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\(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\\ Mg+2HCl\rightarrow MgCl_2+H_2\\ n_{HCl}=2.0,2=0,4\left(mol\right)\\ a,V_{ddHCl}=\dfrac{0,4}{2}=0,2\left(l\right)\\ b,V_{ddMgCl_2}=V_{ddHCl}=0,2\left(l\right)\\ n_{MgCl_2}=n_{Mg}=0,2\left(mol\right)\\ C_{MddMgCl_2}=\dfrac{0,2}{0,2}=1\left(M\right)\)
1:
a) \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
PTHH: \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\uparrow\)
______0,2------>0,2------------------->0,2_____(mol)
=> \(V_{H_2}=0,2.22,4=4,48\left(l\right)\)
b) \(V_{ddH_2SO_4}=\dfrac{0,2}{1}=0,2\left(l\right)\)
2:
a)
\(n_{HCl}=2.0,2=0,4\left(mol\right)\)
PTHH: \(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)
______0,2<------0,4------------------>0,2______(mol)
=> \(m_{Mg}=0,2.24=4,8\left(g\right)\)
b) \(V_{H_2}=0,2.22,4=4,48\left(l\right)\)
Câu 2:
a, \(n_{Fe_2O_3}=\dfrac{6,4}{160}=0,04\left(mol\right)\)
\(n_{H_2SO_4}=0,5.1=0,5\left(mol\right)\)
PT: \(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)
Xét tỉ lệ: \(\dfrac{0,04}{1}< \dfrac{0,5}{3}\), ta được H2SO4 dư.
Vậy: Fe2O3 tan hết.
b, Theo PT: \(\left\{{}\begin{matrix}n_{Fe_2\left(SO_4\right)_3}=n_{Fe_2O_3}=0,04\left(mol\right)\\n_{H_2SO_4\left(pư\right)}=3n_{Fe_2O_3}=0,12\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{H_2SO_4\left(dư\right)}=0,5-0,12=0,38\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}C_{M_{Fe_2\left(SO_4\right)_3}}=\dfrac{0,04}{0,5}=0,08\left(M\right)\\C_{M_{H_2SO_4\left(dư\right)}}=\dfrac{0,38}{0,5}=0,76\left(M\right)\end{matrix}\right.\)
Câu 3:
a, \(n_{Ba\left(OH\right)_2}=0,2.1=0,2\left(mol\right)\)
\(n_{H_2SO_4}=0,3.0,72=0,216\left(mol\right)\)
PT: \(Ba\left(OH\right)_2+H_2SO_4\rightarrow BaSO_{4\downarrow}+2H_2O\)
Xét tỉ lệ: \(\dfrac{0,2}{1}< \dfrac{0,216}{1}\), ta được H2SO4 dư.
Theo PT: \(n_{BaSO_4}=n_{Ba\left(OH\right)_2}=0,2\left(mol\right)\Rightarrow m_{BaSO_4}=0,2.233=46,6\left(g\right)\)
b, Theo PT: \(n_{H_2SO_4\left(pư\right)}=n_{Ba\left(OH\right)_2}=0,2\left(mol\right)\Rightarrow n_{H_2SO_4\left(dư\right)}=0,216-0,2=0,016\left(mol\right)\)
\(\Rightarrow C_{M_{H_2SO_4\left(dư\right)}}=\dfrac{0,016}{0,2+0,3}=0,032\left(M\right)\)
c, - Nhúng quỳ tím vào dd thấy quỳ hóa đỏ do H2SO4 dư.
Bài 9 :
\(a) n_{Fe_2O_3} = \dfrac{3,2}{160}=0,02(mol)\\ Fe_2O_3 + 3H_2SO_4 \to Fe_2(SO_4)_3 + 3H_2O\\ n_{H_2SO_4} = 3n_{Fe_2O_3} = 0,06(mol)\\ m_{dd\ H_2SO_4} = \dfrac{0,06.98}{19,6\%} = 30(gam)\\ b) \text{Chất tan : } Fe_2(SO_4)_3\\ n_{Fe_2(SO_4)_3} = n_{Fe_2O_3} = 0,02(mol)\\ m_{Fe_2(SO_4)_3} = 0,02.400 =8(gam)\)
Bài 13 :
\(a)n_{Fe_2O_3} = \dfrac{9,6}{160} = 0,06(mol)\\ Fe_2O_3 + 6HCl \to 2FeCl_3 + 3H_2O\\ n_{HCl} = 6n_{Fe_2O_3} = 0,36(mol)\\ C\%_{HCl} = \dfrac{0,36.36,5}{150}.100\% = 8,76\%\\ \Rightarrow X = 8,76 b) n_{FeCl_3} = 2n_{Fe_2O_3} = 0,12(mol)\\ m_{FeCl_3} = 0,12.162,5 =19,5(gam)\)
nCuSO4=0,01 mol
Fe+CuSO4=> FeSO4+Cu
0,01 mol =>0,01 mol
mCu=0,01.64=0,64gam
FeSO4+2NaOH=>Fe(OH)2 +Na2SO4
0,01 mol=>0,02 mol
Vdd NaOH=0,02/1=0,02 lit
\(a)n_{H_2SO_4}=1.0,2=0,2\left(mol\right)\\Fe+H_2SO_4\xrightarrow[]{}FeSO_4+H_2\\ \Rightarrow n_{H_2SO_4}=n_{Fe}=n_{FeSO_4}=0,2mol\\ m_{Fe}=0,2. 56=11,2\left(g\right)\\ b)C_{MFeSO_4}=\dfrac{0,2}{0,2}=1\left(M\right)\)