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a) \(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)
PTHH: Zn + 2HCl --> ZnCl2 + H2
0,1-->0,2------>0,1-->0,1
=> VH2 = 0,1.22,4 = 2,24 (l)
mZnCl2 = 0,1.136 = 13,6 (g)
b) \(C\%_{dd.HCl}=\dfrac{0,2.36,5}{200}.100\%=3,65\%\)
c) \(n_{O_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
PTHH: 2H2 + O2 --to--> 2H2O
Xét tỉ lệ: \(\dfrac{0,1}{2}< \dfrac{0,15}{1}\) => H2 hết, O2 dư
PTHH: 2H2 + O2 --to--> 2H2O
0,1--------------->0,1
=> mH2O = 0,1.18 = 1,8 (g)
a) \(n_{Fe}=\dfrac{12}{56}=\dfrac{3}{14}\left(mol\right)\)
PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(\dfrac{3}{14}\)---------------------->\(\dfrac{3}{14}\)
\(\Rightarrow V_{H_2}=\dfrac{3}{14}.22,4=4,8\left(l\right)\)
b) \(n_{ZnO}=\dfrac{8,1}{81}=0,1\left(mol\right)\)
PTHH: \(ZnO+H_2\xrightarrow[]{t^o}Zn+H_2O\)
Xét tỉ lệ: \(0,1< \dfrac{3}{14}\Rightarrow H_2\) dư
Theo PT: \(n_{Zn}=n_{ZnO}=0,1\left(mol\right)\Rightarrow m_{Zn}=0,1.65=6,5\left(g\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(1mol\) \(1mol\)
\(\dfrac{3}{14}mol\) \(\dfrac{3}{14}mol\)
\(a)n_{Fe}=\dfrac{m}{M}=\dfrac{12}{56}\approx0,21=\dfrac{3}{14}\left(mol\right)\)
\(V_{H_2}=n.22,4=\dfrac{3}{14}.22,4=4,8\left(l\right)\)
\(b)n_{ZnO}=\dfrac{m}{M}=\dfrac{8,1}{81}=0,1\left(mol\right)\)
\(ZnO+H_2\rightarrow Zn+H_2O\)
\(1mol\) \(1mol\) \(1mol\)
\(0,1mol\) \(0,1mol\) \(0,1mol\)
\(\text{Ta thấy }H_2\text{ dư,ZnO phản ứng hết.Bài toán tính theo ZnO}\)
\(m_{Zn}=n.M=0,1.65=6,5\left(g\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
Ta có: 56nFe + 65nZn = 35,4 (1)
Theo PT: \(n_{H_2}=n_{Fe}+n_{Zn}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{Fe}=0,4\left(mol\right)\\n_{Zn}=0,2\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Fe}=0,4.56=22,4\left(g\right)\\m_{Zn}=0,2.65=13\left(g\right)\end{matrix}\right.\)
a,\(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right);n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
PTHH: Fe + 2HCl → FeCl2 + H2
Mol: 0,15 0,3
Ta có: \(\dfrac{0,2}{1}>\dfrac{0,15}{1}\) ⇒ H2 pứ hết,Fe dư
\(V_{H_2}=3,36\left(l\right)\) (đề cho)
b, ko tính đc k/lg dd ,chỉ tính đc thể tích dd
\(V_{ddHCl}=\dfrac{0,2}{1}=0,2\left(l\right)=200\left(ml\right)\)
\(n_{Zn}=\dfrac{m}{M}=\dfrac{3,25}{65}=0,05\left(mol\right)\)
\(PTHH:Zn+2HCl\rightarrow ZnCl_2+H_2\)
1 2 1 1
0,05 0,1 0,05 0,05
a) \(V_{H_2}=n.24,79=0,05.24,79=1,2395\left(l\right)\)
\(m_{ZnCl_2}=n.M=0,05.\left(65+35,5.2\right)=6,8\left(g\right)\)
b) \(PTHH:CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
Ta cos tỉ lệ: \(\dfrac{0,1}{1}>\dfrac{0,05}{1}\Rightarrow\) CuO dư.
Theo ptr, ta có: \(n_{Cu}=n_{H_2}=0,05mol\\ \Rightarrow m_{Cu}=n.M=0,05.64=3,2\left(g\right).\)
a, PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
Ta có: \(n_{Zn}=\dfrac{3,25}{65}=0,05\left(mol\right)\)
THeo PT: \(n_{ZnCl_2}=n_{H_2}=n_{Zn}=0,05\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,05.24,79=1,2395\left(l\right)\)
\(m_{ZnCl_2}=0,05.136=6,8\left(g\right)\)
b, Ta có: \(n_{CuO}=\dfrac{8}{80}=0,1\left(mol\right)\)
PT: \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
Xét tỉ lệ: \(\dfrac{0,1}{1}>\dfrac{0,05}{1}\), ta được CuO dư.
Theo PT: \(n_{Cu}=n_{H_2}=0,05\left(mol\right)\Rightarrow m_{Cu}=0,05.64=3,2\left(g\right)\)
\(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)
a. \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
Theo PTHH: \(n_{ZnSO_4}=n_{Zn}=0,1\left(mol\right)\)
\(\Rightarrow m_{muối}=0,1.161=16,1\left(g\right)\)
b. \(n_{H_2thu.được}=n_{Zn}=0,1\left(mol\right)\)
\(H_2+\dfrac{1}{2}O_2\underrightarrow{t^o}H_2O\)
0,1 0,05
\(V_{O_2}=0,05.22,4=1,12\left(l\right)\)
\(\Rightarrow V_{không.khí}=1,12.5=5,6\left(l\right)\)
\(n_{Mg}=a;n_{Fe}=0,5a;n_{Zn}=b\\ a\left(24+28\right)+65b=52a+65b=44,2\\ 1,5a+b=\dfrac{24,64}{22,4}1,1\\ a=0,6;b=0,2\\ \%m_{Mg}=\dfrac{24a}{44,2}=32,58\%\\ \%m_{Fe}=\dfrac{28a}{44,2}=38\%\\ \%m_{Zn}=29,42\%\\ m_{ddacid}=\dfrac{98\left(1,5a+b\right)}{0,08}=1347,5g\\ m_{ddsau}=1389,5g\\ C\%_{MgCl_2}=\dfrac{95a}{1389,5}=4,10\%\\ C\%_{FeCl_2}=\dfrac{127.0,5a}{1389,5}=2,74\%\\ C\%_{ZnCl_2}=\dfrac{136b}{1389,5}=1,96\%\)
a+b+c) PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
Ta có: \(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)=n_{ZnCl_2}=n_{H_2}\)
\(\Rightarrow\left\{{}\begin{matrix}m_{ZnCl_2}=0,1\cdot136=13,6\left(g\right)\\V_{H_2}=0,1\cdot22,4=2,24\left(l\right)\end{matrix}\right.\)
d) PTHH: \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
Theo PTHH: \(n_{H_2}=n_{Cu}=0,1\left(mol\right)\)
\(\Rightarrow m_{Cu}=0,1\cdot64=6,4\left(g\right)\)
a.
\(n_{H_2}=\dfrac{3,36}{22,4}=0,15mol\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,15 0,15 ( mol )
\(m_{Zn}=0,15.65=9,75g\)
b.
\(n_{Fe_2O_3}=\dfrac{6,4}{160}=0,04mol\)
\(Fe_2O_3+3H_2\rightarrow\left(t^o\right)2Fe+3H_2O\)
0,04 < 0,15 ( mol )
0,04 0,08 ( mol )
\(m_{Fe}=0,08.56=4,48g\)
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