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Bài 1:
PTHH: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\uparrow\)
\(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)
Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)=n_{Fe}\)
\(\Rightarrow\%m_{Fe}=\dfrac{0,1\cdot56}{37,6}\cdot100\%\approx14,89\%\)
\(\Rightarrow\%m_{Fe_2O_3}=85,11\%\)
Bài 3:
PTHH: \(2HNO_3+Ba\left(OH\right)_2\rightarrow Ba\left(NO_3\right)_2+2H_2O\)
Ta có: \(\left\{{}\begin{matrix}n_{HNO_3}=0,05\cdot1=0,05\left(mol\right)\\n_{Ba\left(OH\right)_2}=\dfrac{342\cdot5\%}{171}=0,1\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,05}{2}< \dfrac{0,1}{1}\) \(\Rightarrow\) Axit p/ứ hết, Bazơ còn dư sau p/ứ
\(\Rightarrow\) Dung dịch sau p/ứ làm quỳ tím hóa xanh
Theo PTHH: \(n_{Ba\left(NO_3\right)_2}=\dfrac{1}{2}n_{HNO_3}=0,025\left(mol\right)\) \(\Rightarrow m_{Ba\left(NO_3\right)_2}=0,025\cdot261=6,525\left(g\right)\)
PTHH: \(2Fe+6H_2SO_{4\left(đ\right)}\underrightarrow{t^o}Fe_2\left(SO_4\right)_3+3SO_2\uparrow+6H_2O\)
\(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)
a) Ta có: \(n_{SO_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\) \(\Rightarrow n_{Fe}=\dfrac{1}{15}\left(mol\right)\)
\(\Rightarrow\%m_{Fe}=\dfrac{\dfrac{1}{15}\cdot56}{13,6}\cdot100\%\approx27,45\%\) \(\Rightarrow\%m_{CuO}=72,55\%\)
b) Ta có: \(m_{CuO}=13,6-\dfrac{1}{15}\cdot56\approx9,9\left(g\right)\) \(\Rightarrow n_{CuO}=n_{H_2SO_4}=\dfrac{9,9}{80}=0,12375\left(mol\right)\)
*Làm gì có H2SO4 loãng đâu nhỉ ??
a) Y là Cu
$m_{Cu} = 8(gam)$
Gọi $n_{Al} = a(mol) ; n_{Fe} = b(mol)$
Ta có : $27a + 56b + 8 = 13,45(1)$
$2Al + 3H_2SO_4 \to Al_2(SO_4)_3 + 3H_2$
$Fe + H_2SO_4 \to FeSO_4 + H_2$
$n_{H_2} = 1,5a + b = \dfrac{5,6}{22,4} = 0,25(2)$
Từ (1)(2) suy ra a = 0,15 ; b = 0,025$
$\%m_{Cu} = \dfrac{8}{13,45}.100\% = 59,47\%$
$\%m_{Al} = \dfrac{0,15.27}{13,45}.100\% = 30,11\%$
$\%m_{Fe} = 10,42\%$
b)
$n_{H_2SO_4} = n_{H_2} = 0,25(mol)$
$V_{dd\ H_2SO_4} = \dfrac{0,25}{0,5} = 0,5(lít)$
\(n_{SO_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PTHH :
\(Cu+2H_2SO_4\left(đặcnóng\right)\rightarrow CuSO_4+SO_2+2H_2O\)
0,2 0,4 0,2
\(m_{Cu}=0,2.64=12,8\left(g\right)\)
\(\%m_{Cu}=\dfrac{12,8}{20,8}.100\%\approx61,54\%\)
\(\%m_{CuO}=100\%-61,54\%=38,46\%\)
\(m_{H_2SO4_4}=0,4.98=39,2\left(g\right)\)
\(m_{ddH_2SO_4}=\dfrac{39,2.100}{98}=40\left(g\right)\)
Vì Cu không tác dụng với HCl
\(n_{H2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
Pt : \(Fe+2HCl\rightarrow FeCl_2+H_2|\)
1 2 1 1
0,1 0,2 0,1
a) \(n_{Fe}=\dfrac{0,1.1}{1}=0,1\left(mol\right)\)
\(m_{Fe}=0,1.56=5,6\left(g\right)\)
\(m_{Cu}=12-5,6=6,4\left(g\right)\)
b) \(n_{HCl}=\dfrac{0,1.2}{1}=0,2\left(mol\right)\)
200ml = 0,2l
\(C_{M_{ddHCl}}=\dfrac{0,2}{0,2}=1\left(M\right)\)
c) 0/0Fe = \(\dfrac{5,6.100}{12}=46,67\)0/0
0/0Cu = \(\dfrac{6,4.100}{12}=53,33\)0/0
Chúc bạn học tốt
Cu không tác dụng với dung dịch H2SO4 loãng
\(n_{H2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
Pt : \(Fe+2HCl\rightarrow FeCl_2+H_2|\)
1 2 1 1
0,1 0,1
a) \(n_{Fe}=\dfrac{0,1.1}{1}=0,1\left(mol\right)\)
\(m_{Fe}=0,1.56=5,6\left(g\right)\)
\(m_{Cu}=8,8-5,6=3,2\left(g\right)\)
0/0Fe = \(\dfrac{5,6.100}{8,8}=63,64\)0/0
0/0Cu = \(\dfrac{3,2.100}{8,8}=36,36\)0/0
b) Có : \(m_{Cu}=3,2\left(g\right)\)
\(n_{Cu}=\dfrac{3,2}{64}=0,05\left(mol\right)\)
Pt : \(Cu+2H_2SO_{4đặc,nóng}\rightarrow CuSO_4+SO_2+2H_2O|\)
1 2 1 1 2
\(n_{SO2}=\dfrac{0,05.1}{1}=0,05\left(mol\right)\)
\(V_{SO2\left(dktc\right)}=0,05.22,4=1,12\left(l\right)\)
Chúc bạn học tốt
a, \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
PTHH: Fe + H2SO4 → FeSO4 + H2
Mol: 0,1 0,1
\(\%m_{Fe}=\dfrac{0,1.56.100\%}{8,8}=63,64\%;\%m_{Cu}=100-63,64=36,36\%\)
Chất rắn X là Cu (Cu ko tác dụng với H2SO4 loãng)
b,\(n_{Cu}=\dfrac{8,8-5,6}{64}=0,05\left(mol\right)\)
PTHH: Cu + 2H2SO4 (đ) → CuSO4 + SO2 + 2H2O
Mol: 0,05 0,05
\(\Rightarrow V_{SO_2}=0,05.22,4=1,12\left(l\right)\)
a/nH2= 0,1(mol)
Fe + H2SO4 -> FeSO4 + H2
0,1_________________0,1(mol)
=> mFe=0,1.56=5,6(g)
=> %mFe= (5,6/12).100\(\approx\) 46,667%
=> %mCu \(\approx\) 100% - 46,667% \(\approx\) 53,333%
b) mCu= 12-5,6=6,4(g) -> nCu= 0,1(mol)
Cu + 2 H2SO4(đ) -to-> CuSO4 + SO2 + 2 H2O
0,1___0,2__________________0,1(mol)
V=V(SO2,đktc)=0,1.22,4=2,24(l)
mH2SO4(p.ứ)=0,2.98=19,6(g)
=> mH2SO4(bđ)= 19,6 x 100/90 \(\approx21,778\left(g\right)\)
=> mddH2SO4 \(\approx\) (21,778 x 100)/98\(\approx22,222\left(g\right)\)