightarrow m_{KCl}=74,5\cdot0,8=59,6\left(g\right)\)
Mặt khác: \(\left\{{}\begin{matrix}m_{hh}=56,8\left(g\right)\\m_{SO_2}=0,3\cdot64=19,2\left(g\right)\end{matrix}\right.\)
\(\Rightarrow m_{dd}=m_{hh}+m_{ddHCl}-m_{SO_2}=237,6\left(g\right)\)
\(\Rightarrow C\%_{KCl}=\dfrac{59,6}{237,6}\cdot100\%\approx25,1\%\)
\(m_Q=\left(7,7.2\right).0,1=1,54\left(g\right)\)
=> mT = 1,54 (g)
Gọi \(\left\{{}\begin{matrix}n_{CH_4}=a\left(mol\right)\\n_{C_2H_4}=b\left(mol\right)\\n_{H_2}=c\left(mol\right)\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}a+b+c=0,11\left(1\right)\\16a+28b+2c=1,54\left(2\right)\end{matrix}\right.\)
ngiảm = nH2(pư) = 0,11 - 0,1 = 0,01 (mol)
\(n_{Br_2}=\dfrac{4,8}{160}=0,03\left(mol\right)\)
Bảo toàn liên kết: b = 0,01 + 0,03 = 0,04 (mol) (3)
(1)(2)(3) => a = 0,02 (mol); b = 0,04 (mol); c = 0,05 (mol)
=> nH2(Q) = 0,05 - 0,01 = 0,04 (mol)
=> \(\%V_{H_2}=\dfrac{0,04}{0,1}.100\%=40\%\)
$C_2H_4 + Br_2 \to C_2H_4Br_2$
Theo PTHH :
$n_{C_2H_4} = n_{Br_2} = 0,1.2 = 0,2(mol)$
$\%m_{C_2H_4} = \dfrac{0,2.28}{10}.100\% = 56\%$
$\%m_{CH_4} = 100\% - 56\% = 44\%$