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`Zn + H_2 SO_4 -> ZnSO_4 + H_2`
`0,25` `0,25` `0,25` `(mol)`
`n_[Zn]=[16,25]/65=0,25(mol)`
`a)V_[H_2]=0,25.22,4=5,6(l)`
`b)C_[M_[H_2 SO_4]]=[0,25]/[0,3]~~0,8(M)`
`c)`
`H_2 + 3Fe_2 O_3` $\xrightarrow{t^o}$ `2Fe_3 O_4 + H_2 O`
`1/15` `0,2` `2/15` `(mol)`
`n_[Fe_2 O_3]=32/160=0,2(mol)`
Ta có:`[0,25]/1 > [0,2]/3`
`=>H_2` dư
`=>m_[Fe_3 O_4]=2/15 . 232~~30,93(g)`
a) $Fe + 2HCl \to FeCl_2 + H_2$
Theo PTHH : n H2 = n Fe = 8,4/56 = 0,15(mol)
V H2 = 0,15.22,4 = 3,36(lít)
b) n HCl = 2n Fe = 0,3(mol)
=> CM HCl = 0,3/0,2 = 1,5M
c) $CuO + H_2 \xrightarrow{t^o} Cu + H_2O$
Ta thấy :
n CuO = 32/80 = 0,4 > n H2 = 0,15 mol nên CuO dư
Theo PTHH : n Cu = n H2 = 0,15 mol
=> m Cu = 0,15.64 = 9,6 gam
nZn = 13/65 = 0.2 (mol)
Zn + H2SO4 => ZnSO4 + H2
0.2......0.2..........................0.2
VH2 = 0.2*22.4 = 4.48 (l)
C%H2SO4 = 0.2*98/200 * 100% = 9.8 %
nCuO = 8/80 = 0.1 (mol)
CuO + H2 -to-> Cu + H2O
0.1......0.1...........0.1
=> H2 dư
mCu = 0.1*64 = 6.4 (g)
â) nZn=0,2(mol)
PTHH: Zn + H2SO4 -> ZnSO4 + H2
0,2_____0,2______0,2_____0,2(mol)
=> V(H2,đktc)=0,2.22,4=4,48(l)
b) C%ddH2SO4= [(98.0,2)/200)].100=9,8%
c) nCuO=0,1(mol)
PTHH: CuO + H2 -to-> Cu + H2O
Ta có: 0,1/1 < 0,2/1
=> H2 dư, CuO hết, tính theo nCuO
=> nCu=nCuO=0,1(mol)
=>mCu=6,4(g)
\(n_{Zn}=\dfrac{19,5}{65}=0,3\left(mol\right)\)
PTHH :
\(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
0,3 0,6 0,3 0,3
\(a,V_{H_2}=n.22,4=0,3.22,4=6,72\left(l\right)\)
\(m_{ZnCl_2}=0,3.136=40,8\left(g\right)\)
\(b,V_{ddHCl}=\dfrac{n}{C_M}=\dfrac{0,6}{2}=0,3\left(l\right)\)
\(c,Fe_2O_3+3H_2\rightarrow2Fe+3H_2O\)
0,1 0,3
\(n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\)
Ta có :
\(\dfrac{0,1}{1}=\dfrac{0,3}{3}\)
nên không chất nào dư
a, \(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)
PTHH: Zn + 2HCl ---> ZnCl2 + H2
0,1--->0,2------->0,1----->0,1
VH2 = 0,1.22,4 = 2,24 (l)
b, \(C_{M\left(HCl\right)}=\dfrac{0,2}{0,2}=1M\)
c, \(C_{M\left(ZnCl_2\right)}=\dfrac{0,1}{0,2}=0,5M\)
\(n_{Zn}=\dfrac{26}{65}=0,4\left(mol\right)\\ pthh:Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
0,4 0,8 0,4 0,4
\(a,V_{H_2}=0,4.22,4=8,96\left(l\right)\\ b,C\%_{HCl}=\dfrac{0,8.36,5}{150}.100\%=19,5\%\\ c,m_{\text{dd}}=26+150-\left(0,4.2\right)=175,2\left(g\right)\\ C\%_{ZnCl_2}=\dfrac{0,4.136}{175,2}.100\%=31\%\)
\(a) Zn + H_2SO_4 \to ZnSO_4 + H_2\\ b) n_{H_2} = n_{Zn} = \dfrac{13}{65}=0,2(mol)\\ V_{H_2} = 0,2.22,4 = 4,48(lít)\\ c) CuO + H_2 \xrightarrow{t^o} Cu + H_2O\\ n_{CuO} = n_{H_2} = 0,2(mol)\\ m_{CuO} = 0,2.80 = 16(gam)\)
\(n_{H_2}=\dfrac{6.72}{22.4}=0.3\left(mol\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(.........0.6............0.3\)
\(C_{M_{HCl}}=\dfrac{0.6}{0.3}=2\left(M\right)\)
\(n_{Fe_2O_3}=\dfrac{48}{160}=0.3\left(mol\right)\)
\(Fe_2O_3+3H_2\underrightarrow{^{t^0}}2Fe+3H_2O\)
\(1..............3\)
\(0.3..........0.3\)
\(LTL:\dfrac{0.3}{1}>\dfrac{0.3}{3}\Rightarrow Fe_2O_3dư\)
\(n_{Fe}=\dfrac{2}{3}n_{H_2}=\dfrac{2}{3}\cdot0.3=0.2\left(mol\right)\)
\(m_{Fe}=0.2\cdot56=11.2\left(g\right)\)
a)
\(n_{Zn}=\dfrac{16,25}{65}=0,25\left(mol\right)\)
PTHH: Zn + H2SO4 --> ZnSO4 + H2
0,25-->0,25------------->0,25
=> VH2 = 0,25.22,4 = 5,6 (l)
b) \(C_{M\left(dd.H_2SO_4\right)}=\dfrac{0,25}{0,3}=\dfrac{5}{6}M\)
c) \(n_{Fe_2O_3}=\dfrac{32}{160}=0,2\left(mol\right)\)
PTHH: Fe2O3 + 3H2 --to--> 2Fe + 3H2O
Xét tỉ lệ: \(\dfrac{0,2}{1}>\dfrac{0,25}{3}\) => Fe2O3 dư, H2 hết
PTHH: Fe2O3 + 3H2 --to--> 2Fe + 3H2O
\(\dfrac{0,25}{3}\) <--0,25----->\(\dfrac{0,5}{3}\)
=> \(m=32-\dfrac{0,25}{3}.160+\dfrac{0,5}{3}.56=28\left(g\right)\)
PTHH: \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
đb: 0,25
a) số mol của Zn là: \(n_{Zn}=\dfrac{m_{Zn}}{M_{Zn}}=\dfrac{16,25}{65}=0,25\left(mol\right)\)
Theo PTHH, ta có: \(n_{H_2}=\dfrac{0,25\cdot1}{1}=0,25\left(mol\right)\)
Thể tích của H2 ở đktc là: \(V_{H_2\left(đktc\right)}=n_{H_2}\cdot22,4=0,25\cdot22,4=5,6\left(l\right)\)
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