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\(m_{NaOH}=\dfrac{200\cdot8}{100}=16\left(g\right)\Rightarrow n_{NaOH}=\dfrac{16}{40}=0,4mol\)
\(NaOH+HCl\rightarrow NaCl+H_2O\)
0,4 0,4 0,4 0,4
a)\(m_{HCl}=0,4\cdot36,5=14,6\left(g\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{14,6}{7,3}\cdot100=200\left(g\right)\)
b)\(m_{NaCl}=0,4\cdot58,5=23,4\left(g\right)\)
\(m_{H_2O}=0,4\cdot18=7,2\left(g\right)\)
\(m_{ddsau}=200+200-7,2=392,8\left(g\right)\)
\(\Rightarrow C\%=\dfrac{23,4}{392,8}\cdot100=5,96\%\)
c) \(n_{SO_2}=\dfrac{6,72}{22,4}=0,3mol\)
\(2NaOH+SO_2\rightarrow Na_2SO_4+H_2O\)
0,4 0,3 0,3 0,3
\(m_{Na_2SO_4}=0,3\cdot142=42,6\left(g\right)\)
PTHH: \(K_2O+2HCl\rightarrow2KCl+H_2O\)
\(K_2SO_3+2HCl\rightarrow2KCl+SO_2\uparrow+H_2O\)
a) Ta có: \(\left\{{}\begin{matrix}n_{HCl}=\dfrac{200\cdot14,6\%}{36,5}=0,8\left(mol\right)\\n_{SO_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}n_{K_2SO_3}=0,3\left(mol\right)\\n_{K_2O}=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{K_2O}=\dfrac{0,1\cdot94}{0,1\cdot94+0,3\cdot158}\cdot100\%\approx16,55\%\\\%m_{K_2SO_3}=83,45\%\end{matrix}\right.\)
b) Theo các PTHH: \(n_{KCl}=0,8\left(mol\right)\) \(\Rightarrow m_{KCl}=74,5\cdot0,8=59,6\left(g\right)\)
Mặt khác: \(\left\{{}\begin{matrix}m_{hh}=56,8\left(g\right)\\m_{SO_2}=0,3\cdot64=19,2\left(g\right)\end{matrix}\right.\)
\(\Rightarrow m_{dd}=m_{hh}+m_{ddHCl}-m_{SO_2}=237,6\left(g\right)\)
\(\Rightarrow C\%_{KCl}=\dfrac{59,6}{237,6}\cdot100\%\approx25,1\%\)
a hả
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a) PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
b) Ta có: \(n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)=n_{FeCl_2}\)
\(\Rightarrow m_{FeCl_2}=0,25\cdot127=31,75\left(g\right)\)
c) Theo PTHH: \(n_{H_2}=n_{Fe}=0,25mol\) \(\Rightarrow m_{Fe}=0,25\cdot56=14\left(g\right)\)
\(\Rightarrow\%m_{Fe}=\dfrac{14}{20}\cdot100\%=70\%\) \(\Rightarrow\%m_{Ag}=30\%\)
d) Sửa đề cho dễ làm: "dd HCl 7,3%"
Theo PTHH: \(n_{HCl}=2n_{Fe}=0,5mol\)
\(\Rightarrow m_{ddHCl}=\dfrac{0,5\cdot36,5}{7,3\%}=250\left(g\right)\) \(\Rightarrow V_{HCl}=\dfrac{250}{1,03}\approx242,72\left(ml\right)\)
a)
$CH_3COOH + NaHCO_3 \to CH_3COONa + CO_2 + H_2O$
b)
n NaHCO3 = n CH3COOH = 100.12%/60 = 0,2(mol)
m dd NaHCO3 = 0,2.84/8% = 210(gam)
c)
n CO2 = n CH3COOH = 0,2(mol)
=> V CO2 = 0,2.22,4 = 4,48(lít)
d)
m dd = m dd CH3COOH + m dd NaHCO3 - m CO2 = 100 + 210 - 0,2.44 = 301,2(gam)
C% CH3COONa = 0,2.82/301,2 .100% = 5,44%
