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PTHH: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
Ta có: \(\left\{{}\begin{matrix}n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\\n_{O_2}=\dfrac{12,8}{32}=0,4\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,2}{3}< \dfrac{0,4}{2}\) \(\Rightarrow\) Oxi còn dư, Fe p/ứ hết
\(\Rightarrow n_{O_2\left(dư\right)}=0,4-\dfrac{2}{15}=\dfrac{4}{15}\left(mol\right)\)
+) Theo PTHH: \(\left\{{}\begin{matrix}n_{O_2}=\dfrac{2}{15}\left(mol\right)\\n_{Fe_3O_4}=\dfrac{1}{15}\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}V_{kk}=\dfrac{2}{15}\cdot22,4\cdot5\approx14,93\left(l\right)\\m_{Fe_3O_4}=\dfrac{1}{15}\cdot232\approx15,47\left(g\right)\end{matrix}\right.\)
\(a,m_C=48\left(g\right)\rightarrow n_C=\dfrac{m_C}{M_C}=\dfrac{48}{12}=4\left(mol\right)\)
\(V_{O_2}=44,8\left(l\right)\rightarrow n_{O_2}=\dfrac{V_{O_2}}{22,4}=\dfrac{44,8}{22,4}=2\left(mol\right)\)
\(PTHH:C+O_2\underrightarrow{t^o}CO_2\)
\(pt:\) \(1mol\) \(1mol\)
\(đb:\) \(4mol\) \(2mol\)
Xét tỉ lệ:
\(\dfrac{n_{C\left(đb\right)}}{n_{C\left(pt\right)}}=\dfrac{4}{1}=4>\dfrac{n_{O_2\left(đb\right)}}{n_{O_2\left(pt\right)}}=\dfrac{2}{1}=2\)
\(\Rightarrow\) \(O_2\) hết, \(C\) dư.
\(b,PTHH:C+O_2\underrightarrow{t^o}CO_2\)
\(pt:\) \(1mol\) \(1mol\)
\(đb:\) \(2mol\) \(2mol\)
\(\Rightarrow m_{CO_2}=n_{CO_2}.M_{CO_2}=2.\left(1.C+2.O\right)=2.\left(1.12+2.16\right)=88\left(g\right)\)
\(a.n_C=\dfrac{48}{12}=4\left(mol\right);n_{O_2}=\dfrac{44,8}{22,4}=2\left(mol\right)\\ C+O_2\xrightarrow[t^0]{}CO_2\)
Theo pt:\(\dfrac{4}{1}>\dfrac{2}{1}\Rightarrow C\) dư, O2 pư hết
\(b.C+O_2\xrightarrow[t^0]{}CO_2\\ \Rightarrow n_{CO_2}=n_{O_2}=2mol\\ m_{CO_2}=2.44=88\left(g\right)\)
số oxh của Fe cả quá trình k đổi..bảo toàn e =>nCaC03=nC02=n0=n02/2=0,05 mol
a, PTHH: S + O2 -> (t°) SO2
b, nS = 6,4/32 = 0,2 (mol)
nO2 = 6,72/22,4 = 0,3 (mol)
LTL: 0,2 < 0,3 => O2 dư
nO2 (pư) = nSO2 = nS = 0,2 (mol)
mO2 (dư) = (0,3 - 0,2) . 32 = 3,2 (g)
c, mSO2 = 64 . 0,2 = 12,8 (g)
a, \(S+O_2\underrightarrow{t^o}SO_2\)
\(nS=\dfrac{6,4}{32}=0,2\left(mol\right)\)
\(nO_2=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
\(\dfrac{0,2}{1}< \dfrac{0,3}{1}\) => oxi dư
\(nO_{2\left(dư\right)}=0,1\left(mol\right)\)
\(mO_{2\left(dư\right)}=0,1.32=3,2\left(g\right)\)
\(nSO_2=nS=0,2\left(mol\right)\)
\(mSO_2=0,2.64=12,8\left(g\right)\)
Ta có: \(n_{Mg}=\dfrac{2,4}{24}=0,1\left(mol\right)\)
\(n_{O_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
a. PTHH: 2Mg + O2 ---> 2MgO
Ta thấy: \(\dfrac{0,1}{2}< \dfrac{0,5}{1}\)
Vậy oxi dư, magie hết.
Theo PT: \(n_{O_2}=\dfrac{1}{2}.n_{Mg}=\dfrac{1}{2}.0,1=0,05\left(mol\right)\)
=> \(m_{O_{2_{dư}}}=0,5.32-0,05,32=14,4\left(g\right)\)
b. Theo PT: \(n_{MgO}=n_{Mg}=0,1\left(mol\right)\)
=> \(m_{MgO}=0,1.40=4\left(g\right)\)
nAl=\(\dfrac{5,4}{27}\)=0,2mol
nO2=\(\dfrac{4,48}{22,4}\)=0,2mol
PTHH:
4Al + 3O2--to->2Al2O3
Tỉ lệ \(\dfrac{0,2}{4}\) <\(\dfrac{0,2}{3}\)->Al hết O2 dưtính theo Al
=>m O2=\(\dfrac{1}{60}\).32=\(\dfrac{8}{15}\)g
2KMnO4-to>K2MnO4+MnO2+O2
0,4--------------------------------------0,2
m KMnO4=0,4.158=63,2g
.
\(n_P=\dfrac{6,2}{31}=0,2\left(mol\right)\\ n_{O_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\\ PTHH:4P+5O_2\underrightarrow{t^o}2P_2O_5\\ LTL:\dfrac{0,2}{4}< \dfrac{0,4}{5}\Rightarrow O_2dư\)
\(n_{O_2\left(pư\right)}=\dfrac{5}{4}n_P=\dfrac{5}{4}.0,2=0,25\left(mol\right)\\ n_{O_2\left(dư\right)}=0,4-0,25=0,15\left(mol\right)\)
\(n_{P_2O_5\left(lt\right)}=\dfrac{1}{2}n_P=\dfrac{1}{2}.0,2=0,1\left(mol\right)\\ m_{P_2O_5\left(lt\right)}=0,1.142=14,2\left(g\right)\\ m_{P_2O_5\left(tt\right)}=0,1.142.80\%=11,36\left(g\right)\)
PT: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
Ta có: \(n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\)
\(n_{O_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,3}{3}< \dfrac{0,3}{2}\) , ta được O2 dư.
Mà: H% = 80% \(\Rightarrow n_{Fe\left(pư\right)}=0,3.80\%=0,24\left(mol\right)\)
\(\Rightarrow n_{Fe\left(dư\right)}=0,3.0,24=0,06\left(mol\right)\)
Theo PT: \(n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=0,1\left(mol\right)\)
Chất rắn thu được gồm Fe dư và Fe3O4.
⇒ mcr = mFe (dư) + mFe3O4 = 0,06.56 + 0,1.232 = 26,56 (g)
Bạn tham khảo nhé!
nO2 = 8.96/22.4 =0.4 mol
nFe = 11.2 : 56 = 0.2 mol
PTHH: 3Fe + 2O2 -----> Fe2O3
Theo PT: 3 - 2 -1 (mol)
BC: 0.2 - 0.4 (mol)
Ta có: \(\dfrac{3}{0.2}\)>\(\dfrac{2}{0.4}\)
Suy ra: số mol của Fe dư