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Đáp án B
nSO2 = 1,7 (mol)
Chất rắn Z là Fe2O3, nFe2O3 = 0,4 (mol)
2Febđ → Fe2O3
0,8 ← 0,4 (mol)
Ta có: mX = 1,7 ×64 – 48=60,8 (gam)
a)
Gọi \(\left\{{}\begin{matrix}n_{Fe}=a\left(mol\right)\\n_{Mg}=b\left(mol\right)\end{matrix}\right.\)
=> 56a + 24b = 18,4 (1)
PTHH: Fe + 2HCl --> FeCl2 + H2
a-->2a------>a------>a
Mg + 2HCl --> MgCl2 + H2
b--->2b------->b------>b
=> \(a+b=\dfrac{11,2}{22,4}=0,5\) (2)
(1)(2) => a = 0,2 (mol); b = 0,3 (mol)
\(\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{0,2.56}{18,4}.100\%=60,87\%\\\%m_{Mg}=\dfrac{0,3.24}{18,4}.100\%=39,13\%\end{matrix}\right.\)
b) \(n_{HCl\left(pư\right)}=2a+2b=1\left(mol\right)\)
=> \(n_{HCl\left(tt\right)}=\dfrac{1.125}{100}=1,25\left(mol\right)\)
=> mHCl(tt) = 1,25.36,5 = 45,625 (g)
=> \(a=\dfrac{45,625.100}{18,25}=250\left(g\right)\)
c)
mdd sau pư = 18,4 + 250 - 0,5.2 = 267,4 (g)
\(C\%_{FeCl_2}=\dfrac{0,2.127}{267,4}.100\%=9,5\%\)
\(C\%_{MgCl_2}=\dfrac{0,3.95}{267,4}.100\%=10,66\%\)
a)\(n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
PTHH: 2Al + 3H2SO4 → Al2(SO4)3 + 3H2
Mol: x 1,5x
PTHH: Mg + H2SO4 → MgSO4 + H2
Mol: y y
Ta có: \(\left\{{}\begin{matrix}27x+24y=5,1\\1,5x+y=0,25\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,1\\y=0,1\end{matrix}\right.\)
\(\%m_{Al}=\dfrac{0,1.27.100\%}{5,1}=52,94\%;\%m_{Mg}=100-52,94=47,06\%\)
b)
PTHH: 2Al + 3H2SO4 → Al2(SO4)3 + 3H2
Mol: 0,1 0,15 0,05
PTHH: Mg + H2SO4 → MgSO4 + H2
Mol: 0,1 0,1 0,1
\(m_{ddH_2SO_4}=\dfrac{\left(0,1+0,15\right).98.100}{9,8}=250\left(g\right)\)
mdd sau pứ = 5,1+250-0,15.2 = 254,8(g)
\(C\%_{ddAl_2\left(SO_4\right)_3}=\dfrac{0,05.342.100\%}{254,8}=6,71\%\)
\(C\%_{ddMgSO_4}=\dfrac{0,1.120.100\%}{254,8}=4,71\%\)
$a)$
Đặt $n_{Al}=x(mol);n_{Fe}=y(mol)$
$\to 27x+56y=13,75(1)$
Bảo toàn e: $1,5x+y=n_{H_2}=\dfrac{11,2}{22,4}=0,5(2)$
Từ $(1)(2)\to x=0,25(mol);y=0,125(mol)$
$\to \%m_{Al}=\dfrac{0,25.27}{13,75}.100\%\approx 49,09\%$
$\to \%m_{Fe}=100-49,09=50,91\%$
$b)$
Bảo toàn H: $n_{HCl}=2n_{H_2}=1(mol)$
$\to a=\dfrac{1.36,5.120\%}{18,25\%}=240(g)$
$c)$
Bảo toàn Al,Fe: $n_{AlCl_3}=0,25(mol);n_{FeCl_2}=0,125(mol)$
$m_{dd_{HCl(p/ứ)}}=\dfrac{1.36,5}{18,25\%}=200(g)$
Ta có $m_{dd\, sau}=13,75+200-0,5.2=212,75(g)$
$\to \begin{cases} C\%_{AlCl_3}=\dfrac{0,25.133,5}{212,75}.100\%=15,69\%\\ C\%_{FeCl_2}=\dfrac{0,125.127}{212,75}.100\%=7,46\% \end{cases}$
\(n_{HCl}=0,3.2=0,6\left(mol\right)\\ n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\\ 2Al+6HCl\rightarrow2AlCl_3+3H_2\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ Vì:\dfrac{0,6}{2}>\dfrac{0,25}{1}\Rightarrow HCldư\\ Đặt:n_{Al}=t\left(mol\right);n_{Fe}=r\left(mol\right)\\ \left(t,r>0\right)\\ \Rightarrow\left\{{}\begin{matrix}27t+56r=8,3\\1,5t+r=0,25\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}t=0,1\\r=0,1\end{matrix}\right.\\ \Rightarrow m_{Al}=0,1.27=2,7\left(g\right);m_{Fe}=0,1.56=5,6\left(g\right)\\ b,n_{AlCl_3}=n_{Al}=0,1\left(mol\right)\Rightarrow m_{AlCl_3}=0,1.133,5=13,35\left(g\right)\\ n_{Fe}=n_{FeCl_2}=0,1\left(mol\right)\Rightarrow m_{ddFeCl_2}=127.0,1=12,7\left(g\right)\\ m_{ddHCl}=300.1,15=345\left(g\right)\\ m_{ddsau}=8,3+345-0,25.2=352,8\left(g\right)\)
\(n_{HCl\left(dư\right)}=0,6-0,25.2=0,1\left(mol\right)\\ \Rightarrow m_{ddHCl}=0,1.36,5=3,65\left(g\right)\\ C\%_{ddHCl\left(dư\right)}=\dfrac{3,65}{352,8}.100\approx1,035\%\\ C\%_{ddAlCl_3}=\dfrac{13,35}{352,8}.100\approx3,784\%\\ C\%_{ddFeCl_2}=\dfrac{12,7}{352,8}.100\approx3,6\%\)
