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Câu 5. a) \(SO_2+\dfrac{1}{2}O_2-^{t^o,V_2O_5}\rightarrow SO_3\)
\(n_{SO_3}=n_{SO_2}=0,1\left(mol\right)\)
\(SO_3+H_2O\rightarrow H_2SO_4\)
\(n_{H_2SO_4}=n_{SO_3}=0,1\left(mol\right)\)
=> \(CM_{H_2SO_4}=\dfrac{0,1}{0,2}=0,5M\)
b) \(n_{Zn}=0,05\left(mol\right)\)
\(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
Lập tỉ lệ : \(\dfrac{0,05}{1}< \dfrac{0,1}{1}\)=> Sau phản ứng H2SO4 dư
=> \(m_{H_2SO_4\left(dư\right)}=\left(0,1-0,05\right).98=4,9\left(g\right)\)
Câu 5 . \(n_{Al_2O_3}=0,2\left(mol\right);n_{H_2SO_4}=0,8\left(mol\right)\)
\(Al_2O_3+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2O\)
Lập tỉ lệ: \(\dfrac{0,2}{1}< \dfrac{0,8}{3}\) => Sau phản ứng H2SO4 dư
\(m_{H_2SO_4}=\left(0,8-0,2.3\right).98=19,6\left(g\right)\)
b)\(n_{Al_2\left(SO_4\right)_3}=n_{Al_2O_3}=0,2\left(mol\right)\)
\(m_{Al_2\left(SO_4\right)_3}=0,2.342=68,4\left(g\right)\)
a) \(PTHH:2SO_2+O_2\xrightarrow[V_2O_5]{450^oC}2SO_3\)
\(n_{SO_2}=\dfrac{32}{64}=0,5\left(mol\right)\\ n_{O_2}=\dfrac{10}{32}=0,3125\left(mol\right)\)
Lập tỉ lệ: \(\dfrac{n_{SO_2}}{2}< \dfrac{n_{O_2}}{1}\left(\dfrac{0,5}{2}< 0,3125\right)\)
=> SO2 hết O2 dư
Theo pt: \(n_{O_2\left(pư\right)}=\dfrac{n_{SO_2}.2}{3}=\dfrac{0,5.1}{2}=0,25\left(mol\right)\)
\(n_{O_2\left(dư\right)}=0,3125-0,25=0,0625\left(mol\right)\\ m_{O_2}=0,0625.32=2\left(g\right)\)
c) Theo pt, ta có:\(n_{SO_3}=n_{SO_2}=0,5\left(mol\right)\)
\(m_{SO_3}=0,5.80=40\left(g\right)\)
nNaOH = 0,1.0,3 = 0,03 (mol)
Gọi \(\left\{{}\begin{matrix}n_{Na_2SO_3}=a\left(mol\right)\\n_{NaHSO_3}=b\left(mol\right)\end{matrix}\right.\)
=> 126a + 104b = 2,3
Bảo toàn Na: 2a + b = 0,03
=> a = 0,01 (mol); b = 0,01 (mol)
Bảo toàn S: \(n_{SO_2}=0,02\left(mol\right)\)
\(n_{CuSO_4}=\dfrac{19,2}{160}=0,12\left(mol\right)\)
Bảo toàn Cu: nCu = 0,12 (mol)
=> a = 0,12.64 = 7,68 (g)
Bảo toàn S: \(n_{H_2SO_4}=n_{CuSO_4}+n_{SO_2}=0,12+0,02=0,14\left(mol\right)\)
=> \(m_{H_2SO_4}=0,14.98=13,72\left(g\right)\)
=> \(b=m_{dd.H_2SO_4}=\dfrac{13,72.100}{98}=14\left(g\right)\)
Bảo toàn H: \(n_{H_2O}=n_{H_2SO_4}=0,14\left(mol\right)\)
BTKL: \(m_{Cu}+m_{O_2}+m_{H_2SO_4}=m_{CuSO_4}+m_{SO_2}+m_{H_2O}\)
=> mO2 = 19,2 + 0,02.64 + 0,14.18 - 7,68 - 13,72 = 1,6 (g)
=> \(n_{O_2}=\dfrac{1,6}{32}=0,05\left(mol\right)\)
=> \(V_{O_2}=0,05.22,4=1,12\left(l\right)\)
\(n_{H_2S\left(dktc\right)}=\dfrac{V}{22,4}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\\ PTHH:2H_2S+3O_2-^{t^o}>2SO_2+2H_2O\)
tỉ lệ: 2 : 3 : 2 : 2
n(mol) 0,5---->0,75------>0,5------->0,5
\(m_{SO_2}=n\cdot M=0,5\cdot64=32\left(g\right)\)
nMg = 5,76/24 = 0,24 (mol)
PTHH: 2Mg + O2 -> (t°) 2MgO
nMgO = 0,24 (mol)
mMgO = 0,24 . 40 = 9,6 (g)
nMg = 5,76 : 24 = 0,24 ( mol )
pthh : 2Mg+ O2 -t--> 2MgO
0,24->0,12-->0,24 (mol)
=> m = mMgO = 0,24 . 40 = 9,6 (g)
Bảo toàn e :
nO2 = 2 .nH2 = 2 . 2,24 /22,4 = 0,2 (mol)
=> khối lượng oxit = 14,51+ 0,2 . 32 = 20,91 (g)
PT: \(2K+2H_2O\rightarrow2KOH+H_2\)
\(Ba+2H_2O\rightarrow Ba\left(OH\right)_2+H_2\)
\(4K+O_2\underrightarrow{t^o}2K_2O\)
\(2Ba+O_2\underrightarrow{t^o}2BaO\)
Giả sử: \(\left\{{}\begin{matrix}n_K=x\left(mol\right)\\n_{Ba}=y\left(mol\right)\end{matrix}\right.\)
Theo PT: \(\Sigma n_{H_2}=\dfrac{1}{2}n_K+n_{Ba}=\dfrac{1}{2}x+y\left(mol\right)\)
Mà: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
\(\Rightarrow\dfrac{1}{2}x+y=0,1\Rightarrow\dfrac{1}{4}x+\dfrac{1}{2}y=0,05\left(1\right)\)
Theo PT: \(\Sigma n_{O_2}=\dfrac{1}{4}n_K+\dfrac{1}{2}n_{Ba}=\dfrac{1}{4}x+\dfrac{1}{2}y\left(mol\right)\)
\(\Rightarrow\Sigma n_{O_2}=0,05\left(mol\right)\)
Theo ĐLBT KL: \(a=m_{oxit}=m_X+m_{O_2}=14,51+0,05.32=16,11\left(g\right)\)
Bạn tham khảo nhé!
Ta có: \(n_{O_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
a, PT: \(4Na+O_2\underrightarrow{t^o}2Na_2O\)
______0,8___0,2___0,4 (mol)
b, a = mNa = 0,8.23 = 18,4 (g)
c, mNaOH = 0,4.40 = 16 (g)
\(\Rightarrow C\%_{NaOH}=\dfrac{16}{150}.100\%\approx10,67\%\)
Bạn tham khảo nhé!
PTHH: \(4FeS+7O_2\rightarrow^{t^o}2Fe_2O_3+4SO_2\uparrow\)
\(2SO_2+O_2\rightarrow^{t^o}2SO_3\)
\(SO_3+H_2O\rightarrow H_2SO_4\)
\(n_{H_2SO_4}=\frac{50.12,25\%}{98}=0,0625mol\)
Theo phương trình \(n_{SO_3}=n_{SO_2}=n_{H_2SO_4}=0,0625mol\)
\(\rightarrow m_{SO_2}=0,0625.64=4g\)
\(\rightarrow m_{SO_3}=0,0625.80=5g\)
Theo phương trình \(n_{FeS}=n_{SO_2}=0,0625mol\)
\(\rightarrow m_{FeS}=0,0625.88=5,5g\)