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\(PTHH:Cu+Cl_2\overset{t^o}{--->}CuCl_2\)
Ta có: \(n_{Cl_2}=\dfrac{16,8}{22,4}=0,75\left(mol\right)\)
a. Theo PT: \(n_{Cu}=n_{CuCl_2}=n_{Cl_2}=0,75\left(mol\right)\)
\(\Rightarrow a=m_{Cu}=0,75.64=48\left(g\right)\)
\(b.\Rightarrow b=m_{CuCl_2}=135.0,75=101,25\left(g\right)\)
nH2 = 0,336/22,4 = 0,015 (mol)
PTHH: 2A + 6HCl -> 2ACl3 + 3H2
nACl3 = nA = 0,015 : 3 . 2 = 0,01 (mol)
M(A) = 0,27/0,01 = 27 (g/mol)
=> A là Al
mAlCl3 = 0,01 . 133,5 = 1,335 (g)
Câu 6.
\(n_{H_2}=\dfrac{0,336}{22,4}=0,015mol\)
\(2A+6HCl\rightarrow2ACl_3+3H_2\)
0,01 0,015
\(\overline{M_A}=\dfrac{0,27}{0,01}=27đvC\)
\(\Rightarrow A\) là Al nhôm.
\(m_{AlCl_3}=0,01\cdot133,5=1,335g\)
\(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\\ 2Fe+3Cl_2\rightarrow\left(t^o\right)2FeCl_3\\ n_{Cl_2}=\dfrac{3}{2}.0,2=0,3\left(mol\right)\\ n_{FeCl_3}=n_{Fe}=0,2\left(mol\right)\\ a,V_{Cl_2\left(đktc\right)}=0,3.22,4=6,72\left(l\right)\\ b,m_{FeCl_3}=162,5.0,2=32,5\left(g\right)\)
a, \(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\)
PT: \(2Fe+3Cl_2\underrightarrow{t^o}2FeCl_3\)
Theo PT: \(n_{Cl_2}=\dfrac{3}{2}n_{Fe}=0,3\left(mol\right)\)
\(\Rightarrow V_{Cl_2}=0,3.22,4=6,72\left(l\right)\)
b, \(n_{FeCl_3}=n_{Fe}=0,2\left(mol\right)\Rightarrow m_{FeCl_3}=0,2.162,5=32,5\left(g\right)\)
\(1.\\ n_A=\dfrac{16,8}{A}mol\\ n_{H_2}=\dfrac{7,437}{24,79}=0,3mol\\ A+2HCl\rightarrow ACl_2+H_2\\ \Rightarrow\dfrac{16,8}{A}=0,3\\ \Rightarrow A=56g/mol\\ \Rightarrow A.là.Fe\\ \Rightarrow Chọn.A\\ 2.\\ n_{Fe}=\dfrac{5,6}{56}=0,1mol\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ n_{Fe}=n_{H_2}=0,1mol\\ V_{H_2}=0,1.24,79=2,479l\\ \Rightarrow Chọn.B\\ 3.\\ Axit:H_2SO_4;HCl\\ \Rightarrow Chọn.B\\ 4.\\ 3,719l\Rightarrow3,7185\\ CTHH:R\\ n_R=\dfrac{3,6}{R}mol\\ n_{H_2}=\dfrac{3,7185}{24,79}=0,15mol\\ R+2HCl\rightarrow RCl_2+H_2\\ \Rightarrow\dfrac{3,6}{R}=0,15\\ \Rightarrow R=24g/mol,Mg\\ \Rightarrow Chọn.B\)
a, \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
b, \(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
Theo PT: \(n_{HCl}=2n_{H_2}=0,4\left(mol\right)\Rightarrow V_{HCl}=\dfrac{0,4}{2}=0,2\left(l\right)\)
\(n_{ZnCl_2}=n_{H_2}=0,2\left(mol\right)\Rightarrow m_{ZnCl_2}=0,2.136=27,2\left(g\right)\)
a) nCl2=7,28/22,4=0,325(mol)
=> mCl2=0,325.71=23,075(mol)
=> m(muối)= m(hh)+ mCl2= 10,45+23,075=33,525(g)
b) PTHH: 2 Al + 3 Cl2 -to-> 2 AlCl3
a__________1,5a(mol)
Cu + Cl2 -to-> CuCl2
b___b(mol)
Ta có hpt:
\(\left\{{}\begin{matrix}27a+64b=10,45\\1,5a+b=0,325\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,15\\b=0,1\end{matrix}\right.\)
=> mCu=0,1.64=6,4(g)
=>%mCu= (6,4/10,45).100=61,244%
=>%mAl=38,756%
\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\\ PTHH:Fe+2HCl\rightarrow FeCl_2+H_2\\ n_{H_2}=n_{FeCl_2}=n_{Fe}=0,1\left(mol\right);n_{HCl}=2.0,1=0,2\left(mol\right)\\ a,V_{H_2\left(đktc\right)}=0,1.22,4=2,24\left(l\right)\\ b,m_{HCl}=0,2.36,5=7,3\left(g\right)\\ m_{FeCl_2}=127.0,1=12,7\left(g\right)\)
Cái khí ở dạng phân tử nên là H2 chứ không phải H em nha!
Câu 2
\(a,n_{Fe}=0,3\left(mol\right)\\ 2Fe+3Cl_2\rightarrow2FeCl_3\)
0,3 0,45 (mol)
\(V=0,45.22,4=10,08\left(l\right)\)
b,Khối lượng muối thu được
\(m_{FeCl_2}=n.M=0,3.127=38,1\left(g\right)\)