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\(Đặt:\left\{{}\begin{matrix}Fe:x\left(mol\right)\\Zn:y\left(mol\right)\end{matrix}\right.\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ Zn+2HCl\rightarrow ZnCl_2+H_2\\ Tacó:\left\{{}\begin{matrix}56x+65y=5,3\\x+y=0,25\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}x=1,2\\y=-0,97\end{matrix}\right.\left(vô\:lí\right)\)
Em xem lại đề nha!
Fe+2HCl->FeCl2+H2
0,02-0,04--------------0,02
Fe2O3+6HCl->2Fecl3+3H2O
0,03-----0,18 mol
n H2=\(\dfrac{0,448}{22,4}\)=0,02 mol
=>m Fe=0,02.56=1,12g
=>m Fe2O3=4,8g=>n Fe2O3=\(\dfrac{4,8}{160}\)=0,03 mol
=>x=CMHCl=\(\dfrac{0,22}{0,5}\)=0,44M
b)
2Fe+3Cl2-to>2FeCl3
0,02---0,03
=>m Cl2=0,03.71=2,13g
a) nCl2=7,28/22,4=0,325(mol)
=> mCl2=0,325.71=23,075(mol)
=> m(muối)= m(hh)+ mCl2= 10,45+23,075=33,525(g)
b) PTHH: 2 Al + 3 Cl2 -to-> 2 AlCl3
a__________1,5a(mol)
Cu + Cl2 -to-> CuCl2
b___b(mol)
Ta có hpt:
\(\left\{{}\begin{matrix}27a+64b=10,45\\1,5a+b=0,325\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,15\\b=0,1\end{matrix}\right.\)
=> mCu=0,1.64=6,4(g)
=>%mCu= (6,4/10,45).100=61,244%
=>%mAl=38,756%
\(n_{HCl}=\dfrac{58,4.15\%}{36,5}=0,24\left(mol\right)\\ Fe+2HCl\rightarrow\left(t^o\right)FeCl_2+H_2\\ n_{Fe}=n_{H_2}=\dfrac{0,24}{2}=0,12\left(mol\right)\\ \Rightarrow V1=V_{H_2\left(đktc\right)}=0,12.22,4=2,688\left(l\right)\\ x=m_{Cu}=m_{hhA}-m_{Fe}=15,68-0,12.56=8,96\left(g\right)\\ b,n_{Cu}=\dfrac{8,96}{64}=0,14\left(mol\right)\\ 2Fe+3Cl_2\rightarrow\left(t^o\right)2FeCl_3\\ Cu+Cl_2\rightarrow\left(t^o\right)CuCl_2\\ n_{Cl_2}=\dfrac{3}{2}.n_{Fe}+n_{Cu}=\dfrac{3}{2}.0,12+0,14=0,32\left(mol\right)\\ \Rightarrow V2=V_{Cl_2\left(đktc\right)}=0,32.22,4=7,168\left(l\right)\\ y=m_{muối}=m_{AlCl_3}+m_{CuCl_2}=0,12.133,5+0,14.135=34,92\left(g\right)\)
mCu = 2 (g)
Gọi số mol Al, Fe là a, b (mol)
=> 27a + 56b = 10,3 - 2 = 8,3 (1)
\(n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
PTHH: 2Al + 6HCl --> 2AlCl3 + 3H2
a--------------------->1,5a
Fe + 2HCl --> FeCl2 + H2
b---------------------->b
=> 1,5a + b = 0,25 (2)
(1)(2) => a = 0,1 (mol); b = 0,1 (mol)
=> \(\left\{{}\begin{matrix}\%Al=\dfrac{0,1.27}{10,3}.100\%=26,21\%\\\%Fe=\dfrac{0,1.56}{10,3}.100\%=54,37\%\\\%Cu=\dfrac{2}{10,3}.100\%=19,42\%\end{matrix}\right.\)
\(n_{HCl}=2.n_{H_2}=0,5\left(mol\right)\)
=> \(V_{dd.HCl}=\dfrac{0,5}{2}=0,25\left(l\right)\)
TH1:
\(Fe+2HCl\rightarrow FeCl_2+H_2\\ Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2O\)
\(m_{Cu}=m_{rắn}=6,4\left(g\right)\\ \Rightarrow m_{\left(Fe,Fe_2O_3\right)}=28-6,4=21,6\left(g\right)\\ n_{FeCl_2}=n_{Fe}=n_{H_2}=0,15\left(mol\right)\\ \Rightarrow n_{Fe_2O_3}=\dfrac{21,6-0,15.56}{160}=0,0825\left(mol\right)\\ \Rightarrow n_{FeCl_3}=2.0,0825=0,165\left(mol\right)\\ \Rightarrow m_{muối}=m_{FeCl_2}+m_{FeCl_3}=127.0,15+162,5.0,165=45,8625\left(g\right)\)
TH2: Nếu cho 28 gam hỗn hợp đó tác dụng clo thì như nào nhở???