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![](https://rs.olm.vn/images/avt/0.png?1311)
a) \(n_{CuO}=\dfrac{16}{80}=0,2\left(mol\right)\)
PTHHL 2Cu + O2 --to--> 2CuO
0,2<--0,1<-------0,2
=> mCu = 0,2.64 = 12,8 (g)
b) \(V_{O_2}=0,1.22,4=2,24\left(l\right)\)
=> Vkk = 2,24 : 20% = 11,2 (l)
c) \(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
PTHH: CuO + H2 --to--> Cu + H2O
Xét tỉ lệ: \(\dfrac{0,2}{1}>\dfrac{0,15}{1}\) => CuO dư, H2 hết
PTHH: CuO + H2 --to--> Cu + H2O
0,15<-0,15----->0,15
=> \(\left\{{}\begin{matrix}n_{Cu}=0,15\left(mol\right)\\n_{CuO\left(dư\right)}=0,05\left(mol\right)\end{matrix}\right.\)
=> mA = 0,15.64 + 0,05.80 = 13,6 (g)
Bài làm:
Số mol đồng oxit (CuO) là:
$n_{CuO}$ = $\frac{m_{CuO}}{M_{CuO}}$ = $\frac{16}{80}$ = 0,2 (mol)
PTHH: 2Cu + $O_{2}$ --$t^{o}$--> 2CuO
Theo PT: 2 mol 1 mol <-- 2 mol
Theo bài: 0,2 mol 0,1 mol <-- 0,2 mol
a)Khối lượng đồng (Cu) là:
$m_{Cu}$ = $M_{Cu}$ . $n_{Cu}$ = 64. 0,2 = 12,8 (g)
b)Thế tích khí oxi ($O_{2}$) là:
$V_{O_{2}}$ = $n_{O_{2}}$ . 22,4 = 0,1 . 22,4 = 2,24 (lít)
Thể tích chiếm 20% thể tích không khí
=>$V_{kk}$ = 22,4 : 20% = 11,2 (lít)
c)Số mol khí hiđro ($H_{2}$) là:
$n_{H_{2}}$ = $\frac{m_{H_{2}}}{M_{H_{2}}}$ = $\frac{3,36}{22,4}$ = 0,15 (mol)
PTHH: CuO + H2 --to--> Cu + H2O
Theo PT: 1 mol 1 mol 1 mol 1 mol
Theo bài: 0,15 mol 0,15 mol 0,15 mol 0,15 mol
Xét tỉ lệ: $\frac{0,2}{1}$ > $\frac{0,15}{1}$
=> CuO dư, H2 hết
PTHH: CuO + H2 --to--> Cu + H2O
Theo PT: 1 mol 1 mol 1 mol 1 mol
Theo bài: 0,15 mol 0,15 mol 0,15 mol 0,15 mol
Số mol đồng (Cu) là: 0,15 mol như PTHH
Số mol đồng (II) oxit (CuO) dư là: 0,05 mol tự tính
=> mA = 0,15.64 + 0,05.80 = 13,6 (g)
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![](https://rs.olm.vn/images/avt/0.png?1311)
nCu = 8: 80=0,1(mol)
a) PTHH : CuO + H2 -t--> Cu +H2O
0,1-> 0,1------>0,1(mol)
mCu = 0,1.64=6,4(g)
VH2 = 0,1.22,4=2,24(l)
![](https://rs.olm.vn/images/avt/0.png?1311)
Bài 1:
a) PTHH: \(Fe_2O_3+3H_2\xrightarrow[]{t^o}2Fe+2H_2O\)
\(CuO+H_2\xrightarrow[]{t^o}Cu+H_2O\)
b) Ta có: \(\left\{{}\begin{matrix}m_{Fe_2O_3}=20\cdot80\%=16\left(g\right)\\m_{CuO}=20-16=4\left(g\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\\n_{CuO}=\dfrac{4}{80}=0,05\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{H_2}=3n_{Fe_2O_3}+n_{CuO}=0,35\left(mol\right)\) \(\Rightarrow V_{H_2}=0,35\cdot22,4=7,84\left(l\right)\)
c) Theo các PTHH: \(\left\{{}\begin{matrix}n_{Fe}=2n_{Fe_2O_3}=0,2\left(mol\right)\\n_{Cu}=n_{CuO}=0,05\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow m_{hhB}=m_{Fe}+m_{Cu}=0,2\cdot56+0,05\cdot64=14,4\left(g\right)\)
Bài 2:
PTHH: \(Fe_2O_3+3H_2\xrightarrow[]{t^o}2Fe+3H_2O\)
\(CuO+H_2\xrightarrow[]{t^o}Cu+H_2O\)
a) Vì khối lượng Cu bằng \(\dfrac{6}{5}\) khối lượng Fe
\(\Rightarrow\left\{{}\begin{matrix}m_{Cu}=\dfrac{26,4}{6+5}\cdot6=14,4\left(g\right)\\m_{Fe}=26,4-14,4=12\left(g\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}n_{Cu}=\dfrac{14,4}{64}=0,225\left(mol\right)\\n_{Fe}=\dfrac{12}{56}=\dfrac{3}{14}\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{H_2}=\dfrac{3}{2}n_{Fe}+n_{Cu}=\dfrac{9}{28}+0,225=\dfrac{153}{280}\left(mol\right)\) \(\Rightarrow V_{H_2}=\dfrac{153}{280}\cdot22,4=12,24\left(l\right)\)
b) Theo các PTHH: \(\left\{{}\begin{matrix}n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe}=\dfrac{3}{28}\left(mol\right)\\n_{CuO}=n_{Cu}=0,225\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Fe_2O_3}=\dfrac{3}{28}\cdot160\approx17,14\left(g\right)\\m_{CuO}=0,225\cdot80=18\left(g\right)\end{matrix}\right.\) \(\Rightarrow m_{hh}=35,14\left(g\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Fe_2O_3}=\dfrac{17,14}{35,14}\cdot100\%\approx48,78\%\\\%m_{CuO}=51,22\%\end{matrix}\right.\)
![](https://rs.olm.vn/images/avt/0.png?1311)
Zn + 2 HCl -> ZnCl2 + H2
nZn=0,2(mol) -> nH2=0,2(mol)
PTHH: Fe3O4 + 4 H2 -to-> 3 Fe + 4 H2O
nFe3O4=23,2/232=0,1(mol)
Ta có: 0,1/1 > 0,2/4
=> H2 hết, Fe3O4 dư, tính theo nH2
=> nFe=3/4. 0,2=0,15(mol)
=> mFe=0,15. 56=8,4(g)
![](https://rs.olm.vn/images/avt/0.png?1311)
a, \(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
b, \(n_{Fe_2O_3}=\dfrac{24}{160}=0,15\left(mol\right)\)
Theo PT: \(n_{H_2}=3n_{Fe_2O_3}=0,45\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,45.22,4=10,08\left(l\right)\)
c, n\(n_{Fe}=2n_{Fe_2O_3}=0,3\left(mol\right)\)
PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
Theo PT: \(n_{HCl}=2n_{Fe}=0,6\left(mol\right)\Rightarrow V_{HCl}=\dfrac{0,6}{1,5}=0,4\left(M\right)\)
![](https://rs.olm.vn/images/avt/0.png?1311)
\(n_{Fe_3O_4}=\dfrac{24}{232}=\dfrac{3}{29}\left(mol\right)\)
PTHH :
\(Fe_3O_4+4H_2\underrightarrow{t^o}3Fe+4H_2O\)
3/29 9/29
\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
9/29 18/29
\(c,V_{HCl}=\dfrac{\dfrac{18}{29}}{1,5}=\dfrac{12}{29}\left(l\right)\)
![](https://rs.olm.vn/images/avt/0.png?1311)
Theo đề gọi \(\left\{{}\begin{matrix}n_{Fe_2O_3}=3x\left(mol\right)\\n_{CuO}=2x\left(mol\right)\end{matrix}\right.\)
Có: \(m_{hh}=m_{Fe_2O_3}+m_{CuO}=160.3x+80.2x=32\)
\(\Rightarrow x=0,05\\ \Rightarrow\left\{{}\begin{matrix}n_{Fe_2O_3}=0,05.3=0,15\left(mol\right)\\n_{CuO}=0,05.2=0,1\left(mol\right)\end{matrix}\right.\)
\(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
0,15 ---->0,45-->0,3
\(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
0,1 --->0,1-->0,1
a. \(m_{kim.loại}=m_{Fe}+m_{Cu}=0,3.56+0,1.64=23,2\left(g\right)\)
b. \(V_{H_2}=\left(0,45+0,1\right).22,4=12,32\left(l\right)\)
\(a) CuO + H_2 \xrightarrow{t^o} Cu + H_2O\\ n_{Cu} = n_{H_2} = n_{CuO} = \dfrac{8}{80} = 0,1(mol)\\ m_{Cu} = 0,1.64 = 6,4(gam)\\ b) V_{H_2} = 0,1.22,4 = 2,24(lít)\)