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a, \(Cu+2H_2SO_{4\left(đ\right)}\underrightarrow{t^o}CuSO_4+SO_2+2H_2O\)
b, \(n_{SO_2}=\dfrac{3,7185}{24,79}=0,15\left(mol\right)\)
Theo PT: \(n_{Cu}=n_{CuSO_4}=n_{SO_2}=0,15\left(mol\right)\)
\(\Rightarrow m_{Cu}=0,15.64=9,6\left(g\right)=m\)
Theo PT: \(n_{H_2SO_4}=2n_{SO_2}=0,3\left(mol\right)\Rightarrow C\%_{H_2SO_4}=\dfrac{0,3.98}{200}.100\%=14,7\%=x\)
Ta có: m dd sau pư = 9,6 + 200 - 0,15.64 = 200 (g)
\(\Rightarrow C\%_{CuSO_4}=\dfrac{0,15.160}{200}.100\%=12\%\)
Câu 5 :
\(n_{H2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
a) Pt : \(Mg+2HCl\rightarrow MgCl_2+H_2|\)
1 2 1 1
0,1 0,2 0,1 0,1
\(MgO+2HCl\rightarrow MgCl_2+H_2O|\)
1 2 1 1
0,15 0,3 0,15
a) \(n_{Mg}=\dfrac{0,1.1}{1}=0,1\left(mol\right)\)
\(m_{Mg}=0,1.24=2,4\left(g\right)\)
\(m_{MgO}=8,4-2,4=6\left(g\right)\)
0/0Mg = \(\dfrac{2,4.100}{8,4}=28,57\)0/0
0/0MgO = \(\dfrac{6.100}{8,4}=71,43\)0/0
b) Có : \(m_{MgO}=6\left(g\right)\)
\(n_{MgO}=\dfrac{6}{40}=0,15\left(mol\right)\)
\(n_{HCl\left(tổng\right)}=0,2+0,3=0,5\left(mol\right)\)
\(m_{HCl}=0,5.36,5=18,25\left(g\right)\)
\(m_{ddHCl}=\dfrac{18,25.100}{3,65}=500\left(g\right)\)
\(n_{MgCl2\left(tổng\right)}=0,1+0,15=0,25\left(mol\right)\)
⇒ \(m_{MgCl2}=0,15.95=14,25\left(g\right)\)
\(m_{ddspu}=8,4+500-\left(0,1.2\right)=508,2\left(g\right)\)
\(C_{MgCl2}=\dfrac{14,25.100}{508,2}=2,8\)0/0
Chúc bạn học tốt
a, \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(ZnO+2HCl\rightarrow ZnCl_2+H_2O\)
b, Ta có: 65nZn + 81nZnO = 17,85 (1)
Theo PT: \(n_{ZnCl_2}=n_{Zn}+n_{ZnO}=\dfrac{34}{136}=0,25\left(mol\right)\) (2)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{Zn}=0,15\left(mol\right)\\n_{ZnO}=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow m_{ZnO}=0,1.81=8,1\left(g\right)\)
c, \(n_{HCl}=2n_{ZnCl_2}=0,5\left(mol\right)\) \(\Rightarrow V_{HCl}=\dfrac{0,5}{1,5}=\dfrac{1}{3}\left(l\right)=\dfrac{1000}{3}\left(ml\right)\)
\(n_{H_2}=n_{Zn}=0,15\left(mol\right)\Rightarrow V_{H_2}=0,15.24,79=3,7185\left(l\right)\)
\(a)2Al+6HCl\rightarrow2AlCl_3+3H_2\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ b)n_{H_2}=\dfrac{5,6}{22,4}=0,25mol\\ n_{Al}=a;n_{Fe}=b\\ \left\{{}\begin{matrix}3a+b=0,25\\27a+56b=8,3\end{matrix}\right.\\ a=\dfrac{19}{470};b=\dfrac{121}{940}\\ \%m_{Al}=\dfrac{\dfrac{19}{470}\cdot27}{8,3}\cdot100=13,15\%\\ \%m_{Fe}=100-13,15=86,85\%\\ c)n_{HCl}=3\cdot\dfrac{19}{470}+2\cdot\dfrac{121}{940}=\dfrac{89}{235}mol\\ m_{ddHCl=}=\dfrac{\dfrac{89}{235}\cdot36,5}{7,3}\cdot100=189g\\ d)n_{AlCl_3}=n_{Al}=\dfrac{19}{470}mol\\ n_{Fe}=n_{FeCl_2}=\dfrac{121}{940}mol\)
\(m_{dd}=8,3+189-0,25.2=196,8g\\ C_{\%AlCl_3}=\dfrac{\dfrac{19}{470}\cdot133,8}{196,8}\cdot100=2,8\%\\ C_{\%FeCl_2}=\dfrac{\dfrac{121}{940}127}{196,8}\cdot100=8,3\%\)
Bài 1 :
\(n_{H_2}=\dfrac{2.24}{22.4}=0.1\left(mol\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(0.1..................................0.1\)
\(m_{hh}=x=0.1\cdot56+4.4=10\left(g\right)\)
Bài 2 :
\(n_{H_2}=\dfrac{2.24}{22.4}=0.1\left(mol\right)\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
\(0.1.......0.1..........0.1.............0.1\)
\(m_{Fe_2O_3}=7.2-0.1\cdot56=1.6\)
\(n_{Fe_2O_3}=\dfrac{7.2-0.1\cdot56}{160}=0.01\left(mol\right)\)
\(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)
\(0.01...........0.03..............0.01\)
\(c.\)
\(V_{dd_{H_2SO_4}}=\dfrac{0.1+0.03}{1}=0.13\left(l\right)\)
\(d.\)
\(C_{M_{FeSO_4}}=\dfrac{0.1}{0.13}=\dfrac{10}{13}\left(M\right)\)
\(C_{M_{Fe_2\left(SO_4\right)_3}}=\dfrac{0.03}{0.13}=\dfrac{3}{13}\left(M\right)\)
\(n_{H_2}=\dfrac{2,24}{22,4}=0,1(mol)\\ a,Fe+2HCl\to FeCl_2+H_2\\ \Rightarrow n_{Fe}=0,1(mol);n_{HCl}=0,2(mol)\\ \Rightarrow m_{Fe}=0,1.56=5,6(g)\\ C_{M_{HCl}}=\dfrac{0,2}{0,25}=0,8M\\ b,m_{dd_{HCl}}=250.1,12=280(g)\\ n_{FeCl_2}=0,1(mol)\\ \Rightarrow C\%_{FeCl_2}=\dfrac{0,1.127}{5,6+280-0,1.2}.100\%=4,45\%\)
Cho hỗn hợp X vào H2SO4 thu được (a+b)g --> hh X gồm oxit kim loại A và kim loại B
Trong đó: oxit kim loại A ko bị khử bởi CO, kim loại B ko tan trong d.d H2SO4
-->Dễ suy ra kim loại B là Cu
(*)Giả sử oxit kim loại A là AO
AO+H2SO4-->ASO4+H2O
1..........1..........1 mol
m d.d sau pư=A+16+980=A+996 g
C% ASO4=11,765%
\(\Rightarrow\frac{A+96}{A+996}=0,11765\)
\(\Rightarrow A=24\left(Mg\right)\)
(*) Giả sử là A2O3 làm tương tự -->loại
Nếu ko chia trường hợp thì gọi là A2Ox hoặc AxOy
\(\left(a\right)Zn+2HCl\rightarrow ZnCl_2+H_2\\ DungdịchX:ZnCl_2, A:H_2,B:Ag\\ n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\\ n_{HCl}=2n_{H_2}=0,5\left(mol\right)\\ \Rightarrow x=m_{ddHCl}=\dfrac{0,5.36,5}{3,65}=500\left(g\right)\\ n_{Zn}=n_{H_2}=0,2\left(mol\right)\\ \Rightarrow y=m_{Ag}=27,05-0,2.65=14,05\left(g\right)\\ \left(b\right):m_{ddsaupu}=0,2.65+500-0,2.2=512,6\left(g\right)\\ TheoPT:n_{ZnCl_2}=n_{H_2}=0,2\left(mol\right)\\ C\%_{ZnCl_2}=\dfrac{0,2.136}{512,5}.100=5,3\%\)