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a, \(PTHH:3Fe+2O_2\rightarrow Fe_3O_4\)
Theo PTHH : \(n_{Fe}=3n_{Fe3O4}=3.\dfrac{m}{M}=0,45\left(mol\right)\)
\(\Rightarrow m_{Fe}=25,2g\)
b, Theo PTHH : \(n_{O2}=n_{Fe3O4}=0,3\left(mol\right)\)
\(\Rightarrow V_{O2}=6,72\left(l\right)\)
c, PTHH : \(2KClO_3\rightarrow2KCl+3O_2\)
Theo PTHH : \(n_{KClO3}=\dfrac{2}{3}n_{O2}=0,25\left(mol\right)\)
\(\Rightarrow m_{KClo3}=30,625g\)
a)
PTHH: 3Fe + 2O2 ____\(t^o\)____> Fe3O4 (1)
b) Ta có: nFe = \(\dfrac{25.2}{56}=0.45\left(mol\right)\)
Theo (1): n\(O_2\)= \(\dfrac{2}{3}n_{Fe}=\dfrac{2}{3}0.45=0.3\left(mol\right)\)
=> \(V_{O_2\left(đktc\right)}=0.3\cdot22.4=6.72\left(l\right)\)
c) PTHH: 2KClO3 __\(t^o\)___> 2KCl + 3O2 (2)
-Muốn điều chế được lượng oxi dùng cho phản ứng trên thì \(n_{O_2\left(2\right)}=n_{O_2\left(1\right)}=0.3\left(mol\right)\)
Theo (2) \(n_{KClO_3}=\dfrac{2}{3}n_{O_2}=\dfrac{2}{3}0.3=0.2\left(mol\right)\)
=> \(m_{KClO_3}=0.2\cdot122.5=24.5\left(g\right)\)
\(n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right)\)
\(PTHH:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\\ Mol:0,4\rightarrow\dfrac{4}{15}\rightarrow\dfrac{2}{15}\)
\(\rightarrow\left\{{}\begin{matrix}V_{O_2}=\dfrac{4}{15}.22,4=\dfrac{448}{75}\left(l\right)\rightarrow V_{kk}=\dfrac{448}{75}.5=\dfrac{448}{15}\left(l\right)\\m_{Fe_3O_4}=\dfrac{2}{15}.232=\dfrac{464}{15}\left(g\right)\end{matrix}\right.\)
2KClO3 --to--> 2KCl + 3O2
\(\dfrac{8}{45}\) \(\dfrac{4}{15}\)
\(m_{KClO_3}=\dfrac{8}{45}.122,5=\dfrac{196}{9}\left(g\right)\)
a, \(n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right)\)
PTHH: 3Fe + 2O2 ---to---> Fe3O4
Mol: 0,4 \(\dfrac{0,8}{3}\) \(\dfrac{0,4}{3}\)
b, \(V_{O_2}=\dfrac{0,8}{3}.22,4=5,973\left(l\right)\)
c, \(V_{kk}=\dfrac{448}{75}.5=29,867\left(l\right)\)
d, \(m_{Fe_3O_4}=\dfrac{0,4}{3}.232=30,93\left(g\right)\)
e,
PTHH: 2KClO3 ---to---> 2KCl + 3O2
Mol: \(\dfrac{0,16}{9}\) \(\dfrac{0,8}{3}\)
\(m_{KClO_3}=\dfrac{0,16}{9}.122,5=2,178\left(g\right)\)
a)\(n_{Fe}=\dfrac{22,4}{56}=0,4mol\)
\(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
0,4 \(\dfrac{4}{15}\) \(\dfrac{2}{15}\)
\(V_{O_2}=\dfrac{4}{15}\cdot22,4=5,973l\)
b)\(2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
\(\dfrac{8}{45}\) \(\dfrac{4}{15}\)
\(m_{KClO_3}=\dfrac{8}{45}\cdot122,5=21,78g\)
a)
\(b)n_{Fe_3O_4} = \dfrac{6,96}{232} = 0,03(mol)\\ 3Fe + 2O_2 \xrightarrow{t^o}Fe_3O_4\\ n_{Fe} = 3n_{Fe_3O_4} = 0,09(mol)\\ m_{Fe} = 0,09.56 = 5,04(gam)\\ c) n_{O_2} = 2n_{Fe_3O_4} = 0,06(mol)\\ V_{O_2} = 0,06.22,4 = 1,344(lít)\\ d) 2KMnO_4 \xrightarrow{t^o} K_2MnO_4 + MnO_2 + O_2\\ n_{KMnO_4} = 2n_{O_2} = 0,12(mol)\\ m_{KMnO_4} = 0,12.158 = 18,96(gam)\)
\(n_{Fe_3O_4}=\dfrac{6.96}{232}=0.03\left(mol\right)\)
\(3Fe+2O_2\underrightarrow{t^0}Fe_2O_3\)
\(0.09.....0.06.......0.03\)
\(m_{Fe}=0.09\cdot56=5.04\left(g\right)\)
\(V_{O_2}=0.06\cdot22.4=1.344\left(l\right)\)
\(2KMnO_4\underrightarrow{t^0}K_2MnO_4+MnO_2+O_2\)
\(0.12...............................................0.06\)
\(m_{KMnO_4}=0.12\cdot158=18.96\left(g\right)\)
n Fe3O4=\(\dfrac{13,92}{232}\)=0,06 mol
3Fe + 2O2 -to--> Fe3O4
0,18------0,12-------0,06
=>m Fe=0,18.56=10,08g
=>VO2=0,12.22,4=2,688l
2KMnO4-to>K2MnO4+MnO2+O2
0,24-------------------------------------0,12
=>m KMnO4=0,24.158=37,92g
nFe3O4 = 13,92 : 160= 0,087 (mol)
pthh : 3Fe + 2O2 -t--> Fe3O4
0,087->0,058-->0,029 (mol)
=> mFe = 0,029 . 56 = 1,624 (g)
=> VO2 = 0,058 . 22,4 = 1,2992 (L)
pthh : 2KMnO4 -t--> K2MnO4 + MnO2 + O2
0,116<------------------------------0,058 (mol)
=> mKMnO4 = 0,116 . 158 = 18,328 (g)
\(n_{Fe}=\dfrac{126}{56}=2,25\left(mol\right)\\
pthh:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
2,25 1,5
=> \(V_{O_2}=1,5.22,4=33,6\left(L\right)\)
\(PTHH:2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
1 1,5
=> \(m_{KClO3}=122,5\left(g\right)\)
a, \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
b, \(n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{2}{3}n_{Fe}=0,2\left(mol\right)\Rightarrow V_{O_2}=0,2.22,4=4,48\left(l\right)\)
\(n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=0,1\left(mol\right)\Rightarrow m_{Fe_3O_4}=0,1.232=23,2\left(g\right)\)
c, \(n_{CuO}=\dfrac{16}{80}=0,2\left(mol\right)\)
PT: \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
Xét tỉ lệ: \(\dfrac{0,2}{1}< \dfrac{0,3}{1}\), ta được H2 dư.
Theo PT: \(n_{Cu}=n_{CuO}=0,2\left(mol\right)\Rightarrow m_{Cu}=0,2.64=12,8\left(g\right)\)
