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a) \(n_{Fe_2\left(SO_4\right)_3}=\dfrac{20}{400}=0,05\left(mol\right)\)
=> \(\left\{{}\begin{matrix}n_{Fe}=0,1\left(mol\right)\\n_S=0,15\left(mol\right)\\n_O=0,6\left(mol\right)\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}m_{Fe}=0,1.56=5,6\left(g\right)\\m_S=0,15.32=4,8\left(g\right)\\m_O=0,6.16=9,6\left(g\right)\end{matrix}\right.\)
b) \(n_{C_2H_6O}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
=> \(\left\{{}\begin{matrix}n_C=0,6\left(mol\right)\\n_H=1,8\left(mol\right)\\n_O=0,3\left(mol\right)\end{matrix}\right.\) => \(\left\{{}\begin{matrix}m_C=0,6.12=7,2\left(g\right)\\m_H=1,8.1=1,8\left(g\right)\\m_O=0,3.16=4,8\left(g\right)\end{matrix}\right.\)
c) Gọi số mol Fe2O3, MgO là a, b (mol)
=> 160a + 40b = 25
nO = 3a + b = \(\dfrac{25.32\%}{16}=0,5\) (mol)
=> a = 0,125 (mol); b = 0,125 (mol)
=> \(\left\{{}\begin{matrix}n_{Fe}=0,25\left(mol\right)\\n_{Mg}=0,125\left(mol\right)\\n_O=0,5\left(mol\right)\end{matrix}\right.\) => \(\left\{{}\begin{matrix}m_{Fe}=0,25.56=14\left(g\right)\\m_{Mg}=0,125.24=3\left(g\right)\\m_O=0,5.16=8\left(g\right)\end{matrix}\right.\)
a. Số mol sắt (III) sunfat Fe2(SO4)3 là 20/400=0,05 (mol).
mFe=0,05.2.56=5,6 (g), mS=0,05.3.32=4,8 (g), mO=0,05.3.4.16=9,6 (g).
b. Số mol khí C2H6O (ở đktc) là 6,72/22,4=0,3 (mol).
mC=0,3.2.12=7,2 (g), mH=0,3.6=1,8 (g), mO=0,3.16=4,8 (g).
c. Gọi x (mol) và y (mol) lần lượt là số mol của Fe2O3 và MgO.
160x+40y=25 (1).
\(\dfrac{3x.16+16y}{25}=32\%\) \(\Rightarrow\) 48x+16y=8 (2).
Giải hệ phương trình gồm (1) và (2), ta suy ra x=0,125 (mol) và y=0,125 (mol).
mFe=0,125.2.56=14 (g).
mMg=0,125.24=3 (g).
mO=(0,125.3+0,125).16=8 (g).
3/ nhỗn hợp = 8,4.1023 : 6.1023 = 1,4 (mol)
nO = 230,4 : 16 = 14,4 (mol)
Gọi nCa3(PO4)2 = x (mol) \(\rightarrow\)
nO = 8x (mol)
\(\rightarrow\) nAl2(SO4)3 = 1,4-x (mol) \(\rightarrow\) nO = 12.(1,4-x) (mol)
\(\rightarrow\) 8x + 12.(1,4-x) = 14,4 \(\rightarrow\) x = 0,6 (mol)
nCa3(PO4)2= 0,6 (mol) \(\rightarrow Ca_3\left(PO_4\right)_2=\) 0,6.310 = 186 (g)
nAl2(SO4)3= 1,4-x = 0,8 (mol) \(\rightarrow^mAl_2\left(SO_4\right)_3\) = 0,8 . 342 = 273,6 (g)
\(Fe_2O_3+3H_2\rightarrow\left(t^o\right)2Fe+3H_2O\\ CuO+H_2\rightarrow\left(t^o\right)Cu+H_2O\\ Đặt:n_{Fe_2O_3}=a\left(mol\right);n_{CuO}=b\left(mol\right)\left(a,b>0\right)\\ m_{hhoxit}=k\left(g\right)\\ \Rightarrow\left(1\right)160a+80b=k\\ \left(2\right)112a+64b=0,72k\\ \Rightarrow6,4a=12,8b\\ \Leftrightarrow\dfrac{a}{b}=\dfrac{12,8}{6,4}=\dfrac{2}{1}\\ \Rightarrow\%m_{Fe_2O_3}=\dfrac{160.2}{160.2+80.1}.100=80\%\\ \Rightarrow\%m_{CuO}=20\%\)
Đặt \(\left\{{}\begin{matrix}n_{CuO}=x\left(mol\right)\\n_{Fe_2O_3}=y\left(mol\right)\end{matrix}\right.\)
\(m_{CuO}+m_{Fe_2O_3}=40\\ \Rightarrow80x+160y=40\left(1\right)\)
\(PTHH:CuO+H_2\underrightarrow{t^o}Cu+H_2O\\ \left(mol\right)......x\rightarrow.x\\ PTHH:Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\\ \left(mol\right).....y\rightarrow....3y\\ V_{H_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\\ \Rightarrow x+3y=0,6\left(2\right)\)
\(\xrightarrow[\left(2\right)]{\left(1\right)}\left\{{}\begin{matrix}80x+160y=40\\x+3y=0,6\end{matrix}\right.\\ \Leftrightarrow\left\{{}\begin{matrix}x=0,3\\y=0,1\end{matrix}\right.\)
a) \(\left\{{}\begin{matrix}m_{CuO}=80.0,3=24\left(g\right)\\m_{Fe_2O_3}=40-24=16\left(g\right)\end{matrix}\right.\)
b) \(\left\{{}\begin{matrix}\%m_{CuO}=\dfrac{24}{40}.100\%=60\%\\\%m_{Fe_2O_3}=100\%-60\%=40\%\end{matrix}\right.\)
a, - MgO không bị khử bởi H2.
PT: \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
Theo PT: \(n_{CuO}=n_{H_2}=0,1\left(mol\right)\Rightarrow m_{CuO}=0,1.80=8\left(g\right)\)
\(\Rightarrow m_{MgO}=16-8=8\left(g\right)\)
b, Ta có: \(\%m_{CuO}=\%m_{MgO}=\dfrac{8}{16}.100=50\%\)
c, Theo PT: \(n_{Cu}=n_{H_2}=0,1\left(mol\right)\Rightarrow m_{Cu}=0,1.64=6,4\left(g\right)\)
a, -Gọi số mol của CuO và Fe2O3 lần lượt là x, y ( mol )
PTKL : \(80x+160y=40\left(I\right)\)
\(CuO+H_2\rightarrow Cu+H_2O\)
..x.........x............
\(Fe_2O_3+3H_2\rightarrow2Fe+3H_2O\)
...y............3y......
=> \(n_{H_2}=x+3y=\dfrac{V}{22,4}=0,6\left(mol\right)\left(II\right)\)
- Giair I và II ta được : x = 0,3 , y = 0,1 ( mol )
=> \(\left\{{}\begin{matrix}mCuO=n.M=24\left(g\right)\\mFe2O3=mhh-mCuO=16\left(g\right)\end{matrix}\right.\)
b, \(\%CuO=\dfrac{m}{mhh}.100\%=60\%\)
=> %Fe2O3 =100% - %CuO = 40% .
Vậy ...
\(n_{FeO}=a\left(mol\right),n_{ZnO}=b\left(mol\right)\)
\(m_{hh}=72a+81b=15.3\left(g\right)\left(1\right)\)
\(TC:n_{FeO\left(pư\right)}=0.8a\left(mol\right),n_{ZnO\left(pư\right)}=0.8b\left(mol\right)\)
\(FeO+CO\underrightarrow{t^0}Fe+CO_2\)
\(ZnO+CO\underrightarrow{t^0}Zn+CO_2\)
\(BTKL:\)
\(15.3+28n_{CO}=12.74+44n_{CO}\)
\(\Rightarrow n_{CO}=\dfrac{15.3-12.74}{44-28}=0.16\left(mol\right)\)
\(\Rightarrow0.8a+0.8b=0.16\left(2\right)\)
\(\left(1\right),\left(2\right):a=b=0.1\)
\(\%FeO=\dfrac{0.1\cdot72}{15.3}\cdot100\%=47.06\%\)
\(\%ZnO=52.94\%\)
a) Giả sử có 100 gam hỗn hợp
=> \(m_S=\dfrac{100.22,61}{100}=22,61\left(g\right)\)
=> \(n_S=\dfrac{22,61}{32}=\dfrac{2261}{3200}\left(mol\right)\)
Mà nO = 4nS
=> \(n_O=\dfrac{2261}{800}\left(mol\right)\)
\(\%m_O=\dfrac{\dfrac{2261}{800}.16}{100}.100\%=45,22\%\)
b)
\(n_{Fe}=\dfrac{18.10^{24}}{6.10^{23}}=30\left(mol\right)\)
=> \(n_{Fe_2\left(SO_4\right)_3}=15\left(mol\right)\)
Gọi số mol CuSO4 là x (mol)
=> mhh = 160x + 6000 (g)
nS = 15.3 + x = x + 45 (mol)
\(\%m_S=\dfrac{\left(x+45\right).32}{160x+6000}.100\%=22,61\%\)
=> x = 20 (mol)
mhh = 160.20 + 6000 = 9200 (g)
