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\(n_P=\dfrac{12,4}{31}=0,4\left(mol\right)\\
pthh:4P+5O_2\underrightarrow{t^o}2P_2O_5\)
0,4 0,2
\(m_{P_2O_5}=142.0,2=28,4g\)
\(n_{O_2}=\dfrac{17}{32}=0,53\left(mol\right)\)
\(pthh:4P+5O_2\underrightarrow{t^o}2P_2O_5\\
LTL:\dfrac{0,4}{4}< \dfrac{0,53}{5}\)
=> O2 dư
\(n_{O_2\left(p\text{ư}\right)}=\dfrac{5}{4}n_P=0,5\left(mol\right)\\
m_{O_2\left(d\right)}=\left(0,53-0,5\right).32=0,96g\)
`4P + 5O_2` $\xrightarrow[]{t^o}$ `2P_2 O_5`
`0,4` `0,5` `0,2` `(mol)`
`n_P = [ 12,4 ] / 31 = 0,4 (mol)`
`a) m_[P_2 O_5] = 0,2 . 142 = 28,4 (g)`
`b) n_[O_2] = 17 / 32 = 0,53125 (mol)`
Ta có: `[ 0,4 ] / 4 < [ 0,53125 ] / 5`
`->O_2` dư
`=> m_[O_2 (dư)] = ( 0,53125 - 0,5 ) . 32 = 1(g)`
nFe = 5.6/56 = 0.1 (mol)
nHCl = 0.2*2 = 0.4 (mol)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
LTL : 0.1/1 < 0.4/2 => HCl dư
mHCl dư = ( 0.4 - 0.2 ) * 36.5 = 7.3 (g)
VH2 = 0.2*22.4 = 4.48 (l)
CM FeCl2 = 0.1/0.2 = 0.5(M)
CM HCl dư = 0.2 / 0.2 = 1(M)
PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
Ta có: \(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,2\left(mol\right)\\n_{FeCl_2}=0,1\left(mol\right)=n_{H_2}\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,1\cdot22,4=2,24\left(l\right)\\m_{FeCl_2}=0,1\cdot127=12,7\left(g\right)\\C_{M_{FeCl_2}}=\dfrac{0,1}{0,1}=1\left(M\right)\\C_{M_{HCl}}=\dfrac{0,2}{0,1}=2\left(M\right)\end{matrix}\right.\)
a) \(n_{Fe}=\dfrac{2,8}{56}=0,05\left(mol\right)\)
PTHH: `Fe + 2HCl -> FeCl_2 + H_2`
0,05->0,1----->0,05---->0,05
`=> V_{ddHCl} = (0,1)/2 = 0,05 (l)`
b) `V_{H_2} = 0,05.22,4 = 1,12 (l)`
c) `C_{M(FeCl_2)} = (0,05)/(0,05) = 1M`
nAl = 5.4 / 27 = 0.2 (mol)
2Al + 6HCl => 2AlCl3 + 3H2
0.2......0.6............0.2.......0.3
a) VH2 = 0.3 * 22.4 = 6.72 (l)
b) mAlCl3 = 0.2 * 133.5 = 26.7 (g)
c) VddHCl = 0.6 / 1.5 = 0.4 (l)
d) CMAlCl3 = 0.2 / 0.4 = 0.5 (M)
PTHH: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)
Ta có: \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,6\left(mol\right)\\n_{AlCl_3}=0,2\left(mol\right)\\n_{H_2}=0,3\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,3\cdot22,4=6,72\left(l\right)\\m_{AlCl_3}=0,2\cdot133,5=26,7\left(g\right)\\V_{HCl}=\dfrac{0,6}{1,5}=0,4\left(l\right)=400\left(ml\right)\\C_{M_{AlCl_3}}=\dfrac{0,2}{0,4}=0,5\left(M\right)\end{matrix}\right.\)
a) \(n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\)
PTHH: 2Al + 3H2SO4 --> Al2(SO4)3 + 3H2
0,4-->0,6---------->0,2------->0,6
=> \(C_{M\left(dd.H_2SO_4\right)}=\dfrac{0,6}{0,15}=4M\)
b) VH2 = 0,6.22,4 = 13,44 (l)
c) \(C_{M\left(Al_2\left(SO_4\right)_3\right)}=\dfrac{0,2}{0,15}=\dfrac{4}{3}M\)
\(n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\\
pthh:2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
0,4 0,6 0,2 0,6
\(C_M_{H_2SO_4}=\dfrac{0,6}{0,15}=4M\\ V_{H_2}=0,622,4=13,44L\)
\(C_M=\dfrac{0,2}{0,15}=1,3M\)
