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\(C_2H_2+2Br_2->C_2H_2Br_4\\ n_{hh}=\dfrac{3,36}{22,4}=0,15mol\\ n_{CH_4}=\dfrac{2,24}{22,4}=0,1mol\\ n_{C_2H_2}=0,05mol\\ n_{Br_2}=2.0,05=0,1mol\\ m_{Br_2}=0,1.160=16g\\ \%V_{CH_4}=\dfrac{0,1}{0,15}.100\%=66,67\%\\ \%V_{C_2H_2}=33,33\%\)
a) \(n_{C_2H_4Br_2}=\dfrac{18,8}{188}=0,1\left(mol\right)\)
PTHH: C2H4 + Br2 --> C2H4Br2
0,1<----0,1<---0,1
=> \(m_{Br_2}=0,1.160=16\left(g\right)\)
b)
\(\%V_{C_2H_4}=\dfrac{0,1.22,4}{4}.100\%=56\%\)
=> \(\%V_{CH_4}=100\%-56\%=44\%\)
c) \(n_{CH_4}=\dfrac{4.44\%}{22,4}=\dfrac{11}{140}\left(mol\right)\)
PTHH: CH4 + 2O2 --to--> CO2 + 2H2O
\(\dfrac{11}{140}\)-->\(\dfrac{11}{70}\)
C2H4 + 3O2 --to--> 2CO2 + 2H2O
0,1---->0,3
=> \(V_{O_2}=\left(\dfrac{11}{70}+0,3\right).22,4=10,24\left(l\right)\)
=> Vkk = 10,24.5 = 51,2 (l)
a.\(m_{dd.Br_2\left(tăng\right)}=m_{C_2H_2}=2,6g\)
\(n_{hh}=\dfrac{5,6}{22,4}=0,25mol\)
\(n_{C_2H_2}=\dfrac{2,6}{26}=0,1mol\)
\(\%V_{C_2H_2}=\dfrac{0,1}{0,25}.100=40\%\)
\(\%V_{CH_4}=100\%-40\%=60\%\)
b.\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
0,1 0,2 ( mol )
\(C_{M\left(dd.Br_2\right)}=\dfrac{0,2}{0,1}=2M\)
a)
$C_2H_2 + 2Br_2 \to C_2H_2Br_4$
b) $n_{Br_2} = \dfrac{40.20\%}{160} = 0,05(mol)$
Theo PTHH : $n_{C_2H_2Br_4} = n_{C_2H_2} = \dfrac{1}{2}n_{Br_2} = 0,025(mol)$
$m_{C_2H_2Br_4} = 0,025.346 = 8,65(gam)$
c) $\%V_{C_2H_2} = \dfrac{0,025}{0,5}.100\% = 5\%$
$\%V_{CH_4} = 100\% - 5\% = 95\%$
Ta có: \(n_{C_2H_4}+n_{C_2H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\left(1\right)\)
Mà: m dd tăng sau pư = mC2H4 + mC2H2
⇒ 4,9 = 28nC2H4 + 26nC2H2 (2)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{C_2H_4}=-0,15\\n_{C_2H_2}=0,35\end{matrix}\right.\)
Đến đây thì ra số mol âm, bạn xem lại đề nhé.
a, \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
Ta có: \(n_{C_2H_4}+n_{C_2H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\left(1\right)\)
Theo PT: \(n_{Br_2}=n_{C_2H_4}+2n_{C_2H_2}=\dfrac{48}{160}=0,3\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,2\left(mol\right)\\y=0,05\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,2.22,4}{5,6}.100\%=80\%\\\%V_{C_2H_2}=20\%\end{matrix}\right.\)
b, \(V_{ddBr_2}=\dfrac{0,3}{0,25}=1,2\left(M\right)\)
