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a)
$n_{Al} = 0,3(mol)$
$2Al + 3H_2SO_4 \to Al_2(SO_4)_3 + 3H_2$
Theo PTHH :
$n_{H_2SO_4} = \dfrac{3}{2}n_{Al} = 0,45(mol)$
$m_{dd\ H_2SO_4} = \dfrac{0,45.98}{12,25\%} = 360(gam)$
b)
$n_{H_2} = n_{H_2SO_4} = 0,45(mol)$
$V_{H_2} = 0,45.22,4 = 10,08(lít)$
c)
$n_{Al_2(SO_4)_3} = 0,15(mol)$
$m_{dd\ sau\ pư} = 8,1 + 360 - 0,45.2 = 367,2(gam)$
$C\%_{Al_2(SO_4)_3} = \dfrac{0,15.342}{367,2}.100\% = 14\%$
\(a,2Al+3H_2SO_4\to Al_2(SO_4)_3+3H_2\\ b,n_{H_2}=\dfrac{6,72}{22,4}=0,3(mol)\\ \Rightarrow n_{Al}=0,2(mol)\\ \Rightarrow m_{Al}=0,2.27=5,4(g)\\ c,n_{H_2SO_4}=0,3(mol)\\ \Rightarrow m_{dd_{H_2SO_4}}=\dfrac{0,3.98}{9,8\%}=300(g)\\ d,n_{Al_2(SO_4)_3}=0,1(mol)\\ \Rightarrow C\%_{Al_2(SO_4)_3}=\dfrac{0,1.342}{5,4+300-0,3.2}.100\%=11,22\%\)
a, \(Na_2SO_3+H_2SO_4\rightarrow Na_2SO_4+SO_2+H_2O\)
\(K_2SO_3+H_2SO_4\rightarrow K_2SO_4+SO_2+H_2O\)
Ta có: \(n_{SO_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
Theo PT: \(n_{H_2SO_4}=n_{SO_2}=0,3\left(mol\right)\)
\(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,3.98}{20\%}=147\left(g\right)\)
b, Ta có: 126nNa2SO3 + 158nK2SO3 = 44,2 (1)
Theo PT: \(n_{SO_2}=n_{Na_2SO_3}+n_{K_2SO_3}=0,3\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{Na_2SO_3}=0,1\left(mol\right)\\n_{K_2SO_3}=0,2\left(mol\right)\end{matrix}\right.\)
Có: m dd sau pư = 44,2 + 147 - 0,3.64 = 172 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{Na_2SO_3}=\dfrac{0,1.126}{172}.100\%\approx7,33\%\\C\%_{K_2SO_3}=\dfrac{0,2.158}{172}.100\%\approx18,37\%\end{matrix}\right.\)
c, \(n_{Ba\left(OH\right)_2}=0,5.1=0,5\left(mol\right)\)
\(\Rightarrow\dfrac{n_{SO_2}}{n_{Ba\left(OH\right)_2}}=0,6< 1\) → Pư tạo BaSO3.
PT: \(SO_2+Ba\left(OH\right)_2\rightarrow BaSO_3+H_2O\)
\(n_{BaSO_3}=n_{SO_2}=0,3\left(mol\right)\Rightarrow m_{BaSO_3}=0,3.217=65,1\left(g\right)\)
\(n_{H_2}=\dfrac{3,36}{22,4}0,15(mol)\\ a,PTHH:Fe+H_2SO_4\to FeSO_4+H_2\\ b,n_{Fe}=n_{H_2}=0,15(mol)\\ \Rightarrow \%_{Fe}=\dfrac{0,15.56}{14,8}.100\%=56,76\%\\ \Rightarrow \%_{Cu}=100\%-56,76\%=43,24\%\\ c,n_{H_2SO_4}=0,15(mol)\\ \Rightarrow m_{dd_{H_2SO_4}}=\dfrac{0,15.98}{20\%}=73,5(g)\\ \Rightarrow V_{dd_{H_2SO_4}}=\dfrac{73,5}{1,4}=52,5(l)\)
Tham khảo
nSO2=3,3622,4=0,15(mol)nSO2=3,3622,4=0,15(mol)
Pt: 2Al+6H2SO4(đ)to→Al2(SO4)3+3SO2+6H2O2Al+6H2SO4(đ)to→Al2(SO4)3+3SO2+6H2O
0,1mol ←← ------------------------------------- 0,15mol
mAl=0,1.27=2,7(g)
\(n_{SO2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
a) \(2Al+6H_2SO_{4đặc}\underrightarrow{t^o}Al_2\left(SO_4\right)_3+3SO_2+6H_2O|\)
2 6 1 3 6
0,1 0,15
b) \(n_{Al}=\dfrac{0,15.2}{3}=0,1\left(mol\right)\)
⇒ \(m_{Al}=0,1.27=2,7\left(g\right)\)
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