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a, \(n_{CH_4}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
PTHH:
CH4 + 2O2 --to--> CO2 + 2H2O
0,5--->1------------->0,5
Ca(OH)2 + CO2 ---> CaCO3 + H2O
0,5----->0,5
b, \(V_{O_2}=1.22,4=22,4\left(l\right)\)
c, \(m_{CaCO_3}=0,5.100=50\left(g\right)\)
nKMnO4=94,8:158=0,6(mol)
PTHH: 2KMnO4-t--> K2MnO4+MnO2+O2
0,6----------------------------------->0,3(mol)
=>V= VO2=0,3. 22,4= 6,72(l)
b ) 40%nO2 =40%.0,3=0,12(mol)
2R + O2 -t--->2RO
0,24(mol)<- 0,12
=> M(Khối lượng Mol ) R= m:n=5,76:0,24=24(G/MOL)
=> R là Mg
a)-\(n_{KMnO_4}=\dfrac{m}{M}=\dfrac{94,8}{158}=0,6\left(mol\right)\)
-PTHH: \(2KMnO_4\rightarrow^{t^0}K_2MnO_4+MnO_2+O_2\uparrow\)
2 1
0,6 0,3
\(\Rightarrow V_{O_2\left(đktc\right)}=n.22,4=0,3.22,4=6,72\left(l\right)\)
b)-\(V_{O_2\left(cd\right)}=6,72.\dfrac{40}{100}=2,688\left(l\right)\)
\(\Rightarrow n_{O_2}=\dfrac{V}{22,4}=\dfrac{2,688}{22,4}=0,12\left(mol\right)\)
-PTHH: \(2R+O_2\rightarrow^{t^0}2RO\)
2 1
0,24 0,12
\(m_R=n.M=5,76\left(g\right)\)
\(\Rightarrow0,24.M_R=5,76\)
\(\Rightarrow M_R=24\) (g/mol)
-Vậy R là Crom
\(n_{Ba}=\dfrac{24,66}{137}=0,18\left(mol\right)\\
pthh:Ba+2H_2O\rightarrow Ba\left(OH\right)_2+H_2\)
0,18 0,18
\(\Rightarrow V_{H_2}=0,18.22,4=4,032\left(L\right)\\
n_{CuO}=\dfrac{15,2}{80}=0,19\left(mol\right)\\
pthh:H_2+CuO\underrightarrow{t^o}Cu+H_2O\)
\(LTL:0,18< 0,19\)
=> CuO dư
theo pthh : \(n_{CuO\left(p\text{ư}\right)}=n_{Cu}=n_{H_2}=0,18\left(mol\right)\)
=> \(m_{Kl}=\left(64.0,18\right)+\left(80.0,1\right)=19,52\left(g\right)\)
a, Theo giả thiết ta có: \(n_P=\dfrac{3,1}{31}=0,1\left(mol\right)\)
\(4P+5O_2--t^o->2P_2O_5\)
Ta có: \(n_{O_2}=\dfrac{5}{4}.n_P=0,125\left(mol\right)\Rightarrow V_{O_2\left(đktc\right)}=0,125.22,4=2,8\left(l\right)\)
b, Theo giả thiết ta có: \(n_{CH_4}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)
\(CH_4+2O_2--t^o->CO_2+2H_2O\)
Ta có: \(n_{O_2}=2.n_{CH_4}=0,1\left(mol\right)\Rightarrow V_{O_2\left(đktc\right)}=2,24\left(l\right)\)
a.\(n_{KMnO_4}=\dfrac{m}{M}=\dfrac{31,6}{158}=0,2mol\)
\(2KMnO_4\rightarrow\left(t^o\right)K_2MnO_4+MnO_2+O_2\)
0,2 0,1 ( mol )
\(V_{O_2}=n.22,4=0,1.22,4=2,24l\)
b.\(n_{O_2}=0,1.60\%=0,06mol\)
\(2R+\dfrac{1}{2}nO_2\rightarrow\left(t^o\right)R_2O_n\)
\(\dfrac{2,16}{M_R}\) \(\dfrac{2,16n}{M_R}\) ( mol )
\(\Rightarrow\dfrac{2,16n}{M_R}=0,06\)
\(\Rightarrow0,06M_R=2,16n\)
\(\Rightarrow M_R=36n\)
Biện luận:
-n=1 => Loại
-n=2 => Loại
-n=3 => \(M_R=108\) ( g/mol ) R là Bạc ( Ag )
Vậy R là Bạc (Ag)
nKMnO4 = 94,8: 158=0,6(mol)
pthh : 2KMnO4 -t--> K2MnO4 + MnO2 + O2
0,6-------------------------------------->0,3(mol)
V= VO2 = 0,3.22,4 = 6,72 (l)
40%nO2 = 40%.0,3=0,12 (mol )
pthh : 2R+ O2 -t-> 2RO
0,24<-0,12(MOL)
=>MR =5,76: 0,24= 24(g/mol)
=> R là Mg
\(n_{CaCO_3}=\dfrac{7,5}{100}=0,075\left(mol\right)\)
=> nC = 0,075 (mol)
Có \(n_{CO_2}=n_C=0,075\left(mol\right)\)
=> \(n_{H_2O}=\dfrac{4,2-0,075.44}{18}=0,05\left(mol\right)\)
=> nH = 0,1 (mol)
\(n_{O_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
Bảo toàn O: \(n_{O\left(A\right)}=0,075.2+0,05-0,1.2=0\left(mol\right)\)
=> A chứa C, H
mA = mC + mH = 0,075.12 + 0,1.1 = 1 (g)
\(m_{tăng}=m_{H_2O}+m_{CO_2}=4,2\left(g\right)\\ n_{CaCO_3}=\dfrac{7,5}{100}=0,075\left(mol\right)\)
PTHH: Ca(OH)2 + CO2 ---> CaCO3 + H2O
0,075 0,075
\(\rightarrow m_{CO_2}=0,075.44=3,3\left(g\right)\\ \rightarrow m_{H_2O}=4,2-3,3=0,9\left(g\right)\\ \rightarrow n_{H_2O}=\dfrac{0,9}{18}=0,05\left(mol\right)\\ \rightarrow n_{O\left(sau.pư\right)}=0,05+0,075.2=0,1\left(mol\right)\\ n_{O\left(trong.O_2\right)}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\\ \rightarrow\left\{{}\begin{matrix}n_C=0,075\left(mol\right)\\n_H=0,05.2=0,1\left(mol\right)\\n_O=0,1-0,1=0\left(mol\right)\end{matrix}\right.\)
=> mA = 0,075.12 + 0,1.1 + 0 = 1 (g)
Ta có: \(n_{CH_4}=\dfrac{4,958}{24,79}=0,2\left(mol\right)\)
\(n_{C_2H_4}=\dfrac{2,479}{24,79}=0,1\left(mol\right)\)
PT: \(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)
\(C_2H_4+3O_2\underrightarrow{t^o}2CO_2+2H_2O\)
\(CO_2+Ba\left(OH\right)_2\rightarrow BaCO_3+H_2O\)
Theo PT: \(n_{O_2}=2n_{CH_4}+3n_{C_2H_4}=0,7\left(mol\right)\)
\(\Rightarrow V_{O_2}=0,7.24,79=17,353\left(l\right)\)
\(n_{BaCO_3}=n_{CO_2}=n_{CH_4}+2n_{C_2H_4}=0,4\left(mol\right)\)
\(\Rightarrow m_{BaCO_3}=0,4.197=78,8\left(g\right)\)