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a, nBr2 = 8/160 = 0,05 (mol)
PTHH: C2H4 + Br2 -> C2H4Br2
Mol: 0,05 <--- 0,05 <--- 0,05
Vhh khí = 2,8/22,4 = 0,125 (mol)
%VC2H4 = 0,05/0,125 = 40%
%CH4 = 100% - 40% = 60%
b, nCH4 = 0,125 - 0,05 = 0,075 (mol)
PTHH: C2H4 + 3O2 -> (t°) 2CO2 + 2H2O
Mol: 0,05 ---> 0,15
CH4 + 2O2 -> (t°) CO2 + 2H2O
Mol: 0,075 ---> 0,15
Vkk = (0,15 + 0,15) . 5 . 22,4 = 33,6 (l)
a)
\(n_{Br_2}=\dfrac{8}{160}=0,05\left(mol\right)\)
PTHH: C2H4 + Br2 --> C2H4Br2
0,05<-0,05
=> \(n_{CH_4}=\dfrac{3,36}{22,4}-0,05=0,1\left(mol\right)\)
\(\%m_{CH_4}=\dfrac{0,1.16}{0,1.16+0,05.28}.100\%=53,33\%\)
\(\%m_{C_2H_4}=\dfrac{0,05.28}{0,1.16+0,05.28}.100\%=46,67\%\)
b)
PTHH: CH4 + 2O2 --to--> CO2 + 2H2O
0,1-->0,2
C2H4 + 3O2 --to--> 2CO2 + 2H2O
0,05--->0,15
=> \(V_{O_2}=\left(0,2+0,15\right).22,4=7,84\left(l\right)\)
PTHH: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
a) Ta có: \(n_{Br_2}=\dfrac{4}{160}=0,025\left(mol\right)=n_{C_2H_4}\)
\(\Rightarrow\%V_{C_2H_4}=\dfrac{0,025}{\dfrac{5,6}{22,4}}\cdot100\%=10\%\) \(\Rightarrow\%V_{CH_4}=90\%\)
b) Theo PTHH: \(n_{C_2H_4Br_2}=n_{Br_2}=0,025mol\)
\(\Rightarrow m_{C_2H_4Br_2}=0,025\cdot188=4,7\left(g\right)\)
c) Ta có: \(n_{CH_4}=\dfrac{1}{22,4}=\dfrac{5}{112}\left(mol\right)=n_{O_2}\)
\(\Rightarrow\left\{{}\begin{matrix}m_{CH_4}=\dfrac{5}{112}\cdot16\approx0,71\left(g\right)\\m_{O_2}=\dfrac{5}{112}\cdot32\approx1,43\left(g\right)\end{matrix}\right.\)
Vậy 1 lít Metan nhẹ hơn 1 lít Oxi
a.\(n_{Br_2}=\dfrac{48}{160}=0,3mol\)
\(n_{hh}=\dfrac{7,84}{22,4}=0,35mol\)
\(C_2B_2+2Br_2\rightarrow C_2H_2Br_4\)
0,15 0,3 ( mol )
\(\%V_{C_2H_2}=\dfrac{0,15}{0,35},100=42,85\%\)
\(\%V_{CH_4}=100\%-42,85\%=57,15\%\)
b.\(n_{CH_4}=0,35-0,15=0,2mol\)
\(CH_4+2O_2\rightarrow\left(t^o\right)CO_2+2H_2O\)
0,2 0,4 ( mol )
\(2C_2H_2+5O_2\rightarrow\left(t^o\right)4CO_2+2H_2O\)
0,15 0,15 ( mol )
\(m_{H_2O}=\left(0,4+0,15\right).18=9,9g\)
a, \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
Ta có: \(n_{C_2H_4}+n_{C_2H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\left(1\right)\)
Theo PT: \(n_{Br_2}=n_{C_2H_4}+2n_{C_2H_2}=\dfrac{48}{160}=0,3\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,2\left(mol\right)\\y=0,05\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,2.22,4}{5,6}.100\%=80\%\\\%V_{C_2H_2}=20\%\end{matrix}\right.\)
b, \(V_{ddBr_2}=\dfrac{0,3}{0,25}=1,2\left(M\right)\)
a) \(n_{Br_2\left(p\text{ư}\right)}=\dfrac{6,4}{160}=0,04\left(mol\right);n_{hh}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)
PTHH: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
0,04<--0,04
\(\Rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,04}{0,6}.100\%=6,67\%\\\%V_{CH_4}=100\%-6,67\%=93,33\%\end{matrix}\right.\)
b) \(n_{CH_4}=0,6-0,04=0,56\left(mol\right)\)
PTHH: \(CH_4+2O_2\xrightarrow[]{t^o}CO_2+2H_2O\)
0,56----------->0,56
\(C_2H_4+3O_2\xrightarrow[]{t^o}2CO_2+2H_2O\)
0,04----------->0,08
\(\Rightarrow V_{CO_2}=\left(0,08+0,56\right).22,4=14,336\left(l\right)\)
a) \(n_{C_2H_4Br_2}=\dfrac{18,8}{188}=0,1\left(mol\right)\)
PTHH: C2H4 + Br2 --> C2H4Br2
0,1<----0,1<---0,1
=> \(m_{Br_2}=0,1.160=16\left(g\right)\)
b)
\(\%V_{C_2H_4}=\dfrac{0,1.22,4}{4}.100\%=56\%\)
=> \(\%V_{CH_4}=100\%-56\%=44\%\)
c) \(n_{CH_4}=\dfrac{4.44\%}{22,4}=\dfrac{11}{140}\left(mol\right)\)
PTHH: CH4 + 2O2 --to--> CO2 + 2H2O
\(\dfrac{11}{140}\)-->\(\dfrac{11}{70}\)
C2H4 + 3O2 --to--> 2CO2 + 2H2O
0,1---->0,3
=> \(V_{O_2}=\left(\dfrac{11}{70}+0,3\right).22,4=10,24\left(l\right)\)
=> Vkk = 10,24.5 = 51,2 (l)