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\(n_{SO_3}=\dfrac{8}{80}=0.1\left(mol\right)\)
\(SO_3+H_2O\rightarrow H_2SO_4\)
\(0.1......................0.1\)
\(C_{M_{H_2SO_4}}=\dfrac{0.1}{0.5}=0.2\left(M\right)\)
\(n_{CuO}=\dfrac{10}{80}=0.125\left(mol\right)\)
\(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)
\(0.1...........0.1\)
\(m_{CuO\left(dư\right)}=\left(0.125-0.1\right)\cdot80=2\left(g\right)\)
a)
\(SO_3 + H_2O \to H_2SO_4\)
Theo PTHH : \(n_{H_2SO_4} = n_{SO_2} = \dfrac{8}{80} = 0,1(mol)\)
\(\Rightarrow C\%_{H_2SO_4} = \dfrac{0,1.98}{200}.100\% = 4,9\%\)
b)
\(2NaOH + H_2SO_4 \to Na_2SO_4 + 2H_2O\)
Theo PTHH : \(n_{NaOH} = 2n_{H_2SO_4} = 0,2(mol)\\ \Rightarrow m_{dd\ NaOH} = \dfrac{0,2.40}{4\%} = 200(gam)\)
a. PTHH: 2Al(OH)3 + 3H2SO4 ---> Al2(SO4)3 + 6H2O
b. Ta có: \(n_{Al\left(OH\right)_3}=\dfrac{58,5}{78}=0,75\left(mol\right)\)
\(n_{H_2SO_4}=\dfrac{49}{98}=0,5\left(mol\right)\)
Ta thấy: \(\dfrac{0,75}{2}>\dfrac{0,5}{3}\)
Vậy \(Al\left(OH\right)_3\) dư.
\(m_{dư}=0,75.78-98.0,5=9,5\left(g\right)\)
c. Theo PT: \(n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{3}.n_{H_2SO_4}=\dfrac{1}{3}.0,5=\dfrac{1}{6}\left(mol\right)\)
=> \(m_{Al_2\left(SO_4\right)_3}=\dfrac{1}{6}.342=57\left(g\right)\)
a, \(n_{Al\left(OH\right)_3}=\dfrac{58,5}{78}=0,75\left(mol\right);n_{H_2SO_4}=\dfrac{49}{98}=0,5\left(mol\right)\)
PTHH: 2Al(OH)3 + 3H2SO4 → Al2(SO4)3 + 6H2O
Mol: \(\dfrac{1}{3}\) 0,5 \(\dfrac{1}{6}\)
b, Ta có: \(\dfrac{0,75}{2}>\dfrac{0,5}{3}\) ⇒ Al(OH)3 dư, H2SO4 hết
⇒ \(m_{Al\left(OH\right)_3}=\left(0,75-\dfrac{1}{3}\right).78=32,5\left(g\right)\)
c, \(m_{Al_2\left(SO_4\right)_3}=\dfrac{1}{6}.342=57\left(g\right)\)
Ta có: \(n_{Al\left(OH\right)_3}=\dfrac{58,5}{78}=0,75\left(mol\right)\)
a. PTHH: 2Al(OH)3 + 3H2SO4 ---> Al2(SO4)3 + 6H2O
b. Không có chất dư (hoặc có thể bn cho sai 49(g) dung dịch là 49(g) H2SO4)
c. Theo PT: \(n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{2}.n_{Al\left(OH\right)_3}=\dfrac{1}{2}.0,75=0,375\left(mol\right)\)
=> \(m_{Al_2\left(SO_4\right)_3}=0,375.342=128,25\left(g\right)\)
\(n_{NaOH}=\dfrac{200.5\%}{100\%.40}=0,25(mol)\\ n_{HCl}=\dfrac{36,5.20\%}{100\%.36,5}=0,2(mol)\\ a,NaOH+HCl\to NaCl+H_2O\)
Vì \(\dfrac{n_{NaOH}}{1}>\dfrac{n_{HCl}}{1}\) nên \(NaOH\) dư
\(b,n_{NaOH(dư)}=0,25-0,2=0,05(mol);n_{NaCl}=0,2(mol)\\ \Rightarrow m_{\text{dd sau p/ứ}}=0,2.58,5+0,05.40=13,7(g)\\ c,m_{NaCl}=0,2.58,5=11,7(g)\\ d,n_{H_2}=0,2(mol)\\ \Rightarrow \begin{cases} C\%_{NaOH}=\dfrac{0,05.40}{36,5+200-0,2.2}.100\%=0,85\%\\ C\%_{NaCl}=\dfrac{11,7}{36,5+200-0,2.2}.100\%=4,96\% \end{cases}\)
a) PTHH: \(MgO+2HCl\rightarrow MgCl_2+H_2O\)
b) Ta có: \(n_{MgO}=\dfrac{8}{40}=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{MgCl_2}=0,2\left(mol\right)\\n_{HCl}=0,4\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{MgCl_2}=0,2\cdot95=19\left(g\right)\\C\%_{HCl}=\dfrac{0,4\cdot36,5}{200}\cdot100\%=7,3\%\end{matrix}\right.\)
Mặt khác: \(m_{dd\left(sau.p/ứ\right)}=m_{MgO}+m_{ddHCl}=208\left(g\right)\)
\(\Rightarrow C\%_{MgCl_2}=\dfrac{19}{208}\cdot100\%\approx9,13\%\)
c) PTHH: \(MgCl_2+2NaOH\rightarrow2NaCl+Mg\left(OH\right)_2\downarrow\)
Ta có: \(\left\{{}\begin{matrix}n_{MgCl_2}=0,2\left(mol\right)\\n_{NaOH}=\dfrac{200\cdot4\%}{40}=0,2\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,2}{1}>\dfrac{0,2}{2}\) \(\Rightarrow\) NaOH p/ứ hết, MgCl2 còn dư
\(\Rightarrow\left\{{}\begin{matrix}n_{NaCl}=0,2\left(mol\right)\\n_{Mg\left(OH\right)_2}=0,1\left(mol\right)=n_{MgCl_2\left(dư\right)}\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{NaCl}=0,2\cdot58,5=11,7\left(g\right)\\m_{MgCl_2\left(dư\right)}=9,5\left(g\right)\\m_{Mg\left(OH\right)_2}=0,1\cdot58=5,8\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd\left(sau.p/ứ\right)}=m_{ddA}+m_{ddNaOH}-m_{Mg\left(OH\right)_2}=402,2\left(g\right)\)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{NaCl}=\dfrac{11,7}{402,2}\cdot100\%\approx2,91\%\\C\%_{MgCl_2\left(dư\right)}=\dfrac{9,5}{402,2}\cdot100\%\approx2,36\%\end{matrix}\right.\)
Theo gt ta có: $n_{MgO}=0,2(mol)$
a, $MgO+2HCl\rightarrow MgCl_2+H_2O$
b, Ta có: $n_{HCl}=0,4(mol)\Rightarrow x=7,3$
Bảo toàn khối lượng ta có: $m_{ddA}=208(g)$
$\Rightarrow \%C_{MgCl_2}=9,13\%$
c, Ta có: $n_{NaOH}=0,2(mol)$
$\Rightarrow n_{Mg(OH)_2}=0,1(mol)$
Bảo toàn khối lượng ta có: $m_{ddB}=208+200-0,1.58=402,2(g)$
$\Rightarrow \%C_{MgCl_2}=2,36\%$
\(a.HCl+NaOH\rightarrow NaCl+H_2O\)
PỨ trung hoà
\(b,n_{NaOH}=0,1.1=0,1mol\\ n_{NaCl}=n_{NaOH}=n_{HCl}0,1mol\\ m=m_{HCl}=0,1.36,5=3,65g\\ c,m_{NaCl}=0,1.58,5=5,85g\\ d,n_{HCl}=\dfrac{73.10}{100.36,5}=0,2mol\\ \Rightarrow\dfrac{0,1}{1}< \dfrac{0,2}{1}\Rightarrow HCl.dư\\ n_{HCl,pứ}=n_{NaOH}=0,1mol\\ m_{HCl,dư}=\left(0,2-0,1\right).36,5=3,65g\)
\(a.Zn+2HCl\rightarrow ZnCl_2+H_2\\ n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right);n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\\ LTL:\dfrac{0,2}{1}< \dfrac{0,5}{2}\Rightarrow HCldư\\ n_{HCl\left(pứ\right)}=2n_{Zn}=0,4\left(mol\right)\\\Rightarrow m_{HCl\left(dư\right)}=\left(0,5-0,4\right).36,5=3,65\left(g\right)\\ b.n_{ZnCl_2}=n_{Zn}=0,2\left(mol\right)\\ \Rightarrow m_{ZnCl_2}=0,2.136=27,2\left(g\right)\\ c.n_{H_2}=n_{Zn}=0,2\left(mol\right)\\ \Rightarrow V_{H_2}=0,2.22,4,=4,48\left(l\right)\\ d.3H_2+Fe_2O_3-^{t^o}\rightarrow2Fe+3H_2O \\ n_{Fe_2O_3}=\dfrac{19,2}{160}=0,12\left(mol\right)\\ LTL:\dfrac{0,2}{3}< \dfrac{0,12}{1}\Rightarrow Fe_2O_3dưsauphảnứng\\ \Rightarrow n_{Fe}=\dfrac{2}{3}n_{H_2}=\dfrac{2}{15}\left(mol\right)\\ \Rightarrow m_{Fe}=\dfrac{2}{15}.56=7,467\left(g\right)\)
a) n\(Zn\)=\(\dfrac{m}{M}\)=\(\dfrac{13}{65}\)=0,2(mol)
n\(HCl\)=\(\dfrac{m}{M}\)=\(\dfrac{18,25}{36,5}=\)0,5(mol)
PTHH : Zn + 2HCl->ZnCl\(2\) + H\(2\)
0,2 0,5
Lập tỉ lệ mol : \(^{\dfrac{0,2}{1}}\)<\(\dfrac{0,5}{2}\)
n\(Zn\) hết , n\(HCl\) dư
-->Tính theo số mol hết
Zn + 2HCl->ZnCl\(2\) + H\(2\)
0,2 -> 0,4 0,2 0,2
n\(HCl\) dư= n\(HCl\)(đề) - n\(HCl\)(pt)= 0,5 - 0,4 = 0,1(mol)
m\(HCl\) dư= 0,1.36,5 = 3,65(g)
b) m\(ZnCl2\) = n.M= 0,2.136= 27,2 (g)
c)V\(H2\)=n.22,4=0,2.22,4=4,48(l)
d) n\(Fe\)\(2\)O\(3\)=\(\dfrac{m}{M}\)=\(\dfrac{19,2}{160}\)=0,12 (mol)
3H2 +Fe2O3 → 2Fe + 3H2O
0,2 0,12
Lập tỉ lệ mol: \(\dfrac{0,2}{3}\)<\(\dfrac{0,12}{1}\)
nH2 hết .Tính theo số mol hết
\(HCl\)
3H2 +Fe2O3 → 2Fe + 3H2O
0,2-> 0,2
m\(Fe\)=n.M= 0,2.56= 11,2(g)
a) \(2Al+6HCl\rightarrow2AlCl_3+3H_2\left(1\right)\\ Fe+2HCl\rightarrow FeCl_2+H_2\left(2\right)\\ 2Al+2NaOH+2H_2O\rightarrow2NaAlO_2+3H_2\)
Cho hỗn hợp tác dụng với NaOH, chất rắn không tan là Fe
=> mFe= 1,12 (g) \(\Rightarrow n_{Fe}=0,02\left(mol\right)\)
Ta có: \(n_{H_2\left(2\right)}=n_{Fe}=0,02\left(mol\right)\)
=> \(n_{H_2\left(1\right)}=\Sigma n_{H_2}-n_{H_2\left(2\right)}=0,065-0,02=0,045\left(mol\right)\)
\(\Rightarrow n_{Al}=\dfrac{2}{3}n_{H_2\left(1\right)}=0,03\left(mol\right)\)
\(\Rightarrow m_{Al}=0,03.27=0,81\left(g\right)\)
\(\Rightarrow\%m_{Al}=41,97\%,\%m_{Fe}=58,03\%\)
b) \(m_{FeCl_2}=0,02.127=2,54\left(g\right)\\ m_{AlCl_3}=0,03.133,5=4,005\left(g\right)\)
nSO3 = \(\frac{1,2}{80}\) = 0,015 (mol)
SO3 + H2O \(\rightarrow\) H2SO4
0,015 -----------> 0,015 (mol)
a) C%(H2SO4) = \(\frac{0,015.98}{100}\) . 100% = 1,47%
b) nMgO = \(\frac{5}{40}\) = 0,125 (mol)
PT: MgO + H2SO4 \(\rightarrow\) MgSO4 + H2O
bđ 0,125 .... 0,015 (mol)
pư 0,015\(\leftarrow\) 0,015 \(\rightarrow\) 0,015 (mol)
spư 0,1125 .... 0 .............. 0,015 (mol)
Sau pư, MgO dư
mMgO = 0,1125 . 40 = 4,5 (g)
c) m dd spư = 5 + 100 - 4,5 = 100,5 (g)
C% (MgSO4)= \(\frac{0,015.120}{100,5}\) . 100% = 1,8%
thanks bạn nha