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nHCl=0,6 mol
FeO+2HCl-->FeCl2+ H2O
x mol x mol
Fe2O3+6HCl-->2FeCl3+3H2O
x mol 2x mol
72x+160x=11,6 =>x=0,05 mol
A/ CFeCl2=0,05/0,3=1/6 M
CFeCl3=0,1/0,3=1/3 M
CHCl du=(0,6-0,4)/0,3=2/3 M
B/
NaOH+ HCl-->NaCl+H2O
0,2 0,2
2NaOH+FeCl2-->2NaCl+Fe(OH)2
0,1 0,05
3NaOH+FeCl3-->3NaCl+Fe(OH)3
0,3 0,1
nNaOH=0,6
CNaOH=0,6/1,5=0,4M
Gọi x,y lần lượt là số mol của MgO, Fe3O4
Pt: MgO + H2SO4 --> MgSO4 + H2O
.......x............x..................x
......Fe3O4 + 4H2SO4 --> Fe2(SO4)3 + FeSO4 + 4H2O
.........y................4y..................y................y
Ta có hệ pt: \(\left\{{}\begin{matrix}40x+232y=35,84\\120x+552y=90,24\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,2\\y=0,12\end{matrix}\right.\)
mMgO = 0,2 . 40 = 8 (g)
mFe3O4 = 35,84 - 8 = 27,84 (g)
nH2SO4 = x + 4y = 0,2 + 4 . 0,12 = 0,68 mol
mdd H2SO4 = \(\dfrac{0,68\times98}{9,8}.100=680\left(g\right)\)
mdd sau pứ = mhh + mdd H2SO4 = 35,84 + 680 = 715,84 (g)
C% dd MgSO4 = \(\dfrac{0,2.120}{715,84}.100\%=3,35\%\)
C% dd FeSO4 = \(\dfrac{0,12.152}{715,84}.100\%=2,548\%\)
C% dd Fe2(SO4)3 = \(\dfrac{0,12.400}{715,84}.100\%=6,705\%\)
\(n_{H_2SO_4}=0,25.2=0,5\left(mol\right)\)
Gọi \(\left\{{}\begin{matrix}n_{Al_2O_3}=x\left(mol\right)\\n_{CuO}=y\left(mol\right)\end{matrix}\right.\)
\(Al_2O_3+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2O\)
x----------> 3x --------> x
\(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)
y --------> y --------> y
Có hệ phương trình
\(\left\{{}\begin{matrix}102x+80y=26,2\\3x+y=0,5\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,1\\y=0,2\end{matrix}\right.\)
\(\%_{m_{Al_2O_3}}=\dfrac{102.0,1.100}{26,2}=38,93\%\)
\(\%_{m_{CuO}}=\dfrac{80.0,2.100}{26,2}=61,07\%\)
\(CM_{Al_2\left(SO_4\right)_3}=\dfrac{x}{0,25}=\dfrac{0,1}{0,25}=0,4M\)
\(CM_{CuSO_4}=\dfrac{y}{0,25}=\dfrac{0,2}{0,25}=0,8M\)
Bài 1:
PTHH: \(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)
Ta có: \(n_{Mg}=\dfrac{1}{2}n_{HCl}=\dfrac{1}{2}\cdot0,11\cdot1,5=0,0825\left(mol\right)\)
\(\Rightarrow m_{Mg}=0,0825\cdot24=1,98\left(g\right)\)
Bài 1:
\(n_{Na_2SO_3}=\frac{100,8}{126}=0,8\left(mol\right)\)
\(m_{HCl}=\frac{120.14,6}{100}=17,52\left(g\right)=>n_{HCl}=\frac{17,52}{36,5}=0,48\left(mol\right)\)
PTHH: \(Na_2SO_3+2HCl\rightarrow2NaCl+SO_2+H_2O\)
________0,24<-------0,48------->0,48---->0,24____________(mol)
=> \(m_{dd}=100,8+120-0,24.64=205,44\left(g\right)\)
\(C\%\left(Na_2SO_3\right)=\frac{\left(0,8-0,24\right).126}{205,44}.100\%=34,35\%\)
\(C\%\left(NaCl\right)=\frac{0,48.58,5}{205,44}.100\%=13,67\%\)
PT: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
\(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)
a, Giả sử: \(\left\{{}\begin{matrix}n_{Fe}=x\left(mol\right)\\n_{Fe_2O_3}=y\left(mol\right)\end{matrix}\right.\)
Ta có: \(m_{H_2SO_4}=\frac{196.20}{100}=39,2\left(g\right)\Rightarrow n_{H_2SO_4}=\frac{39,2}{98}=0,4\left(mol\right)\)
Theo PT: \(\Sigma n_{H_2SO_4}=x+3y=0,4\left(1\right)\)
Ta có: \(n_{H_2}=\frac{0,4}{2}=0,2\left(mol\right)\)
Theo PT: \(n_{Fe}=n_{H_2}=0,2\left(mol\right)\Rightarrow x=0,2\left(2\right)\)
Từ (1) và (2) ⇒ x = 0,2 (mol) ; y = 1/15 (mol)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Fe}=\frac{0,2.56}{0,2.56+\frac{1}{15}.160}.100\%\approx51,2\%\text{ }\\\%m_{Fe_2O_3}\approx48,8\%\end{matrix}\right.\)
b, Theo PT: \(\left\{{}\begin{matrix}n_{FeSO_4}=n_{Fe}=0,2\left(mol\right)\\n_{Fe_2\left(SO_4\right)_3}=n_{Fe_2O_3}=\frac{1}{15}\left(mol\right)\end{matrix}\right.\)
Ta có: m dd sau pư = mFe + mFe2O3 + m dd H2SO4 - mH2
= 0,2.56 + 1/15.160 + 196 - 0,4
≃ 217,467 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{FeSO_4}=\frac{0,2.152}{217,467}.100\%\approx13,98\%\\C\%_{Fe_2\left(SO_4\right)_3}=\frac{\frac{1}{15}.400}{217,467}.100\%\approx12,26\%\end{matrix}\right.\)
Bạn tham khảo nhé!
a)
nH2SO4 = 0.5a (mol)
nKOH = 0.4 (mol)
nAl(OH)3 = 0.005 (mol)
Trường hợp 1: H2SO4 dư
H2SO4 + 2KOH -----> K2SO4 + 2H2O
_0.2_____0.4_
nH2SO4dư = 0.5a - 0.2 (mol) => 1/2nH2SO4dư = 0.25a - 0.1 (mol)
2Al(OH)3 + 3H2SO4 -----> Al2(SO4)3 + 6H2O
_0.005____0.0075_
=> 0.25a - 0.1 = 0.0075 => a = 0.43
Trường hợp 2: KOH dư
H2SO4 + 2KOH -----> K2SO4 + 2H2O
_0.5a_____a_
nKOHdư = 0.4 - a (mol) => 1/2nKOHdư = 0.2 - 0.5a (mol)
Al(OH)3 + KOH -----> KAlO2 + 2H2O
_0.005__0.005_
=> 0.2 - 0.5a = 0.005 => a = 0.39
b)
Vì ddA td với Fe3O4 và FeCO3 => ddA có chứa H2SO4 dư, chọn TH1: a = 0.43
=> nH2SO4 trong 100ml ddA = 0.1x0.43 = 0.043 (mol)
Fe3O4 + 4H2SO4 -----> FeSO4 + Fe2(SO4)3 + 4H2O
__x_______4x_
FeCO3 + H2SO4 -----> FeSO4 + H2O + CO2
__y_______y_
mhhB = 2.668 (g) => 232x + 116y = 2.668
nH2SO4 = 0.043 (mol) => 4x + y = 0.043
=> x = 0.01; y = 0.003
mFe3O4 = 2.32 (g)
mFeCO3 = 0.348 (g)
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