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a)
Khí thoát ra: CH4
\(\%V_{CH_4} = \dfrac{6,72}{16,8}.100\% = 40\%\\ \%V_{C_2H_4} = 100\% - 40\% = 60\%\)
b)
\(n_{C_2H_4} = \dfrac{16,8-6,72}{22,4} = 0,45(mol)\\ C_2H_4 + Br_2 \to C_2H_4Br_2\\ n_{Br_2} = n_{C_2H_4} = 0,45(mol)\\ \Rightarrow C_{M_{Br_2}} = \dfrac{0,45}{2} = 0,225M\\ c) n_{C_2H_4Br_2} = n_{C_2H_4} = 0,45(mol)\\ \Rightarrow n_{C_2H_4Br_2} = 0,45.188 = 84,6(gam)\)
Bài 4:
a) n(hỗn hợp khí)= 16,8/22,4=0,75(mol)
- Khí thoát ra là khí CH4.
=> nCH4=6,72/22,4=0,3(mol)
nC2H4=0,75-0,3=0,45(mol)
- Số mol tỉ lệ thuận với thể tích.
%V(CH4)=%nCH4= (0,3/0,75).100=40%
=> %V(C2H4)=100% - 40%=60%
b) PTHH: C2H4 + Br2 -> C2H4Br2
nC2H4Br2= nBr2=nC2H4=0,45(mol)
=>VddBr2= 0,45/2=0,225(l)
c) mC2H4Br2=0,45. 188= 84,6(g)
\(n_{Br_2}=\dfrac{4}{160}=0,025\left(mol\right);n_{hh}=\dfrac{2,8}{22,4}=0,125\left(mol\right)\)
PTHH: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
0,025<-0,125
\(\Rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,025}{0,125}.100\%=20\%\\\%V_{CH_4}=100\%-20\%=80\%\end{matrix}\right.\)
a, \(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
b, - Khí thoát ra là CH4 ⇒ VCH4 = 6,72 (l)
\(\Rightarrow\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{6,72}{13,44}.100\%=50\%\\\%V_{C_2H_2}=50\%\end{matrix}\right.\)
a. PTHH: \(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
a. Vì CH4 không phản ứng với dd Br2 nên
\(V_{CH_4}=6,72\left(l\right)\)
\(\%V_{CH_4}=\dfrac{6,72}{13,44}x100\%=50\%\)
\(\%V_{C_2H_2}=100\%-50\%=50\%\)
1. \(n_{Br_2}=0,4.0,5=0,2\left(mol\right)\)
PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
Theo PT: \(n_{C_2H_4}=n_{Br_2}=0,2\left(mol\right)\Rightarrow V_{C_2H_4}=0,2.22,4=4,48\left(l\right)\)
2. \(n_{C_2H_4Br_2}=\dfrac{9,4}{188}=0,05\left(mol\right)\)
PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
Theo PT: \(n_{C_2H_4}=n_{C_2H_4Br_2}=0,05\left(mol\right)\)
\(\Rightarrow\%V_{C_2H_4}=\dfrac{0,05.22,4}{1,4}.100\%=80\%\)
\(\Rightarrow\%V_{CH_4}=100-80=20\%\)
a, \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
b, \(n_{C_2H_4Br_2}=\dfrac{1,88}{188}=0,01\left(mol\right)\)
Theo PT: \(n_{C_2H_4}=n_{C_2H_4Br_2}=0,01\left(mol\right)\Rightarrow V_{C_2H_4}=0,01.22,4=0,224\left(l\right)\)
\(\Rightarrow V_{CH_4}=20-0,224=19,776\left(l\right)\)
c, \(\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,224}{20}.100\%=1,12\%\\\%V_{CH_4}=98,88\%\end{matrix}\right.\)
d, \(n_{Br_2}=n_{C_2H_4Br_2}=0,01\left(mol\right)\Rightarrow C_{M_{Br_2}}=\dfrac{0,01}{0,2}=0,05\left(M\right)\)
Khí thoát ra là metan
\(\%V_{CH_4} = \dfrac{5,6}{13,44}.100\% =41,67\%\\ \%V_{C_2H_4} = 100\% - 41,67\% = 58,33\%\\ b) V_{C_2H_2} = 13,44 -5,6 = 7,84(lít)\\ n_{C_2H_2} = \dfrac{7,84}{22,4} = 0,35(mol)\\ C_2H_2 + 2Br_2 \to C_2H_2Br_4\\ n_{Br_2} = 2n_{C_2H_2} = 0,7(mol)\\ \Rightarrow C_{M_{Br_2}} = \dfrac{0,7}{0,25} = 2,8M\\ c)\)
\(CH_4 + 2O_2 \xrightarrow{t^o} CO_2 + 2H_2O\\ C_2H_4 + 3O_2 \xrightarrow{t^o} 2CO_2 + 2H_2O\\ V_{O_2} = 2V_{CH_4} + 3V_{C_2H_4} = 5,6.2 + 7,84.3 = 34,72(lít)\)
\(n_{Br_2}=\dfrac{20}{160}=0,125\left(mol\right)\)
PTHH: C2H4 + Br2 ---> C2H4Br2
0,125 0,125
\(\%V_{C_2H_4}=\dfrac{0,125.22,4}{5,6}=50\%\\ \%V_{CH_4}=100\%-50\%=50\%\)
a) \(n_{C_2H_4Br_2}=\dfrac{37,6}{188}=0,2\left(mol\right)\)
PTHH: C2H4 + Br2 ---> C2H4Br2
0,2<---0,2<------0,2
b) \(\left\{{}\begin{matrix}V_{C_2H_4}=0,2.24,79=4,958\left(l\right)\\V_{CH_4}=20-4,958=15,042\left(l\right)\end{matrix}\right.\)
c) \(\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{4,958}{20}.100\%=24,79\%\\\%V_{CH_4}=100\%-24,79\%=75,21\%\end{matrix}\right.\)
d) \(V_{\text{dd}Br_2}=\dfrac{0,2}{0,2}=1\left(l\right)\)
a, \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
b, \(n_{C_2H_4Br_2}=\dfrac{37,6}{188}=0,2\left(mol\right)\)
\(n_{C_2H_4}=n_{C_2H_4Br_2}=0,2\left(mol\right)\Rightarrow V_{C_2H_4}=0,2.22,4=4,48\left(l\right)\)
\(\Rightarrow V_{CH_4}=20-4,48=15,52\left(l\right)\)
c, \(\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{4,48}{20}.100\%=22,4\%\\\%V_{CH_4}=77,6\%\end{matrix}\right.\)
d, \(n_{Br_2}=n_{C_2H_4Br_2}=0,2\left(mol\right)\Rightarrow V_{ddBr_2}=\dfrac{0,2}{0,2}=1\left(l\right)\)
a) Khí thoát ra là CH4
\(\%V_{CH_4} = \dfrac{6,72}{13,44}.100\% = 50\%\\ \%V_{C_2H_4} = 100\% -50\% = 50\%\\ b)\\ C_2H_4 + Br_2 \to C_2H_4Br_2\\ n_{Br_2} = n_{C_2H_4}= \dfrac{13,44.50\%}{22,4} = 0,3(mol)\\ C_{M_{Br_2}} = \dfrac{0,3}{0,2} = 1,5M\)