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nH2SO4 = 14,7: 27=0,54(mol)
PTHH : 2Al + 3H2SO4 --> Al2(SO4)3 + 3H2
theo pt , nH2 = nH2SO4=0,54(mol)
=> VH2(đktc) = 0,54. 22,4=12,096 (l)
b theo pt nAl = 3/2. nH2=0,36 (mol)
=> mAl = 0,36.27 =9,72(g)
c)theo pt n Al2(SO4)3 = 1/2nAl = 0,18(mol)
=>mAl2(SO4)3= 0,18.342=61,56(g)
a, \(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)
PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
Theo PT: \(n_{H_2}=n_{Zn}=0,1\left(mol\right)\Rightarrow V_{H_2}=0,1.22,4=2,24\left(l\right)\)
b, \(n_{ZnCl_2}=n_{Zn}=0,1\left(mol\right)\Rightarrow m_{ZnCl_2}=0,1.136=13,6\left(g\right)\)
c, m dd muối = 13,6 + 172,8 = 186,4 (g)
\(\Rightarrow C\%_{ZnCl_2}=\dfrac{13,6}{186,4}.100\%\approx7,3\%\)
\(pthh:Zn+2HCl--->ZnCl_2+H_2\uparrow\)
a. Ta có: \(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)
Theo pt: \(n_{H_2}=n_{Zn}=0,1\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,1.22,4=2,24\left(lít\right)\)
b. Theo pt: \(n_{ZnCl_2}=n_{Zn}=0,1\left(mol\right)\)
\(\Rightarrow m_{ZnCl_2}=0,1.136=13,6\left(g\right)\)
c. \(C_{\%_{ZnCl_2}}=\dfrac{m_{ZnCl_2}}{m_{dd_{ZnCl_2}}}.100\%=\dfrac{13,6}{13,6+172,8}.100\%=7,3\%\)
\(n_{HCl}=0.5\cdot2=1\left(mol\right)\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(..........1.........\dfrac{1}{3}.......0.5\)
\(V_{H_2}=0.5\cdot22.4=11.2\left(l\right)\)
\(m_{AlCl_3}=\dfrac{1}{3}\cdot133.5=44.5\left(g\right)\)
\(CuO+H_2\underrightarrow{^{t^0}}Cu+H_2O\)
\(0.5.....0.5\)
\(m_{CuO}=0.5\cdot80=40\left(g\right)\)
Ta có: \(n_{Mg}=\dfrac{2,4}{24}=0,1\left(mol\right)\)
PT: \(Mg+2HCl\rightarrow MgCl_2+H_2\)
Theo PT: \(n_{MgCl_2}=n_{H_2}=n_{Mg}=0,1\left(mol\right)\)
a, \(m_{MgCl_2}=0,1.95=9,5\left(g\right)\)
b, \(V_{H_2}=0,1.24,79=2,479\left(l\right)\)
c, \(n_{HCl}=2n_{Mg}=0,2\left(mol\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{0,2.36,5}{3,65\%}=200\left(g\right)\)
\(n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\\ pthh:2Al+6HCl\rightarrow2AlCl_3+3H_2\)
Mol : 0,4 0,4 0,6
\(m_{AlCl_3}=133,5.0,4=53,4\left(g\right)\\ V_{H_2}=0,6.22,4=13,44\left(l\right)\)
\(n_{CuO}=\dfrac{8}{80}=0,8\left(mol\right)\\
pthh:CuO+H_2\underrightarrow{t^o}Cu+H_2O\\
LTL:\dfrac{0,8}{1}>\dfrac{0,6}{1}\)
=> CuO dư
\(n_{CuO\left(p\text{ư}\right)}=n_{Cu}=n_{H_2}=0,6\left(mol\right)\\
m_{CuO\left(d\right)}=\left(0,8-0,6\right).80=16\left(g\right)\\
m_{Cu}=0,6.64=38,4\left(g\right)\\
m_{cr}=16+38,4=54,4\left(g\right)\)
a, PT: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
b, Ta có: \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
Theo PT: \(\left\{{}\begin{matrix}n_{HCl}=3n_{Al}=0,6\left(mol\right)\\n_{H_2}=\dfrac{3}{2}n_{Al}=0,3\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow m_{HCl}=0,6.36,5=21,9\left(g\right)\)
\(V_{H_2}=0,3.22,4=6,72\left(l\right)\)
c, Cách 1:
Theo PT: \(n_{AlCl_3}=n_{Al}=0,2\left(mol\right)\)
\(\Rightarrow m_{AlCl_3}=0,2.133,5=26,7\left(g\right)\)
Cách 2:
Ta có: \(m_{H_2}=0,3.2=0,6\left(g\right)\)
Theo ĐLBT KL, có: mAl + mHCl = mAlCl3 + mH2
⇒ mAlCl3 = mAl + mHCl - mH2 = 5,4 + 21,9 - 0,6 = 26,7 (g)
Bạn tham khảo nhé!
\(n_{HCl}=\dfrac{150.7,3\%}{36,5}=0,3\left(mol\right)\\ 2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\\ a,n_{Al}=n_{AlCl_3}=\dfrac{2}{6}.0,3=0,1\left(mol\right)\\ \Rightarrow m_{Al}=0,1.27=2,7\left(g\right)\\ b,m_{AlCl_3}=0,1.133,5=13,35\left(g\right)\\ c,n_{H_2}=\dfrac{3}{6}.0,3=0,15\left(mol\right)\\ \Rightarrow V_{H_2\left(đktc\right)}=0,15.22,4=3,36\left(l\right)\)
2Al+6HCl->2AlCl3+3H2
0,2----0,6-----0,2--------0,3
nHCl=0,6 mol
=>mAlCl3=0,2.133,5=26,7g
=>mH2=0,3.22,4=6,72l
=>mAl=0,2.27=5,4g