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CH4 -> CO2
C2H6 -> 2 CO2
Gọi nCH4 = x mol, nC2H6 = y mol
x + y = 0,15 (1)
x + 2y = 0,2 (2)
Nên: x = 0,1 mol, y = 0,05 mol
Vậy: % VCH4 = 66,67 % => %VC2H6 = 33,33 %
\(n_{CH_4} = a\ mol ;n_{C_2H_6} = b\ mol\\ \Rightarrow a + b = \dfrac{3,36}{22,4}= 0,15(1)\\ CH_4 + 2O_2 \xrightarrow{t^o} CO_2 + 2H_2O\\ C_2H_6 + \dfrac{7}{2}O_2 \xrightarrow{t^o} 2CO_2 + 3H_2O\\ n_{CO_2} = a + 2b = \dfrac{4,48}{22,4} = 0,2(2)\\ (1)(2) \Rightarrow a = 0,1 ;b = 0,05\\ \Rightarrow \%V_{CH_4} = \dfrac{0,1}{0,15}.100\% = 66,67\%\\ \%V_{C_2H_6} = 100\% - 66,67\% = 33,33\%\)
\(n_{CH_4}=a\left(mol\right),n_{C_2H_6}=b\left(mol\right)\)
\(\Rightarrow a+b=0.15\left(mol\right)\left(1\right)\)
\(n_{CO_2}=\dfrac{4.48}{22.4}=0.2\left(mol\right)\)
\(\Rightarrow a+2b=0.2\left(2\right)\)
\(\left(1\right),\left(2\right):a=0.1,b=0.05\)
\(\%CH_4=\dfrac{0.1}{0.15}\cdot100\%=66.67\%\)
\(\%C_2H_6=33.33\%\)
Gọi x là số mol của CH 4 => V CH 4 = n.22,4 = 22,4x
y là số mol của H 2 => V H 2 = 22,4y
V hh = V H 2 + V CH 4 => 22,4x + 22,4y = 11,2
n H 2 O = m/M = 16,2/18 = 0,9 mol
n H 2 O = 2x + y = 0,9
Từ (1) và (2), ta có hệ phương trình:
22,4x + 22,4y = 11,2
2x + y = 0,9
Giải hệ phương trình ta có: x = 0,4( mol); y= 0,1 mol
V CH 4 = 22,4x = 22,4x0,4 = 8,96l
% V CH 4 = 8,96/11,2 x 100% = 80%
% V H 2 = 100% - 80% = 20%
a, PT: \(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)
\(2H_2+O_2\underrightarrow{t^o}2H_2O\)
Ta có: \(n_{CH_4}+n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\left(1\right)\)
Theo PT: \(n_{H_2O}=2n_{CH_4}+n_{H_2}=\dfrac{16,2}{18}=0,9\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{CH_4}=0,4\left(mol\right)\\n_{H_2}=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,4.22,4}{11,2}.100\%=80\%\\\%V_{H_2}=20\%\end{matrix}\right.\)
b, Theo PT: \(n_{CO_2}=n_{CH_4}=0,4\left(mol\right)\Rightarrow V_{CO_2}=0,4.22,4=8,96\left(l\right)\)
a, \(CH_4+2O_2\underrightarrow{t^o}CO_2+H_2O\)
\(2C_2H_2+5O_2\underrightarrow{t^o}4CO_2+2H_2O\)
Ta có: \(n_{CH_4}+n_{C_2H_2}=\dfrac{33,6}{22,4}=1,5\left(mol\right)\left(1\right)\)
Theo PT: \(n_{CO_2}=n_{CH_4}+2n_{C_2H_2}=\dfrac{56}{22,4}=2,5\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{CH_4}=0,5\left(mol\right)\\n_{C_2H_2}=1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,5.22,4}{33,6}.100\%\approx33,33\%\\\%V_{C_2H_2}\approx66,67\%\end{matrix}\right.\)
b, Theo PT: \(n_{O_2}=2n_{CH_4}+\dfrac{5}{2}n_{C_2H_2}=3,5\left(mol\right)\Rightarrow m_{O_2}=3,5.32=112\left(g\right)\)
\(n_{hh}=\dfrac{3,36}{22,4}=0,15mol\)
\(n_{CO_2}=\dfrac{4,48}{22,4}=0,2mol\)
\(\left\{{}\begin{matrix}n_{CH_4}=x\left(mol\right)\\n_{C_2H_2}=y\left(mol\right)\end{matrix}\right.\)
\(CH_4+2O_2\rightarrow CO_2+2H_2O\)
\(C_2H_2+\dfrac{5}{2}O_2\rightarrow2CO_2+H_2O\)
Từ hai pt trên:\(\Rightarrow\left\{{}\begin{matrix}x+y=0,15\\x+2y=0,2\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,1\\y=0,05\end{matrix}\right.\)
\(\%V_{CH_4}=\dfrac{0,1}{0,1+0,05}\cdot100\%=66,67\%\)
\(\%V_{C_2H_2}=100\%-66,67\%=33,33\%\)
\(n_{CO_2}=\dfrac{V_{CO_2}}{22,4}=\dfrac{4,48}{22,4}=0,2mol\)
Gọi \(n_{CH_4}\) là x \(\Rightarrow V_{CH_4}=22,4x\)
\(n_{C_2H_2}\) là y \(\Rightarrow V_{C_2H_2}=22,4y\)
\(CH_4+2O_2\rightarrow\left(t^o\right)CO_2+2H_2O\)
x x ( mol )
\(2C_2H_2+5O_2\rightarrow\left(t^o\right)4CO_2+2H_2O\)
y 2y ( mol )
Ta có:
\(\left\{{}\begin{matrix}22,4x+22,4y=3,36\\x+2y=0,2\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}x=0,1\\y=0,05\end{matrix}\right.\)
\(\Rightarrow V_{CH_4}=22,4.0,1=2,24l\)
\(\Rightarrow V_{C_2H_2}=22,4.0,05=1,12l\)
\(\%V_{CH_4}=\dfrac{2,24}{3,36}.100=66,67\%\)
\(\%V_{C_2H_2}=100\%-66,67\%=33,33\%\)
- Gọi mol metan và etan là x, y ( mol )
\(x+y=n_{hh}=\dfrac{V}{22,4}=0,25\left(mol\right)\)
Lại có : \(x+2y=n_{CO_2}=\dfrac{V}{22,4}=0,4\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}x=0,1\\y=0,15\end{matrix}\right.\) ( mol )
\(\Rightarrow\left\{{}\begin{matrix}m_{CH_4}=1,6\left(g\right)\\m_{C_2H_6}=4,5\left(g\right)\end{matrix}\right.\)
=> mhh = 6,1 ( g )
=> %mCH4 = ~ 26,22%
=> %mC2H6 = ~73,78%
Ta có : \(\%V_{CH4}=\dfrac{V}{Vhh}=40\%\)
=> %VC2H6 = 100 - %VCH4 = 60% .
PT: \(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)
\(2C_2H_6+5O_2\underrightarrow{t^o}4CO_2+6H_2O\)
Giả sử: \(\left\{{}\begin{matrix}n_{CH_4}=x\left(mol\right)\\n_{C_2H_6}=y\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow x+y=\dfrac{5,6}{22,4}=0,25\left(1\right)\)
Ta có: \(n_{CO_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)
Theo PT: \(\Sigma n_{CO_2}=n_{CH_4}+2n_{C_2H_6}\)
\(\Rightarrow x+2y=0,4\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,1\left(mol\right)\\y=0,15\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,1}{0,25}.100\%=40\%\\\%V_{C_2H_6}=60\%\end{matrix}\right.\)
\(\left\{{}\begin{matrix}\%m_{CH_4}=\dfrac{0,1.16}{0,1.16+0,15.30}.100\%\approx26,2\%\\\%m_{C_2H_6}\approx73,8\%\end{matrix}\right.\)
Bạn tham khảo nhé!
Tính % thể tích các khí :
% V C 2 H 2 = 0,448/0,896 x 100% = 50%
% V CH 4 = % V C 2 H 6 = 25%
\(Đặt:n_{CH_4}=a\left(mol\right),n_{C_2H_4}=b\left(mol\right)\)
\(\Rightarrow a+b=0.15\left(1\right)\)
\(n_{CO_2}=\dfrac{4.48}{22.4}=0.2\left(mol\right)\)
\(CH_4+2O_2\underrightarrow{t^0}CO_2+2H_2O\)
\(C_2H_4+3O_2\underrightarrow{t^0}2CO_2+2H_2O\)
\(\Rightarrow a+2b=0.2\left(2\right)\)
\(\left(1\right),\left(2\right):a=0.1,b=0.05\)
Vì : tỉ lệ thể tích tương ứng với tỉ lệ số mol :
\(\%n_{CH_4}=\dfrac{0.1}{0.15}\cdot100\%=66.67\%\)
\(\%n_{C_2H_4}=100-66.67=33.33\%\)
Chúc em học tốt !!
Đặt \(\left\{{}\begin{matrix}n_{CH_4}=x\left(mol\right)\\n_{C_2H_4}=y\left(mol\right)\end{matrix}\right.\)
\(\Sigma n_{hhkA}=\dfrac{3,36}{22,4}=0,15\\ \rightarrow x+y=0,15\left(1\right)\)
\(PTHH:CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)
(mol)........x....->...2x.......x..............2x
\(PTHH:C_2H_4+3O_2\underrightarrow{t^o}2CO_2+2H_2O\)
(mol)........y......->...3y...........2y........2y
\(\Sigma n_{CO_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\\ \rightarrow x+2y=0,2\)
Giải hpt (1) (2) ta được x=0,1 ; y=0,05
\(\%V_{CH_4}=\dfrac{0,1.22,4}{3,36}.100\%=66,67\%\\ \%V_{C_2H_4}=100\%-66,67\%=33,33\%\)