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\(n_{CuSO4}=\dfrac{16\%.50}{100\%.160}=0,05\left(mol\right)\)
Pt : \(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)
0,05-------->0,1---------->0,05--------->0,05
a) \(C\%_{ddNaOH}=\dfrac{0,1.40}{250}.100\%=1,6\%\)
b) \(m_{ddspu}=50+250-0,05.98=295,1\left(g\right)\)
\(C\%_{Na2SO4}=\dfrac{0,05.142}{295,1}.100\%=2,41\%\)
\(n_{CuSO_4}=\dfrac{m_{dd}\cdot C\%}{100\cdot M}=\dfrac{50\cdot16\%}{100\cdot\left(64+32+16\cdot4\right)}=0,05\left(mol\right)\)
\(PTHH:CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)
1 2 1 1
0,05 0,1 0,05 0,05 (mol)
\(a)C\%_{NaOH}=\dfrac{n\cdot100\cdot M}{m_{dd}}=\dfrac{01\cdot100\cdot\left(23+16+1\right)}{250}=1,6\%\)
\(b)m_{dd-sau-pư}=m_{dd_đ}+m_{ct_đ}-m\downarrow-m\uparrow\)
\(=50+250-\left(0,05\cdot23+32+16\cdot4\right)=294,05\left(g\right)\)
\(C\%_{Na_2SO_4}=\dfrac{n\cdot100\cdot M}{m_{dd}}=\dfrac{0,05\cdot100\cdot\left(23\cdot2+32+16\cdot4\right)}{294,05}\approx2,41\%.\)
a, PT: \(Mg+2HCl\rightarrow MgCl_2+H_2\)
\(MgCl_2+2NaOH\rightarrow2NaCl+Mg\left(OH\right)_{2\downarrow}\)
\(Mg\left(OH\right)_2\underrightarrow{t^o}MgO+H_2O\)
b, Ta có: \(n_{Mg}=\dfrac{9,6}{24}=0,4\left(mol\right)\)
Theo PT: \(n_{HCl}=2n_{Mg}=0,8\left(mol\right)\)
\(\Rightarrow C_{M_{HCl}}=\dfrac{0,8}{0,2}=4\left(M\right)\)
c, Theo PT: \(n_{MgO}=n_{Mg}=0,4\left(mol\right)\)
\(\Rightarrow m_{MgO}=0,4.40=16\left(g\right)\)
a, \(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(n_{Fe}=n_{H_2}=0,15\left(mol\right)\Rightarrow m_{Fe}=0,15.56=8,4\left(g\right)\)
b, \(n_{Na_2O}=\dfrac{6,2}{62}=0,1\left(mol\right)\)
\(Na_2O+H_2O\rightarrow2NaOH\)
\(n_{NaOH}=2n_{Na_2O}=0,2\left(mol\right)\Rightarrow C_{M_{NaOH}}=\dfrac{0,2}{0,5}=0,4\left(M\right)\)
\(a,n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
PTHH:
\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
0,15 0,3 0,15 0,15
\(m_{Fe}=0,15.56=8,4\left(g\right)\)
\(a,n_{Na_2O}=\dfrac{6,2}{62}=0,1\left(mol\right)\)
PTHH :
\(Na_2O+H_2O\rightarrow2NaOH\)
0,1 0,1 0,2
\(C_{M\left(A\right)}=\dfrac{0,2}{0,5}=0,4\left(M\right)\)
Gọi \(n_{Fe}=x\left(mol\right)\)\(;n_{Zn}=y\left(mol\right)\)
\(n_{H_2}=\dfrac{6,72}{22,4}=0,3mol\)
Ta có: \(\left\{{}\begin{matrix}56x+65y=18,6\\2x+2y=2n_{H_2}=0,6\end{matrix}\right.\)\(\Rightarrow\left\{{}\begin{matrix}x=0,1\\y=0,2\end{matrix}\right.\)
\(\%m_{Fe}=\dfrac{0,1\cdot56}{18,6}\cdot100\%=30,11\%\)
\(\%m_{Zn}=100\%-30,11\%=69,89\%\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
0,1 0,2
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,2 0,4
\(n_{HCl}=0,2+0,4=0,6mol\)
\(C_M=\dfrac{n}{V}=\dfrac{0,6}{0,2}=3M\)
\(n_{CuO}=\dfrac{8}{80}=0,1\left(mol\right)\)
PT: \(CuO+2HCl\rightarrow CuCl_2+H_2O\)
a, \(n_{HCl}=2n_{CuO}=0,2\left(mol\right)\Rightarrow C\%_{HCl}=\dfrac{0,2.36,5}{200}.100\%=3,65\%\)
b, \(n_{CuCl_2}=n_{CuO}=0,1\left(mol\right)\)
\(\Rightarrow C\%_{CuCl_2}=\dfrac{0,1.135}{8+200}.100\%\approx6,49\%\)
\(n_{H_2}=\dfrac{2,24}{22,4}=0,1(mol)\\ PTHH:Zn+2HCl\to ZnCl_2+H_2\\ \Rightarrow n_{Zn}=n_{H_2}=0,1(mol)\\ a,\%_{Zn}=\dfrac{0,1.65}{9,7}.100\%=67,01\%\\ \Rightarrow \%_{Cu}=100\%-67,01\%=32,99\%\\ b,n_{HCl}=2n_{H_2}=0,2(mol)\\ \Rightarrow C\%_{HCl}=\dfrac{0,2.36,5}{50}.100\%=14,6\%\\ c,PTHH:Zn+H_2SO_4\to ZnSO_4+H_2\\ \Rightarrow n_{H_2SO_4}=n_{H_2}=0,1(mol)\\ \Rightarrow V_{dd_{H_2SO_4}}=\dfrac{0,1}{0,2}=0,5(l)\)
\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\\ PTHH:Fe+2HCl\rightarrow FeCl_2+H_2\\ n_{FeCl_2}=n_{H_2}=n_{Fe}=0,1\left(mol\right)\\ m_{ddFeCl_2}=5,6+50-0,1.2=55,4\left(g\right)\\ C\%_{ddFeCl_2}=\dfrac{127.0,1}{55,4}.100\%\approx22,924\%\)