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Ta có: \(n_S=\dfrac{6,4}{32}=0,2\left(mol\right)\)
a. PTHH: S + O2 ---to---> SO2
Theo PT: \(n_{SO_2}=n_S=0,2\left(mol\right)\)
=> \(m_{SO_2}=0,2.64=12,8\left(g\right)\)
b. Theo PT: \(n_{O_2}=n_S=0,2\left(mol\right)\)
=> \(m_{O_2}=0,2.32=6,4\left(g\right)\)
a)S+O2-------->SO2
b)n S=6,4/32=0,2(mol)
Theo pthh
n SO2 =n S=0,2(mol)
V SO2=0,2.22,4=4,48(mol)
a)
n CuO = a(mol) ; n MgO = b(mol) ; n Fe2O3 = c(mol)
=> 80a + 40b + 160c = 12(1)
CuO + 2HCl $\to$ CuCl2 + H2O
MgO + 2HCl $\to$ MgCl2 + H2O
Fe2O3 + 6HCl $\to$ 2FeCl3 + 3H2O
n HCl = 2a + 2b + 6c = 0,225.2 = 0,45(2)
Thí nghiệm 2 :
$CuO + CO \xrightarrow{t^o} Cu + H_2O$
$Fe_2O_3 + 3CO \xrightarrow{t^o} 2Fe + 3CO_2$
m chất rắn = 64a + 40b + 56.2c = 10(2)
Từ (1)(2)(3) suy ra a = 0,05 ; b = 0,1 ; c = 0,025
%m CuO = 0,05.80/12 .100% = 33,33%
%m MgO = 0,1.40/12 .100% = 33,33%
%m Fe2O3 = 33,34%
b)
n BaCO3 = 14,775/197 = 0,075(mol) > n CO2 = n CuO + 3n Fe2O3 = 0,125
Do đó, kết tủa bị hòa tan một phần
Ba(OH)2 + CO2 → BaCO3 + H2O
0,075........0,075.......0,075.............(mol)
Ba(OH)2 + 2CO2 → Ba(HCO3)2
0,025..........0,05..............................(mol)
=> n Ba(OH)2 = 0,075 + 0,025 = 0,1(mol)
=> CM Ba(OH)2 = 0,1/0,5 = 0,2M
\(a) m_{Cu} = 9,6(gam)\\ n_{Al} = a(mol) ; n_{Fe} = b(mol)\\ \Rightarrow 27a + 56b = 16,55 -9,6 =6,95(1)\\ 2Al + 6HCl \to 2AlCl_3 + 3H_2\\ Fe + 2HCl \to FeCl_2 + H_2\\ n_{H_2} = 1,5a + b = \dfrac{3,92}{22,4} = 0,175(2)\\ (1)(2) \Rightarrow a = 0,05 ; b = 0,1\\ m_{Al} = 0,05.27 = 1,35(gam); n_{Fe} = 0,1.56 = 5,6(gam)\)
\(b) n_{HCl} = 2n_{H_2} = 0,175.2 = 0,35(mol) \Rightarrow m_{HCl} = 0,35.36,5 = 12,775(gam)\)
\(n_{Zn}=\dfrac{6.5}{65}=0.1\left(mol\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(0.1.................................0.1\)
\(Đặt:n_{CuO\left(pư\right)}=x\left(mol\right)\)
\(CuO+H_2\underrightarrow{t^0}Cu+H_2O\)
\(x............x\)
\(m_{cr}=6-80x+64x=5.2\left(g\right)\)
\(\Rightarrow x=0.05\)
\(H\%=\dfrac{0.05}{0.075}\cdot100\%=66.67\%\)
PTHH: \(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
\(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
\(2Cu+O_2\underrightarrow{t^o}2CuO\)
Ta có: \(n_{O_2}=\dfrac{1,6}{32}=0,05\left(mol\right)\)\(\Rightarrow n_{Cu}=n_{CuO}=0,1\left(mol\right)\)
\(\Rightarrow\%m_{CuO}=\dfrac{0,1\cdot80}{40}\cdot100\%=20\%\)
\(\Rightarrow\%m_{Fe_2O_3}=80\%\)
a) A gồm Cu, Fe
\(n_O=\dfrac{39,2-29,6}{16}=0,6\left(mol\right)\)
=> \(n_{H_2O}=0,6\left(mol\right)\)
=> \(n_{H_2}=0,6\left(mol\right)\)
=> \(V_{H_2}=0,6.22,4=13,44\left(l\right)\)
b)
Gọi \(\left\{{}\begin{matrix}n_{CuO}=a\left(mol\right)\\n_{Fe_xO_y}=b\left(mol\right)\end{matrix}\right.\)
=> 80a + b(56x + 16y) = 39,2
=> 80a + 56bx + 16by = 39,2 (1)
nO = 0,6 (mol)
=> a + by = 0,6
=> 80a + 80by = 48 (2)
\(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
PTHH: Fe + 2HCl --> FeCl2 + H2
0,3<-------------------0,3
=> nFe = bx = 0,3 (mol)
(2) - (1) => 64by - 56bx = 8,8
=> by = 0,4
Xét \(\dfrac{bx}{by}=\dfrac{x}{y}=\dfrac{0,3}{0,4}=\dfrac{3}{4}\)
=> CTHH: Fe3O4
Có: \(\left\{{}\begin{matrix}80a+232b=39,2\\a+4b=0,6\end{matrix}\right.\)
=> a = 0,2; b = 0,1
=> \(\left\{{}\begin{matrix}m_{CuO}=0,2.80=16\left(g\right)\\m_{Fe_3O_4}=0,1.232=23,2\left(g\right)\end{matrix}\right.\)
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