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\(\text{Đ}\text{ặt}:A\\ A+HCl\rightarrow ACl+H_2\\ n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\\ n_A=n_{ACl_2}=2.n_{H_2}=0,1.2=0,2\left(mol\right)\\ M_{ACl}=\dfrac{11,7}{0,2}=58,5\left(\dfrac{g}{mol}\right)\\ M\text{à}:M_{ACl}=M_A+35,5\\ \Rightarrow M_A=23\left(\dfrac{g}{mol}\right)\\ \Rightarrow A:Natri\left(Na\right)\\ a=23.0,2=4,6\left(g\right)\)
nH2=2,24/22,4=0,1(mol)
2M+2HCl→2MCl+H2
0,2 ← 0,2 ← 0,1
Có 0,2 .(M+35,5)=11,7(gam)
⇒ M=23 ⇒M là Na
mNa=23. 0,2= 4,6 (gam)
Gọi kim loại cần tìm là A
a) PTHH: \(A+H_2O\rightarrow AOH+\dfrac{1}{2}H_2\uparrow\)
\(AOH+HCl\rightarrow ACl+H_2O\)
b) Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\) \(\Rightarrow n_A=0,2mol\)
\(\Rightarrow M_A=\dfrac{7,8}{0,2}=39\) \(\Rightarrow\) Kim loại cần tìm là Kali
b) Ta có: \(\left\{{}\begin{matrix}n_{KCl}=0,2mol\\n_{HCl\left(pư\right)}=0,2mol\Rightarrow n_{HCl\left(dư\right)}=0,2\cdot20\%=0,04\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{KCl}=0,2\cdot74,5=14,9\left(g\right)\\m_{HCl\left(dư\right)}=0,04\cdot36,5=1,46\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{H_2}=2\cdot0,1=0,2\left(g\right)\)
\(\Rightarrow m_{dd}=m_K+m_{ddHCl}-m_{H_2}=7,8+\dfrac{0,24\cdot36,5}{10\%}-0,2=95,2\left(g\right)\)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{KCl}=\dfrac{14,9}{95,2}\cdot100\%\approx15,65\%\\C\%_{HCl\left(dư\right)}=\dfrac{1,46}{95,2}\cdot100\%\approx1,53\%\end{matrix}\right.\)
\(n_{H_2}=\dfrac{4.48}{22.4}=0.2\left(mol\right)\)
\(M+2H_2O\rightarrow M\left(OH\right)_2+H_2\)
\(0.2........................................0.2\)
\(M_M=\dfrac{8}{0.2}=40\left(\dfrac{g}{mol}\right)\)
\(M:Ca\left(Canxi\right)\)
\(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PTHH: A + 2H2O --> A(OH)2 + H2
_____0,2<--------------------------0,2
=> \(M_A=\dfrac{8}{0,2}=40\left(g/mol\right)=>Ca\)
\(Đặt.kim.loại.kiềm:A\\ 2A+2HCl\rightarrow2ACl+H_2\\ m_{muối}-m_{kl}=m_{Cl^-}\\ \Leftrightarrow m_{Cl^-}=7,45-3,9=3,55\left(g\right)\\ \Rightarrow n_{HCl}=n_{Cl^-}=\dfrac{3,55}{35,5}=0,1\left(mol\right)\\ \Rightarrow n_A=n_{ACl}=n_{HCl}=0,1\left(mol\right)\\ a,M_A=\dfrac{3,9}{0,1}=39\left(\dfrac{g}{mol}\right)\\ \Rightarrow A\left(I\right):Kali\left(K=39\right)\\ b,n_{H_2}=\dfrac{n_{HCl}}{2}=\dfrac{0,1}{2}=0,05\left(mol\right)\\ \Rightarrow V_{H_2\left(đktc\right)}=0,05.22,4=1,12\left(l\right)\\ c,m_{ddHCl}=\dfrac{0,1.36,5.100}{31,7}=\dfrac{3650}{317}\left(g\right)\\ \Rightarrow V_{ddHCl}=\dfrac{\dfrac{3650}{317}}{1,15}\approx10,012\left(g\right)\)
\(n_{H_2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\\ KL:M\\ M+2HCl\rightarrow MCl_2+H_2\\ n_{MCl_2}=n_M=n_{H_2}=0,05\left(mol\right)\\ M_{MCl_2}=\dfrac{4,75}{0,05}=95\left(\dfrac{g}{mol}\right)\\ M\text{à}:M_{MCl_2}=M_M+71\left(\dfrac{g}{mol}\right)\\ \Rightarrow M_M+71=95\\ \Leftrightarrow M_M=24\left(\dfrac{g}{mol}\right)\\ \Rightarrow M\left(II\right):Magie\left(Mg=24\right)\\ a=24.0,05=1,2\left(g\right)\)
Ta có: \(n_{H_2}=\dfrac{2,479}{24,79}=0,1\left(mol\right)\)
Gọi KLK cần tìm là A.
PT: \(2A+2H_2O\rightarrow2AOH+H_2\)
Theo PT: \(n_A=2n_{H_2}=0,2\left(mol\right)\)
\(\Rightarrow M_A=\dfrac{7,8}{0,2}=39\left(g/mol\right)\)
Vậy: Kim loại kiềm đó là Kali.
Bạn tự làm phần tính chất hóa học nhé.