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Gọi số mol C, S là a, b
=> 12a + 32b = 7,68
PTHH: C + O2 --to--> CO2
_____a--------------->a
S + O2 --to--> SO2
b--------------->b
=> a + b = \(\dfrac{9,856}{22,4}=0,44\)
=> a = 0,32; b = 0,12
=> \(\left\{{}\begin{matrix}\%C=\dfrac{0,32.12}{7,68}.100\%=50\%\\\%S=\dfrac{0,12.32}{7,68}.100\%=50\%\end{matrix}\right.\)
2Zn + O2 \(\underrightarrow{to}\) 2ZnO (1)
2Mg + O2 \(\underrightarrow{to}\) 2MgO (2)
Ta có: \(\dfrac{m_{ZnO}}{m_{MgO}}=\dfrac{2,025}{1}=\dfrac{81}{40}\)
\(\Rightarrow m_{ZnO}=12,1\div\left(81+40\right)\times81=8,1\left(g\right)\)
\(\Rightarrow m_{MgO}=12,1-8,1=4\left(g\right)\)
\(\Rightarrow n_{ZnO}=\dfrac{8,1}{81}=0,1\left(mol\right)\)
\(n_{MgO}=\dfrac{4}{40}=0,1\left(mol\right)\)
Theo PT1: \(n_{Zn}=n_{ZnO}=0,1\left(mol\right)\)
\(\Rightarrow m_{Zn}=0,1\times65=6,5\left(g\right)\)
Theo PT2: \(n_{Mg}=n_{MgO}=0,1\left(mol\right)\)
\(\Rightarrow m_{Mg}=0,1\times24=2,4\left(g\right)\)
\(n_{HCl}=1.0,2=0,2(mol)\\ PTHH:Mg+2HCl\to MgCl_2+H_2\\ \Rightarrow n_{Mg}=\dfrac{1}{2}n_{HCl}=0,1(mol)\\ \Rightarrow m_{Mg}=0,1.24=2,4(g)\\ \Rightarrow m_{Cu}=10-2,4=7,6(g)\)
Đặt \(\left\{{}\begin{matrix}n_{Mg}=x\left(mol\right)\\n_{Fe}=y\left(mol\right)\end{matrix}\right.\)
Theo đề: \(m_{hh}=36\left(g\right)\)
\(\Rightarrow m_{Mg}+m_{Fe}=36\\ \Rightarrow24x+56y=36\left(1\right)\)
\(PTHH:2Mg+O_2\underrightarrow{t^o}2MgO\\ \left(mol\right)....x\rightarrow...0,5x.....x\\ PTHH:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\\ \left(mol\right)....y\rightarrow...\dfrac{2}{3}y....\dfrac{1}{3}y\)
Theo đề: \(n_{O_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)
\(\Rightarrow0,5x+\dfrac{2}{3}y=0,6\left(2\right)\)
\(\xrightarrow[\left(2\right)]{\left(1\right)}\left\{{}\begin{matrix}24x+56y=36\\0,5x+\dfrac{2}{3}y=0,6\end{matrix}\right.\\ \Leftrightarrow\left\{{}\begin{matrix}x=0,8\\y=0,3\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}m_{Mg}=0,8.24=19,2\left(g\right)\\m_{Fe}=0,3.56=16,8\left(g\right)\end{matrix}\right.\\ m_r=m_{MgO}+m_{Fe_3O_4}=0,8.40+\dfrac{1}{3}.0,3.232=55,2\left(g\right)\)
PTHH: C+O2→CO20,3mol:0,3mol→0,3molC+O2→CO20,3mol:0,3mol→0,3mol
S+O2→SO20,2mol:0,2mol→0,2molS+O2→SO20,2mol:0,2mol→0,2mol
mC=36%10100%=3,6(g)⇔nC=3,612=0,3(mol)mC=36%10100%=3,6(g)⇔nC=3,612=0,3(mol)
mS=10−3,6=6,4(g)⇔nS=6,432=0,2(mol)mS=10−3,6=6,4(g)⇔nS=6,432=0,2(mol)
VO2=(0,3+0,2)22,4=11,2(l)VO2=(0,3+0,2)22,4=11,2(l)
mhh=mCO2+mSO2=0,3.44+0,2.64=26(g)
Đặt \(\left\{{}\begin{matrix}n_{Al}=x\left(mol\right)\\n_{Fe}=y\left(mol\right)\end{matrix}\right.\)
Theo đề: \(m_{hh}=39\left(g\right)\)
\(\Rightarrow m_{Al}+m_{Fe}=39\\ \Rightarrow27x+56y=39\left(1\right)\)
\(PTHH:4Al+3O_2\underrightarrow{t^o}2Al_2O_3\\ \left(mol\right)....x\rightarrow..0.75x....0,5x\\ PTHH:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\\ \left(mol\right)....y\rightarrow..\dfrac{2}{3}y.....\dfrac{1}{3}y\)
Theo đề: \(n_{O_2}=\dfrac{V}{22,4}=\dfrac{12,32}{22,4}=0,55\left(mol\right)\)
\(\Rightarrow0,75x+\dfrac{2}{3}y=0,55\left(2\right)\)
\(\xrightarrow[\left(1\right)]{\left(2\right)}\left\{{}\begin{matrix}27x+56y=39\\0,75x+\dfrac{2}{3}y=0,55\end{matrix}\right.\\ \Leftrightarrow\left\{{}\begin{matrix}x=0,2\\y=0,6\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}m_{Al}=0,2.27=5,4\left(g\right)\\m_{Fe}=0,6.56=33,6\left(g\right)\end{matrix}\right.\\ m_r=m_{Al_2O_3}+m_{Fe_3O_4}=0,5.0,2.102+\dfrac{1}{3}.0,6.232=56,6\left(g\right)\)
Gọi $n_{Al}= a(mol) ; n_{Fe} = b(mol) \Rightarrow 27a + 56b = 4,44(1)$
$4Al + 3O_2 \xrightarrow{t^o} 2Al_2O_3$
$3Fe + 2O_2 \xrightarrow{t^o} Fe_3O_4$
$Fe_3O_4 + 4H_2 \xrightarrow{t^o} 3Fe + 4H_2O$
B gồm : $Al_2O_3, Fe$
$n_{Al_2O_3} = \dfrac{1}{2}n_{Al} = 0,5a(mol)$
Suy ra: $0,5a.102 + 56b = 5,4(2)$
Từ (1)(2) suy ra a = 0,04 ; b = 0,06
$m_{Al} = 0,04.27 =1,08\ gam$
$m_{Fe} = 0,06.56 = 3,36\ gam$
PTHH: \(Mg+\dfrac{1}{2}O_2\xrightarrow[]{t^o}MgO\)
\(Cu+\dfrac{1}{2}O_2\xrightarrow[]{t^o}CuO\)
Theo đề bài: \(m_{tăng}=32\left(g\right)=m_{O_2\left(p.ứ\right)}\)
Bảo toàn khối lượng: \(m_{oxit\:}=m_{KL}+m_{O_2}=120\left(g\right)\)
\(\Rightarrow m_{MgO}=\dfrac{120}{3}=40\left(g\right)\) \(\Rightarrow m_{CuO}=80\left(g\right)\)