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Sửa lại câu c .
\(n_{H_2SO_4}=\dfrac{49.40}{100}:98=0,2\left(mol\right)\)
\(PTHH:\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\uparrow\)
trc p/u : 0,3 0,2
p/u : 0,2 0,2 0,2 0,2
sau : 0,1 0 0,2 0,2
-> Fe dư
\(m_{ddFeSO_4}=0,3.56+49-0,4=65,4\left(g\right)\) ( ĐLBTKL )
\(m_{FeSO_4}=0,2.152=30,4\left(g\right)\)
\(C\%=\dfrac{30,4}{65,4}.100\%\approx46,48\%\)
PTHH :
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\uparrow\)
0,3 0,3 0,3 0,3
\(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
\(a,m_{Fe}=0,3.56=16,8\left(g\right)\)
\(b,C_M=\dfrac{n}{V}=\dfrac{0,3}{0,2}=1,5M\)
\(c,n_{H_2SO_4}=\dfrac{\dfrac{49.40}{100}}{98}=0,2\left(mol\right)\)
\(\rightarrow n_{FeSO_4}=n_{H_2SO_4}=0,2\left(mol\right)\)
\(m_{FeSO_4}=0,2.152=30,4\left(g\right)\)
\(m_{ddFeSO_4}=49+\left(0,2.56\right)-0,2.2=59,8\left(g\right)\)( định luật bảo toàn khối lượng )
\(C\%=\dfrac{30,4}{59,8}.100\%\approx50,84\%\)
\(n_{Zn}=\dfrac{m}{M}=\dfrac{13}{65}=0,2\left(mol\right)\)
\(PTHH:Zn+2HCl\rightarrow ZnCl_2+H_2\)
1 2 1 1
0,2 0,4 0,2 0,2 (mol)
\(a)V_{H_2}=n\cdot22,4=0,2\cdot22,4=4,48\left(l\right)\)
\(b)m_{ZnCl_2}=n\cdot M=0,2\cdot\left(65+35,5\cdot2\right)=27,2\left(g\right)\)
\(c)400ml=0,4l\\ C_{M_{HCl}}=\dfrac{n}{V_{dd}}=\dfrac{0,4}{0,4}=1M.\)
a) PTHH:
Zn + 2HCl -> ZnCl2 + H2
0,2 0,4 0,2 0,2
nZn = 13 : 65 = 0,2 (mol)
VH2 = 0,2 . 22,4 = 4,48 (l)
b) mZnCl2 = 0,2 . 201 = 40,2 (g)
c) CM HCl = 0,4 : 0,4 = 1 (M)
nH2 = 4.48/22.4 = 0.2 (mol)
Zn + 2HCl => ZnCl2 + H2
0.2......0.4.....................0.2
mZn = 65*0.2 = 13 (g)
mHCl = 0.4*36.5 = 14.6 (g)
C%HCl = 14.6*100%/200 = 7.3%
a) \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
\(n_{H_2}=\dfrac{V_{H_2}}{24,79}=\dfrac{4,958}{24,79}=0,2\left(mol\right)\)
Theo PTHH: \(n_{Zn}=n_{H_2}=0,2\left(mol\right)\)
\(\Rightarrow m_{Zn}=n_{Zn}.M_{Zn}=0,2.65=13\left(g\right)\)
b) Theo PTHH: \(n_{ZnSO_4}=n_{H_2}=0,2\left(mol\right)\)
\(m_{ZnSO_4}=n_{ZnSO_4}.M_{ZnSO_4}=0,2.161=32,2\left(g\right)\)
\(m_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\\
m_{H_2SO_4}=200.12,25\%=24,5g\\
n_{H_2SO_4}=\dfrac{24,5}{98}=0,25\\
pthh:Fe+H_2SO_4\rightarrow FeSO_4+H_2\uparrow\\
LTL:0,2< 0,25=>H_2SO_4\left(d\text{ư}\right)Fe\left(h\text{ết}\right)\)
\(n_{H_2}=n_{Fe}=0,2\left(mol\right)\\
V_{H_2}=0,2.22,4=4,48l\)
\(C\%=\dfrac{11,2}{24,5}.100\%=45,7\%\)
Ta có: \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
Theo PT: \(n_{Zn}=n_{H_2}=0,3\left(mol\right)\Rightarrow m_{Zn}=0,3.65=19,5\left(g\right)\)
⇒ m tạp chất = 26 - 19,5 = 6,5 (g)
Ta có: \(n_{H_2}=\dfrac{4,958}{24,79}=0,2\left(mol\right)\)
PT: \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
___________0,2_____________0,2 (mol)
\(\Rightarrow m_{H_2SO_4}=n_{H_2}=0,2\left(mol\right)\)
\(\Rightarrow C\%_{H_2SO_4}=\dfrac{0,2.98}{200}.100\%=9,8\%\)