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Bài 1:
a) PTHH: \(Fe_2O_3+3H_2\xrightarrow[]{t^o}2Fe+2H_2O\)
\(CuO+H_2\xrightarrow[]{t^o}Cu+H_2O\)
b) Ta có: \(\left\{{}\begin{matrix}m_{Fe_2O_3}=20\cdot80\%=16\left(g\right)\\m_{CuO}=20-16=4\left(g\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\\n_{CuO}=\dfrac{4}{80}=0,05\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{H_2}=3n_{Fe_2O_3}+n_{CuO}=0,35\left(mol\right)\) \(\Rightarrow V_{H_2}=0,35\cdot22,4=7,84\left(l\right)\)
c) Theo các PTHH: \(\left\{{}\begin{matrix}n_{Fe}=2n_{Fe_2O_3}=0,2\left(mol\right)\\n_{Cu}=n_{CuO}=0,05\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow m_{hhB}=m_{Fe}+m_{Cu}=0,2\cdot56+0,05\cdot64=14,4\left(g\right)\)
Bài 2:
PTHH: \(Fe_2O_3+3H_2\xrightarrow[]{t^o}2Fe+3H_2O\)
\(CuO+H_2\xrightarrow[]{t^o}Cu+H_2O\)
a) Vì khối lượng Cu bằng \(\dfrac{6}{5}\) khối lượng Fe
\(\Rightarrow\left\{{}\begin{matrix}m_{Cu}=\dfrac{26,4}{6+5}\cdot6=14,4\left(g\right)\\m_{Fe}=26,4-14,4=12\left(g\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}n_{Cu}=\dfrac{14,4}{64}=0,225\left(mol\right)\\n_{Fe}=\dfrac{12}{56}=\dfrac{3}{14}\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{H_2}=\dfrac{3}{2}n_{Fe}+n_{Cu}=\dfrac{9}{28}+0,225=\dfrac{153}{280}\left(mol\right)\) \(\Rightarrow V_{H_2}=\dfrac{153}{280}\cdot22,4=12,24\left(l\right)\)
b) Theo các PTHH: \(\left\{{}\begin{matrix}n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe}=\dfrac{3}{28}\left(mol\right)\\n_{CuO}=n_{Cu}=0,225\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Fe_2O_3}=\dfrac{3}{28}\cdot160\approx17,14\left(g\right)\\m_{CuO}=0,225\cdot80=18\left(g\right)\end{matrix}\right.\) \(\Rightarrow m_{hh}=35,14\left(g\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Fe_2O_3}=\dfrac{17,14}{35,14}\cdot100\%\approx48,78\%\\\%m_{CuO}=51,22\%\end{matrix}\right.\)
a.b.
\(\left\{{}\begin{matrix}n_{Fe_2O_3}=40.80\%=32g\\m_{CuO}=40-32=8g\end{matrix}\right.\)
\(\left\{{}\begin{matrix}n_{Fe_2O_3}=\dfrac{32}{160}=0,2mol\\n_{CuO}=\dfrac{8}{80}=0,1mol\end{matrix}\right.\)
\(CuO+H_2\rightarrow\left(t^o\right)Cu+H_2O\)
0,1 0,1 0,1 ( mol )
\(Fe_2O_3+3H_2\rightarrow\left(t^o\right)2Fe+3H_2O\)
0,2 0,6 0,4 ( mol )
\(V_{H_2}=\left(0,1+0,6\right).22,4=15,68l\)
\(\left\{{}\begin{matrix}m_{Cu}=0,1.64=6,4g\\m_{Fe}=0,4.56=22,4g\end{matrix}\right.\)
\(\rightarrow\left\{{}\begin{matrix}\%m_{Cu}=\dfrac{6,4}{6,4+22,4}.100=22,22\%\\\%m_{Fe}=100\%-22,22\%=77,78\%\end{matrix}\right.\)
c.
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\) ( Cu không phản ứng với H2SO4 loãng )
0,4 0,4 ( mol )
\(V_{H_2}=0,4.22,4=8,96l\)
\(n_{CuO}=2a\left(mol\right)\Rightarrow n_{Fe_2O_3}=a\left(mol\right)\)
\(m_X=80\cdot2a+160a=80\left(g\right)\)
\(\Rightarrow a=0.25\left(mol\right)\)
\(CuO+H_2\underrightarrow{^{^{t^0}}}Cu+H_2O\)
\(Fe_2O_3+3H_2\underrightarrow{^{^{t^0}}}2Fe+3H_2O\)
\(n_{H_2}=0.5+0.25\cdot3=1.25\left(mol\right)\)
\(V_{H_2}=1.25\cdot22.4=28\left(l\right)\)
\(m_{cr}=0.5\cdot64+0.5\cdot56=60\left(g\right)\)
a) Gọi số mol H2 là x
=> \(n_{H_2O}=x\left(mol\right)\)
Theo ĐLBTKL: \(m_A+m_{H_2}=m_B+m_{H_2O}\)
=> 200 + 2x = 156 + 18x
=> x = 2,75 (mol)
=> \(V_{H_2}=2,75.22,4=61,6\left(l\right)\)
b) Gọi \(\left\{{}\begin{matrix}n_{CuO}=a\left(mol\right)\\n_{Fe_2O_3}=1,5a\left(mol\right)\\n_{Al_2O_3}=b\left(mol\right)\end{matrix}\right.\)
=> 80a + 240a + 102b = 200
=> 320a + 102b = 200
PTHH: CuO + H2 --to--> Cu + H2O
a---------------->a
Fe2O3 + 3H2 --to--> 2Fe + 3H2O
1,5a------------------>3a
=> 64a + 168a + 102b = 156
=> 232a + 102b = 156
=> a = 0,5; b = \(\dfrac{20}{51}\)
=> \(\left\{{}\begin{matrix}\%m_{CuO}=\dfrac{0,5.80}{200}.100\%=20\%\\\%m_{Fe_2O_3}=\dfrac{0,75.160}{200}.100\%=60\%\\\%m_{Al_2O_3}=\dfrac{\dfrac{20}{51}.102}{200}.100\%=20\%\end{matrix}\right.\)
c) \(n_{H_2}=\dfrac{2,75}{5}=0,55\left(mol\right)\)
\(n_{FeO\left(tt\right)}=\dfrac{36}{72}=0,5\left(mol\right)\)
Gọi số mol FeO phản ứng là t (mol)
PTHH: FeO + H2 --to--> Fe + H2O
t--------------->t
=> 56t + (0,5-t).72 = 29,6
=> t = 0,4 (mol)
=> \(H\%=\dfrac{0,4}{0,5}.100\%=80\%\)
PT: \(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
\(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
Giả sử: \(\left\{{}\begin{matrix}n_{Fe_2O_3}=x\left(mol\right)\\n_{CuO}=y\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow160x+80y=40\left(1\right)\)
Ta có: \(n_{H_2}=\dfrac{14,56}{22,4}=0,65\left(mol\right)\)
Theo PT: \(n_{H_2}=3n_{Fe_2O_3}+n_{CuO}=3x+y\left(mol\right)\)
⇒ 3x + y = 0,65 (2)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,15\left(mol\right)\\y=0,2\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Fe_2O_3}=\dfrac{0,15.160}{40}.100\%=60\%\\\%m_{CuO}=40\%\end{matrix}\right.\)
Bạn tham khảo nhé!
\(m_{Fe_2O_3}=\dfrac{80\cdot50}{100}=40\left(g\right)\)
\(m_{CuO}=50-40=10\left(g\right)\)
\(n_{Fe_2O_3}=\dfrac{40}{160}=0.25\left(mol\right)\)
\(n_{CuO}=\dfrac{10}{80}=0.125\left(mol\right)\)
\(Fe_2O_3+3H_2\underrightarrow{t^0}2Fe+3H_2O\)
\(CuO+H_2\underrightarrow{t^0}Cu+H_2O\)
\(n_{H_2}=3\cdot0.25+0.125=0.875\left(mol\right)\)
\(V_{H_2}=0.875\cdot22.4=19.6\left(l\right)\)
Chúc bạn học tốt <3
Vì: %mCH4 = 80%
\(\Rightarrow m_{CH_4}=25.80\%=20\left(g\right)\Rightarrow n_{CH_4}=\dfrac{20}{16}=1,25\left(mol\right)\)
\(\Rightarrow m_{H_2}=5\left(g\right)\Rightarrow n_{H_2}=\dfrac{5}{2}=2,5\left(mol\right)\)
PT: \(2H_2+O_2\underrightarrow{t^o}2H_2O\)
\(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)
Theo PT: \(\Sigma n_{O_2}=\dfrac{1}{2}n_{H_2}+2n_{CH_4}=3,75\left(mol\right)\)
\(\Rightarrow V_{O_2}=3,75.22,4=84\left(l\right)\)
Mà: %VO2 = 20%
\(\Rightarrow V_{kk}=\dfrac{84}{20\%}=420\left(l\right)\)
Bạn tham khảo nhé!
a) \(m_{CuO}=\dfrac{20.40}{100}=8\left(g\right)\) => \(n_{CuO}=\dfrac{8}{80}=0,1\left(mol\right)\)
\(m_{Fe_2O_3}=20-8=12\left(g\right)\) => \(n_{Fe_2O_3}=\dfrac{12}{160}=0,075\left(mol\right)\)
PTHH: CuO + H2 --to--> Cu + H2O
0,1--->0,1------>0,1
Fe2O3 + 3H2 --to--> 2Fe + 3H2O
0,075--->0,225----->0,15
=> mCu = 0,1.64 = 6,4 (g)
=> mFe = 0,15.56 = 8,4 (g)
b) \(V_{H_2}=\left(0,1+0,225\right).22,4=7,28\left(l\right)\)
\(m_{Fe_2O_3}=80\%.50=40\left(g\right)\Rightarrow n_{Fe_2O_3}=0,25\left(mol\right)\\ m_{CuO}=50-40=10\left(g\right)\Rightarrow n_{CuO}=0,125\left(mol\right)\\Fe_2O_3+3H_2-^{t^o}\rightarrow 2Fe+3H_2O\\ CuO+H_2-^{t^o}\rightarrow Cu+H_2O\\ \Sigma n_{H_2}=0,25.3+0,125=0,875\left(mol\right)\\ \Rightarrow V_{H_2}=0,875.22,4=19,6\left(l\right)\)