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a) \(V_r=\frac{Đ_r.V_{hh}}{100}=\frac{92.25}{100}=13,8\left(ml\right)\)
\(m_r=d.V=0,8.13,8=11,04\left(g\right)\)
b) PTHH :\(2C_2H_5OH+2Na\rightarrow2C_2H_5ONa+H_2\uparrow\)
Theo PT: \(n_{H_2}=\frac{1}{2}n_{C_2H_5OH}=\frac{1}{2}.\frac{11,04}{46}=0,12\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,12.22,4=2,688\left(l\right)\)
\(a,V_{C_2H_5OH}=\dfrac{10.96}{100}=9,6\left(ml\right)\\ m_{C_2H_5OH}=9,6.0,8=7,68\left(g\right)\\ n_{C_2H_5OH}=\dfrac{7,68}{46}=\dfrac{96}{575}\left(mol\right)\)
PTHH: 2C2H5OH + 2Na ---> 2C2H5ONa + H2
\(\dfrac{96}{575}\)------------------------------------->\(\dfrac{48}{575}\)
\(V_{H_2}=\dfrac{48}{575}.22,4=1,87\left(l\right)\)
\(b,V_{dd}=12+10,6=20,6\left(ml\right)\\ Đ_r=\dfrac{9,6}{20,6}.100=46,6^o\)
\(a,n_{C_6H_{12}O_6}=\dfrac{36}{180}=0,2\left(mol\right)\)
PTHH: \(C_6H_{12}O_6\underrightarrow{\text{men rượu}}2C_2H_5OH+2CO_2\uparrow\)
0,2----------------->0,4----------->0,4
=> VCO2 = 0,4.22,4 = 8,96 (l)
b, mC2H5OH = 0,4.46.50% = 9,2 (g)
\(c,V_{C_2H_5OH}=\dfrac{9,2}{0,8}=11,5\left(ml\right)\\ \rightarrow V_{ddC_2H_5OH}=\dfrac{11,5.100}{60}=\dfrac{115}{6}\left(ml\right)\)
\(a,V_{C_2H_5OH}=\dfrac{96.30}{100}=28,8\left(ml\right)\\ \rightarrow m_{C_2H_5OH}=28,8.0,8=23,04\left(ml\right)\\ \rightarrow n_{C_2H_5OH}=\dfrac{23,04}{46}=0,5\left(mol\right)\)
PTHH: 2C2H5OH + 2Na ---> 2C2H5ONa + H2
0,5----------------------------------->0,25
\(\rightarrow V_{H_2}=0,25.22,4=5,6\left(l\right)\)
b, \(n_{CH_3COOH}=\dfrac{36}{60}=0,6\left(mol\right)\)
PTHH: \(C_2H_5OH+CH_3COOH\xrightarrow[t^o]{H_2SO_{4\left(đ\right)}}CH_3COOC_2H_5+H_2O\)
LTL: 0,5 < 0,6 => CH3COOH dư
Theo pthh: nCH3COOH = nC2H5OH = 0,5 (mol)
=> meste = 0,5.88.70% = 30,8 (g)
a)
$C_6H_{12}O_6 \xrightarrow{t^o,xt} 2CO_2 + 2C_2H_5OH$
720 ml = 720 cm3
m dd glucozo = D.V = 720.1 = 720(gam)
m glucozo = 720.5% = 36(gam)
n glucozo = 36/180 = 0,2(mol)
Theo PTHH :
n C2H5OH = 2n glucozo = 0,4(mol)
m C2H5OH = 0,4.46 = 18,4(gam)
b)
V rượu = m/D = 18,4/0,8 = 23(ml)
Vậy :
Đr = 23/240 .100 = 9,583o
