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BTKL: \(m_{S+C}+m_{O_2}=m_{SO_2+CO_2}\)
\(\Rightarrow m_{O_2}=15,2-5,6=9,6g\)
\(\Rightarrow n_{O_2}=0,3mol\)
\(\Rightarrow V_{O_2}=0,3\cdot22,4=6,72l\)
\(\Rightarrow V_{kk}=5\cdot6,72=33,6l\)
\(n_S=\dfrac{6.4}{32}=0,2\left(mol\right)\)
PTHH : S + O2 ---to---> SO2
0,2 0,2
\(V_{O_2}=0,2.22,4=4,48\left(l\right)\)
\(V_{kk}=4,48.5=22,4\left(l\right)\)
Gọi nC = a (mol); nS = b (mol)
12a + 32b = 12 (1)
PTHH:
C + O2 -> (t°) CO2
a ---> a ---> a
S + O2 -> (t°) SO2
b ---> b ---> b
44a + 64b = 28 (2)
Từ (1)(2) => a = 0,2 (mol); b = 0,3 (mol)
nO2 = 0,2 + 0,3 = 0,5 (mol)
VO2 = 0,5 . 22,4 = 11,2 (l)
\(n_{SO_2}=\dfrac{V_{SO_2\left(ĐKTC\right)}}{22,4}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
PTHH: \(S+O_2\underrightarrow{t^o}SO_2\)
...........1.........1........1......
...........0,3......0,3......0,3.....
a. \(m_S=n_S\cdot M_S=0,3\cdot32=9,6\left(g\right)\)
b. \(V_{O_2\left(ĐKTC\right)}=n_{O_2}\cdot22,4=0,3\cdot22,4=6,72\left(l\right)\)
\(V_{kk\left(ĐKTC\right)}=V_{O_2\left(ĐKTC\right)}\cdot5=6,72\cdot5=33,6\left(l\right)\)
\(n_{SO_2}=\dfrac{6.72}{22.4}=0.3\left(mol\right)\)
\(S+O_2\underrightarrow{t^0}SO_2\)
\(0.3..0.3...0.3\)
\(m_S=0.3\cdot32=9.6\left(g\right)\)
\(V_{kk}=5V_{O_2}=5\cdot22.4\cdot0.3=33.6\left(l\right)\)
\(n_{O_2}=\dfrac{44,8}{22,4}.20\%=0,4(mol)\)
Bảo toàn NT (O): \(n_{O_2}=n_{CO_2}=\dfrac{1}{2}n_{H_2O}\)
\(\Rightarrow n_{CO_2}=0,4(mol);n_{H_2O}=0,8(mol)\\ \Rightarrow V_{CO_2}=0,4.22,4=8,96(g);m_{H_2O}=0,8.18=14,4(g)\)
\(n_{O_2}=\dfrac{41,44}{22,4}.20\%=0,37(mol)\\ n_{H_2O}=\dfrac{4,68}{18}=0,26(mol)\)
Bảo toàn nguyên tố (O): \(n_{CO_2}=n_{O_2}=0,37(mol)\)
\(\Rightarrow V_{CO_2}=0,37.22,4=8,288(l)\)
BTKL: \(m_{hh}=m_{CO_2}+m_{H_2O}-m_{O_2}=0,37.44+4,68-0,37.32=9,12(g)\)
\(n_S=\dfrac{3.2}{32}=0.1\left(mol\right)\)
\(n_{O_2}=\dfrac{1.12}{22.4}=0.05\left(mol\right)\)
\(S+O_2\underrightarrow{t^0}SO_2\)
\(0.05.0.05...0.05\)
\(\Rightarrow Sdư\)
\(V_{SO_2}=0.05\cdot22.4=1.12\left(l\right)\)
\(b.\)
\(S+O_2\underrightarrow{t^0}SO_2\)
\(0.1..0.1\)
\(V_{kk}=5V_{O_2}=5\cdot0.1\cdot22.4=11.2\left(l\right)\)
a, PT: \(S+O_2\underrightarrow{t^o}SO_2\)
Ta có: \(n_S=\dfrac{3,2}{32}=0,1\left(mol\right)\)
\(n_{O_2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,1}{1}>\dfrac{0,05}{1}\), ta được S dư.
Theo PT: \(n_{SO_2}=n_{O_2}=0,05\left(mol\right)\) \(\Rightarrow V_{SO_2}=0,05.22,4=1,12\left(l\right)\)
b, Theo PT: \(n_{O_2}=n_S=0,1\left(mol\right)\)
\(\Rightarrow V_{O_2}=0,1.22,4=2,24\left(l\right)\)
\(\Rightarrow V_{kk}=2,24.5=11,2\left(l\right)\)
S + O2 \(\xrightarrow[]{t^o}\) SO2
nS = 1,6/32 = 0,05 mol
Theo pt: nO2 = nS = 0,05 mol
=> VO2 = 0,05.22,4 = 1,12 lít
PTHH: \(S+O_2\xrightarrow[]{t^o}SO_2\)
Theo PTHH: \(V_{O_2}=22,4\cdot20\%=4,48\left(l\right)=V_{SO_2}\)
\(\Rightarrow n_{O_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)=n_S\) \(\Rightarrow m_S=0,2\cdot32=6,4\left(g\right)\)