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CH4+2O2-to>CO2+2H2O
x------2x---------x
C2H4+3O2-to>2CO2+2H2O
y----------3y--------2y
=>\(\left\{{}\begin{matrix}x+y=\dfrac{5,6}{22,4}\\2x+3y=\dfrac{13,44}{22,4}\end{matrix}\right.\)
=>x=0,15 mol , y=0,1 mol
=>%VCH4=\(\dfrac{0,15.22,4}{5,6}\).100=60%
=>%VC2H4=100-60=40%
b)
VCO2=(0,15+0,1.2).22,4=7,84l
mhh khí = 5,6/22,4 = 0,25 (mol)
nO2 = 13,44/22,4 = 0,6 (mol)
Gọi nC2H4 = a (mol); nCH4 = b (mol)
a + b = 0,25 (1)
PTHH:
C2H4 + 3O2 -> (t°) 2CO2 + 2H2O
Mol: a ---> 3a ---> 2a
CH4 + 2O2 -> (t°) CO2 + 2H2O
Mol: b ---> 2b ---> b
3a + 2b = 0,6 (2)
(1)(2) => a = 0,1 (mol); b = 0,15 (mol)
%VC2H4 = 0,1/0,25 = 40%
%VCH4 = 100% - 40% = 60%
VCO2 = (0,1 . 2 + 0,15) . 22,4 = 7,84 (l)
a, \(CH_4+2O_2\underrightarrow{^{t^o}}CO_2+2H_2O\)
\(C_2H_4+3O_2\underrightarrow{^{t^o}}2CO_2+2H_2O\)
b, Gọi: \(\left\{{}\begin{matrix}n_{CH_4}=x\left(mol\right)\\n_{C_2H_4}=y\left(mol\right)\end{matrix}\right.\) \(\Rightarrow x+y=\dfrac{4,48}{22,4}=0,2\left(mol\right)\left(1\right)\)
Theo PT: \(n_{O_2}=2n_{CH_4}+3n_{C_2H_4}=2x+3y=\dfrac{15,68}{22,4}=0,7\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=-0,1\\y=0,3\end{matrix}\right.\)
Đến đây thì ra số mol âm, bạn xem lại đề nhé.
a)
\(n_{Br_2}=\dfrac{8}{160}=0,05\left(mol\right)\)
PTHH: C2H4 + Br2 --> C2H4Br2
0,05<-0,05
=> \(n_{CH_4}=\dfrac{3,36}{22,4}-0,05=0,1\left(mol\right)\)
\(\%m_{CH_4}=\dfrac{0,1.16}{0,1.16+0,05.28}.100\%=53,33\%\)
\(\%m_{C_2H_4}=\dfrac{0,05.28}{0,1.16+0,05.28}.100\%=46,67\%\)
b)
PTHH: CH4 + 2O2 --to--> CO2 + 2H2O
0,1-->0,2
C2H4 + 3O2 --to--> 2CO2 + 2H2O
0,05--->0,15
=> \(V_{O_2}=\left(0,2+0,15\right).22,4=7,84\left(l\right)\)
a, PT: \(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)
\(C_2H_4+3O_2\underrightarrow{t^o}2CO_2+2H_2O\)
Ta có: \(n_{CH_4}+n_{C_2H_4}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\left(1\right)\)
Theo PT: \(n_{CO_2}=n_{CH_4}+2n_{C_2H_4}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{CH_4}=0,2\left(mol\right)\\n_{C_2H_4}=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,2.22,4}{6,72}.100\%\approx66,67\%\\\%V_{C_2H_4}\approx33,33\%\end{matrix}\right.\)
b, Theo PT: \(n_{O_2}=2n_{CH_4}+3n_{C_2H_4}=0,7\left(mol\right)\)
\(\Rightarrow V_{O_2}=0,7.22,4=15,68\left(l\right)\)
\(n_{Br_2}=\dfrac{m_{Br_2}}{M_{Br_2}}=\dfrac{56}{160}=0,35mol\)
Gọi \(n_{C_2H_4}\) là x \(\Rightarrow V_{C_2H_4}=22,4x\)
\(n_{C_2H_2}\) là y \(\Rightarrow V_{C_2H_2}=22,4y\)
\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
x x ( mol )
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
y 2y ( mol )
Ta có:
\(\left\{{}\begin{matrix}22,4x+22,4y=5,6\\x+2y=0,35\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}x=0,15\\y=0,1\end{matrix}\right.\)
\(\Rightarrow V_{C_2H_4}=22,4.0,15=3,36l\)
\(\Rightarrow V_{C_2H_2}=22,4.0,1=2,24l\)
\(\%V_{C_2H_4}=\dfrac{3,36}{5,6}.100=60\%\)
\(\%V_{C_2H_2}=\dfrac{2,24}{5,6}.100=40\%\)
nhh khí = 5,6/22,4 = 0,25 (mol)
Gọi nC2H4 = a (mol); nC2H2 = b (mol)
a + b = 0,25 (1)
nBr2 = 56/160 = 0,35 (mol)
PTHH:
C2H4 + Br2 -> C2H4Br2
Mol: a ---> a
C2H2 + 2Br2 -> C2H2Br4
Mol: b ---> 2b
a + 2b = 0,35 (2)
(1)(2) => a = 0,15 (mol); b = 0,1 (mol)
%VC2H2 = 0,15/0,25 = 60%
%VC2H4 = 100% - 60% = 40%
a, \(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)
\(2C_2H_2+5O_2\underrightarrow{t^o}4CO_2+2H_2O\)
Ta có: \(n_{CH_4}+n_{C_2H_2}=\dfrac{0,028}{22,4}=0,00125\left(mol\right)\left(1\right)\)
Theo PT: \(n_{O_2}=2n_{CH_4}+\dfrac{5}{2}n_{C_2H_2}=\dfrac{0,0672}{22,4}=0,003\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{CH_4}=0,00025\left(mol\right)\\n_{C_2H_2}=0,001\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,00025.22,4}{0,028}.100\%=20\%\\\%V_{C_2H_2}=80\%\end{matrix}\right.\)
b, Theo PT: \(n_{CO_2}=n_{CH_4}+2n_{C_2H_2}=0,00225\left(mol\right)\)
\(\Rightarrow V_{CO_2}=0,00225.22,4=0,0504\left(l\right)\)
Bài 2.
\(n_{C_2H_2}=\dfrac{4,48}{22,4}=0,2mol\)
\(n_{O_2}=\dfrac{6,72}{22,4}=0,3mol\)
\(2C_2H_2+5O_2\rightarrow\left(t^o\right)4CO_2+2H_2O\)
0,2 > 0,3 ( mol )
0,3 0,24 0,12 ( mol )
\(m_{CO_2}=0,24.44=10,56g\)
\(m_{H_2O}=0,12.18=2,16g\)
PTHH: 2CO + O2→2CO2
C2H4 + 3O2→ 2CO2 +2 H2O
nH2O= mM=\(\dfrac{1,8}{18}\)=0,1(mol)
nC2H4=\(\dfrac{1}{2}\).nH2O=\(\dfrac{1}{2}\).0,1=0,05(mol)
=> VC2H4=n.22,4=0,05.22,4=1,12(lít)
->VCO=4,48 − 1,12= 3,36(lít)
b) nCO2 (1)=nCO=\(\dfrac{3,36}{22,4}\)=0,15(mol)
mCO2 (1)=n.M=0,15.44=6,6(g)
nCO2 (2)=2.nC2H4=2.0,05=0,1(mol)
mCO2 (2)=n.M=0,1.44=4,4(g)
mCO2 sau pư=6,6 + 4,4= 11(g)
Tính % thể tích các khí :
% V C 2 H 2 = 0,448/0,896 x 100% = 50%
% V CH 4 = % V C 2 H 6 = 25%
CH4+2O2-to>CO2+2H2O
x------2x---------x
C2H2+\(\dfrac{5}{2}\)O2-to>2CO2+H2O
y----------\(\dfrac{5}{2}\)y--------2y
Ta có :
\(\left\{{}\begin{matrix}x+y=\dfrac{6,72}{22,4}\\x+2y=\dfrac{8,96}{22,4}\end{matrix}\right.\)
=>x=0,2 mol, y=0,1 mol
=>%VCH4=\(\dfrac{0,2.22,4}{6,72}\).100=66,67%
=>%VC2H2=100-66,67=33,33%
b)
VO2=(2.0,2+\(\dfrac{5}{2}\).0,1).22,4=14,56l