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a) PTHH :
2KClO3 \(\rightarrow\)2KCl + 3O2 (1)
CH4 + 2O2 \(\rightarrow\)CO2 + 2H2O (2)
2H2 + O2 \(\rightarrow\) 2H2O (3)
Theo PT(2) => nO2 = 2.nCH4 = 2 x 0.5 =1(mol)
Theo PT(3) => nO2 = 1/2 x nH2 = 1/2 x 0.25 =0.125(mol)
=> tổng nO2 = 1+ 0.125 =1.125(mol)
Theo PT(1) => nKClO3 = 2/3 . nO2 = 2/3 x 1.125 = 0.75(mol)
=> mKClO3 = n .M = 0.75 x 122.5 =91.875(g)
b) 4Al + 3O2 \(\rightarrow\) 2Al2O3 (4)
2Zn + O2 \(\rightarrow\) 2ZnO (5)
nAl = m : M = 6.75/27=0.25(mol)
nZn = m/M = 9.75/65 =0.15(mol)
Theo PT(4) => nO2 = 3/4 . nAl = 3/4 x 0.25 =0.1875(mol)
Theo PT(5) => nO2 = 1/2 x nZn = 1/2 x 0.15 =0.075(mol)
tổng nO2 = 0.1875 + 0.075 =0.2625(mol)
theo PT(1) => nKClO3 = 2/3 x nO2 = 2/3 x 0.2625 =0.175(mol)
=> mKClO3 = n .M = 0.175 x 122.5 =21.4375(g)
a) \(CH_4+2O_2\underrightarrow{t\text{°}}CO_2+2H_2O\)(1)
___0,5------>1___________________(mol)
\(2H_2+O_2\underrightarrow{t\text{°}}2H_2O\)(2)
0,25->0,125__0,25____(mol)
\(2KClO_3\underrightarrow{t\text{°}}2KCl+3O_2\)(3)
0,75<---------------0,125+1=1,125(mol)
=> mKClO3= 0,75*122,5=91,875(g)
b) n Al= 6,75/27=0,25(mol)
n Zn= 9,75/65= 0,15 (mol)
\(4Al+2O_2\underrightarrow{t\text{°}}2Al_2O_3\) (1')
0.25-->0.125_________(mol)
\(2Zn+O_2\underrightarrow{t\text{}\text{°}}2ZnO\) (2')
0.15->0.075_________(mol)
\(2KClO_3\underrightarrow{t\text{°}}2KCl+3O_2\)(3')
\(\frac{2}{15}\)<-------------------0.075+0.125=0.2(mol)
m KClO3=\(\frac{2}{15}\)*122,5=\(\frac{49}{3}\) (g)
nAl=16,2/27= 0,6(mol)
a) PTHH: 4 Al +3 O2 -to-> 2 Al2O3
nO2= 3/4 . nAl=3/4 . 0,6= 0,45(mol)
=> V(O2,đktc)=0,45 x 22,4=10,08(l)
b) nAl2O3= nAl/2=0,6/2=0,3(mol)
=>mAl2O3=102. 0,3= 30,6(g)
c) 2KMnO4 -to-> K2MnO4 + MnO2 + O2
nKMnO4= 2.nO2=2. 0,45=0,9(mol)
=>mKMnO4= 158 x 0,9= 142,2(g)
\(n_C=\dfrac{1.2}{12}=0.1\left(mol\right)\\ n_S=\dfrac{4}{32}=0.125\left(mol\right)\)
\(2KMnO_4\underrightarrow{t^0}K_2MnO_4+MnO_2+O_2\)
\(C+O_2\underrightarrow{t^0}CO_2\)
\(S+O_2\underrightarrow{t^0}SO_2\)
\(\sum n_{O_2}=n_C+n_S=0.1+0.125=0.225\left(mol\right)\)
\(\Rightarrow n_{KMnO_4}=2n_{O_2}=0.225\cdot2=0.45\left(mol\right)\)
\(m_{KMnO_4}=0.45\cdot158=71.1\left(g\right)\)
Ta có PTHH
2KMnO4\(\rightarrow\) MnO2 + O2+ K2MnO4 (1)
4Al +3 O2 \(\rightarrow\) 2Al2O3 (2)
nAl = m/M = 10.8/27 =0.4 (mol)
theo PT(2) => nO2 = 3/4 nAl = 3/4 . 0.4 = 0.3 (mol)
=> nO2(PT1) = 0.3 (mol)
theo PT(1) => nKMnO4 = 2 nO2 = 2 x 0.3 = 0.6(mol)
=> mKMnO4 = n . M = 0.6 x 158=94.8 (g)
Bài 1 :
\(n_{Na}=\dfrac{m}{M}=0,1\left(mol\right)\)
\(4Na+O_2\rightarrow2Na_2O\)
..0,1....0,025....0,05.......
a, \(V_{O_2}=n.22,4=0,56\left(l\right)\)
b, \(m=m_{Na_2o}=n.M=3,1\left(g\right)\)
Bài 2 :
\(n_{Al}=\dfrac{m}{M}=0,1\left(mol\right)\)
\(4Al+3O_2\rightarrow2Al_2O_3\)
..0,1...0,075...
\(\Rightarrow n_{O_2}=0,075\left(mol\right)\)
Mà : \(\Sigma n_{O_2}=\dfrac{V}{22,4}=0,4\left(mol\right)\)
\(\Rightarrow n_{O_2\left(Mg\right)}=0,4-0,075=0,325\left(mol\right)\)
\(2Mg+O_2\rightarrow2MgO\)
.0,65.....0,325........
\(\Rightarrow m_{Mg}=15,6\left(g\right)\)
\(\Rightarrow m_{hh}=2,7+15,6=18,3\left(g\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%Al=~14,75\\\%Mg=~85,25\end{matrix}\right.\) %
Bài 3 :
- Gọi số mol Al và Mg lần lượt là x , y
\(4Al+3O_2\rightarrow2Al_2O_3\)
..x....0,75x
\(2Mg+O_2\rightarrow2MgO\)
..y........0,5y...........
Có : \(n_{O_2}=0,75x+0,5y=\dfrac{V}{22,4}=0,1\left(mol\right)\left(I\right)\)
Lại có : \(m_{hh}=m_{Al}+m_{Mg}=27x+24y=3,9\left(II\right)\)
- Giair ( i ) và ( ii ) ta được : \(\left\{{}\begin{matrix}x=0,1\\y=0,05\end{matrix}\right.\) ( mol )
\(\Rightarrow\left\{{}\begin{matrix}\%Al=~69,23\\\%Mg=~30,77\end{matrix}\right.\) %
Vậy ...
nAl= 6,75/27=0,25(mol)
nZn= 9,75/65= 0,15(mol)
4 Al + 3 O2 -to-> 2 Al2O3
0,25____0,1875___0,125(mol)
Zn + 1/2 O2 -to->ZnO
0,15___0,075___0,15(mol)
=> n(O2, tổng)= 0,1875+ 0,075= 0,2625(mol)
PTHH: 2 KMnO4 -to-> K2MnO4 + MnO2 + O2
0,525<----------------------------------------------0,2625(mol)
=> mKMnO4= 0,525.158= 82,95(g)
=> m=82,95(g)
Giải chi tiết cho mik nhé!