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Gọi a, b lần lượt là mol của Al và Zn
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
a 1,5a
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
b b
\(\Rightarrow\left\{{}\begin{matrix}27a+65b=9,2\\1,5a+b=\dfrac{5,6}{22,4}\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\)
\(\%m_{Al}=\dfrac{0,1.27}{9,2}.100\%=29,35\%\)
\(\%m_{Zn}=\dfrac{0,1.65}{9,2}.100\%=70,35\%\)
b. \(n_{H_2}=0,25mol\) \(\Rightarrow n_{HCl}=0,5mol\)
\(\Rightarrow m_{HCl}=0,5.36,5=18,25g\)
Ta có: \(10\%=\dfrac{18,25}{m_{dd}}.100\%\)
\(\Leftrightarrow m_{dd}=182,5g\)
a) Gọi `n_{Al} = a (mol); n_{Fe} = b (mol)`
PTHH:
`2Al + 3H_2SO_4 -> Al_2(SO_4)_3 + 3H_2`
`Fe + H_2SO_4 -> FeSO_4 + H_`
b) `n_{H_2} = (0,56)/(22,4) = 0,025 (mol)`
Theo PT: `n_{H_2} = n_{Fe} + 3/2 n_{Al}`
`=> b + 1,5a = 0,025`
Giải hpt \(\left\{{}\begin{matrix}27a+56b=0,83\\1,5a+b=0,025\end{matrix}\right.\Leftrightarrow a=b=0,01\)
=> \(\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,01.27}{0,83}.100\%=32,53\%\\\%m_{Fe}=100\%-32,53\%=67,47\%\end{matrix}\right.\)
\(n_{HCl}=2.0,4=0,8(mol)\\ n_{Fe}=x(mol);n_{Al}=y(mol)\\ \Rightarrow 56x+27y=11(1)\\ Fe+2HCl\to FeCl_2+H_2\\ 2Al+6HCl\to 2AlCl_3+3H_2\\ \Rightarrow 2x+3y=0,8(2)\\ (1)(2)\Rightarrow x=0,1(mol);y=0,2(mol)\)
\(a,\Sigma n_{H_2}=x+1,5y=0,4(mol)\\ \Rightarrow V_{H_2}=0,4.22,4=8,96(l)\\ b,m_{Fe}=0,1.56=5,6(g);m_{Al}=0,2.27=5,4(g)\\ c,m_{dd_{HCl}}=400.1,12=448(g)\\ n_{FeCl_2}=0,1(mol);n_{AlCl_3}=0,2(mol)\\ \Rightarrow C\%_{FeCl_2}=\dfrac{0,1.127}{5,6+448-0,1.2}.100\%=2,8\%\\ C\%_{AlCl_3}=\dfrac{0,2.133,5}{5,4+448-0,3.2}.100\%=5,9\%\)
a, \(Fe+2HCl\rightarrow FeCl_2+H_2\)
b, \(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)
Theo PT: \(n_{Fe}=n_{H_2}=0,4\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{0,4.56}{35}.100\%=64\%\\\%m_{Cu}=36\%\end{matrix}\right.\)
Ta có nH2 = 3,36/22,4 = 0,15 mol
Fe +2 HCl -> FeCl2 + H2
0,15. 0,3 <-. 0,15. ( Mol)
=> mFe = 0,15 × 56 = 8,4g
=> %Fe = 8,4/15×100% = 56%
=> %Cu = 100% - 56% = 44%
=>VHCl =1\0,3=10\3 l
PTHH : 2Fe + 6HCl --> 2FeCl3 + 3H2 (1)
nH2 = \(\dfrac{3.36}{22.4}=0.15\left(mol\right)\)
Từ (1) -> nFe = \(\dfrac{2}{3}n_{H_2}=0.1\left(mol\right)\)
-> mFe = n.M = 0,1 . 56 = 5.6 (g) => %mFe = \(\dfrac{5.6}{15}x100\%\approx37.3\%\)
-> %mCu = 100% - 37.3% = 62.7 %
\(n_{Fe} = a(mol) ; n_{Mg} = b(mol)\\ \Rightarrow 56a + 24b = 16,8 - 6,4 = 10,4(1)\\ Fe + 2HCl \to FeCl_2 + H_2\\ Mg + 2HCl \to MgCl_2 + H_2\\ n_{H_2} = a + b = \dfrac{6,72}{22,4} = 0,3(2)\)
Từ (1)(2) suy ra: a = 0,1 ; b = 0,2
Vậy :
\(\%m_{Fe} = \dfrac{0,1.56}{16,8}.100\% = 33,33\%\\ \%m_{Mg} = \dfrac{0,2.24}{16,8}.100\% = 28,57\%\\ \%m_{Cu} = 100\% - 33,33\% - 28,57\% = 38,1\%\)
\(\text{Đặt }\left\{{}\begin{matrix}n_{Al}=x\left(mol\right)\\n_{Fe}=y\left(mol\right)\end{matrix}\right.\\ n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\\ a,PTHH:\left\{{}\begin{matrix}2Al+6HCl\rightarrow2AlCl_3+3H_2\\Fe+2HCl\rightarrow FeCl_2+H_2\end{matrix}\right.\\ b,\text{Theo đề ta có HPT: }\left\{{}\begin{matrix}27x+56y=8,3\\\dfrac{3}{2}x+y=0,25\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,1\left(mol\right)\\y=0,1\left(mol\right)\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}\%_{Al}=\dfrac{0,1\cdot27}{8,3}\approx32,53\%\\\%_{Fe}\approx67,47\%\end{matrix}\right.\)
\(c,\left\{{}\begin{matrix}n_{AlCl_3}=0,1\left(mol\right)\\n_{FeCl_2}=0,1\left(mol\right)\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}m_{AlCl_3}=0,1\cdot133,5=13,35\left(g\right)\\m_{FeCl_2}=0,1\cdot127=12,7\left(g\right)\end{matrix}\right.\\ \Rightarrow\sum m_{muối}=13,35+12,7=26,05\left(g\right)\)
a,\(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
PTHH: Zn + 2HCl → ZnCl2 + H2
Mol: x x
PTHH: Fe + 2HCl → FeCl2 + H2
Mol: y y
Ta có: \(\left\{{}\begin{matrix}65x+56y=30,7\\x+y=0,5\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,3\left(mol\right)\\y=0,2\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\%m_{Zn}=\dfrac{0,3.65.100\%}{30,7}=63,52\%;\%m_{Fe}=100\%-63,52\%=36,48\%\)
b,
PTHH: Zn + 2HCl → ZnCl2 + H2
Mol: 0,3 0,6
PTHH: Fe + 2HCl → FeCl2 + H2
Mol: 0,2 0,4
nHCl = 0,6+0,4 = 1 (mol)
\(V_{ddHCl}=\dfrac{1}{2}=0,5\left(l\right)=500\left(ml\right)\)