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\(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\) ; \(n_{O_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
\(3Fe+2O_2\rightarrow\left(t^o\right)Fe_3O_4\)
0,2 < 0,25 ( mol )
0,2 \(\dfrac{2}{15}\) \(\dfrac{1}{15}\) ( mol )
`->` Chất dư là O2
\(m_{O_2\left(dư\right)}=\left(0,25-\dfrac{2}{15}\right).32=3,73\left(g\right)\)
\(V_{kk}=V_{O_2}.5=\dfrac{2}{15}.22,4.5=14,93\left(l\right)\)
\(m_{bôt.sắt}=\dfrac{11,2.100}{100-12}=12,72\left(g\right)\)
Câu 7.
a. \(n_P=\dfrac{15.5}{31}=0,5\left(mol\right)\)
PTHH : 4P + 5O2 ----to---> 2P2O5
0,5 0,625 0,25
\(m_{P_2O_5}=0,25.142=35,5\left(g\right)\)
b. \(V_{O_2}=0,625.22,4=14\left(l\right)\\ \Rightarrow V_{kk}=14.5=70\left(l\right)\)
Ta có: \(n_P=\dfrac{12,4}{31}=0,4\left(mol\right)\)
PT: \(4P+5O_2\underrightarrow{t^o}2P_2O_5\)
____0,4____0,5____0,2 (mol)
a, \(m_{P_2O_5}=0,2.142=28,4\left(g\right)\)
b, \(V_{O_2}=0,5.22,4=11,2\left(l\right)\Rightarrow V_{kk}=5V_{O_2}=56\left(l\right)\)
nP= 12.4/31=0.4 mol
4P + 5O2 -to-> 2P2O5
0.4___0.5
VO2= 0.5*22.4=11.2l
VKK=5VO2= 11.2*5=56l
2KClO3 -to-> 2KCl + 3O2
1/3________________0.5
mKClO3= 1/3*122.5=245/6g
\(n_{H_2}=\dfrac{13,44}{22,4}=0,6mol\)
\(2H_2+O_2\rightarrow\left(t^o\right)2H_2O\)
0,6 0,3 0,6 ( mol )
\(m_{H_2O}=0,6.18=10,8g\)
\(V_{kk}=V_{O_2}.5=\left(0,3.22,4\right).5=33,6l\)
a, \(2Zn+O_2\underrightarrow{t^o}2ZnO\)
b, \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{1}{2}n_{Zn}=0,1\left(mol\right)\Rightarrow V_{O_2}=0,1.22,4=2,24\left(l\right)\)
\(\Rightarrow V_{kk}=5V_{O_2}=11,2\left(l\right)\)
c, \(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
Theo PT: \(n_{KMnO_4}=2n_{O_2}=0,2\left(mol\right)\Rightarrow m_{KMnO_4}=0,2.158=31,6\left(g\right)\)
Theo gt ta có: $n_{H_2}=0,75(mol)$
a, $2H_2+O_2\rightarrow 2H_2O$
Ta có: $n_{O_2}=0,5.n_{H_2}=0,375(mol)\Rightarrow V_{O_2}=8,4(l)\Rightarrow V_{kk}=42(l)$
b, $2KMnO_4\rightarrow K_2MnO_4+MnO_2+O_2$
Ta có: $n_{KMnO_4}=2.n_{O_2}=0,75(mol)\Rightarrow m_{KMnO_4}=118,5(g)$
a)
\(2H_2 + O_2 \xrightarrow{t^o} 2H_2O\\ V_{O_2} = \dfrac{V_{H_2}}{2} = \dfrac{16,8}{2} = 8,4(lít)\\ V_{không\ khí} = \dfrac{8,4}{20\%} = 42(lít)\)
b)
\(n_{O_2} = \dfrac{8,4}{22,4} = 0,375(mol)\\ 2KMnO_4 \xrightarrow{t^o} K_2MnO_4 + MnO_2 + O_2\\ n_{KMnO_4} = 2n_{O_2} = 0,75(mol)\\ \Rightarrow m_{KMnO_4} = 0,75.158 = 118,5(gam)\\ 2KClO_3 \xrightarrow{t^o} 2KCl + 3O_2\\ n_{KClO_3} = \dfrac{2}{3}n_{O_2} = 0,25(mol)\\ \Rightarrow m_{KClO_3} = 0,25.122,5 = 30,625(gam)\)
\(1,2H_2+O_2\underrightarrow{t}2H_2O\)
\(2Mg+O_2\underrightarrow{t}2MgO\)
\(2Cu+O_2\underrightarrow{t}2CuO\)
\(S+O_2\underrightarrow{t}SO_2\)
\(4Al+3O_2\underrightarrow{t}2Al_2O_3\)
\(C+O_2\underrightarrow{t}CO_2\)
\(4P+5O_2\underrightarrow{t}2P_2O_5\)
\(2,PTHH:C+O_2\underrightarrow{t}CO_2\)
\(a,n_{O_2}=0,2\left(mol\right)\Rightarrow n_{CO_2}=0,2\left(mol\right)\Rightarrow m_{CO_2}=8,8\left(g\right)\)
\(b,n_C=0,3\left(mol\right)\Rightarrow n_{CO_2}=0,3\left(mol\right)\Rightarrow m_{CO_2}=13,2\left(g\right)\)
c, Vì\(\frac{0,3}{1}>\frac{0,2}{1}\)nên C phản ửng dư, O2 phản ứng hết, Bài toán tính theo O2
\(n_{O_2}=0,2\left(mol\right)\Rightarrow n_{CO_2}=0,2\left(mol\right)\Rightarrow m_{CO_2}=8,8\left(g\right)\)
\(3,PTHH:CH_4+2O_2\underrightarrow{t}CO_2+2H_2O\)
\(C_2H_2+\frac{5}{2}O_2\underrightarrow{t}2CO_2+H_2O\)
\(C_2H_6O+3O_2\underrightarrow{t}2CO_2+3H_2O\)
\(4,a,PTHH:4P+5O_2\underrightarrow{t}2P_2O_5\)
\(n_P=1,5\left(mol\right)\Rightarrow n_{O_2}=1,2\left(mol\right)\Rightarrow m_{O_2}=38,4\left(g\right)\)
\(b,PTHH:C+O_2\underrightarrow{t}CO_2\)
\(n_C=2,5\left(mol\right)\Rightarrow n_{O_2}=2,5\left(mol\right)\Rightarrow m_{O_2}=80\left(g\right)\)
\(c,PTHH:4Al+3O_2\underrightarrow{t}2Al_2O_3\)
\(n_{Al}=2,5\left(mol\right)\Rightarrow n_{O_2}=1,875\left(mol\right)\Rightarrow m_{O_2}=60\left(g\right)\)
\(d,PTHH:2H_2+O_2\underrightarrow{t}2H_2O\)
\(TH_1:\left(đktc\right)n_{H_2}=1,5\left(mol\right)\Rightarrow n_{O_2}=0,75\left(mol\right)\Rightarrow m_{O_2}=24\left(g\right)\)
\(TH_2:\left(đkt\right)n_{H_2}=1,4\left(mol\right)\Rightarrow n_{O_2}=0,7\left(mol\right)\Rightarrow m_{O_2}=22,4\left(g\right)\)
\(5,PTHH:S+O_2\underrightarrow{t}SO_2\)
\(n_{O_2}=0,46875\left(mol\right)\)
\(n_{SO_2}=0,3\left(mol\right)\)
Vì\(0,46875>0,3\left(n_{O_2}>n_{SO_2}\right)\)nên S phản ứng hết, bài toán tính theo S.
\(a,\Rightarrow n_S=n_{SO_2}=0,3\left(mol\right)\Rightarrow m_S=9,6\left(g\right)\)
\(n_{O_2}\left(dư\right)=0,16875\left(mol\right)\Rightarrow m_{O_2}\left(dư\right)=5,4\left(g\right)\)
\(6,a,PTHH:C+O_2\underrightarrow{t}CO_2\)
\(n_{O_2}=1,5\left(mol\right)\Rightarrow n_C=1,5\left(mol\right)\Rightarrow m_C=18\left(g\right)\)
\(b,PTHH:2H_2+O_2\underrightarrow{t}2H_2O\)
\(n_{O_2}=1,5\left(mol\right)\Rightarrow n_{H_2}=0,75\left(mol\right)\Rightarrow m_{H_2}=1,5\left(g\right)\)
\(c,PTHH:S+O_2\underrightarrow{t}SO_2\)
\(n_{O_2}=1,5\left(mol\right)\Rightarrow n_S=1,5\left(mol\right)\Rightarrow m_S=48\left(g\right)\)
\(d,PTHH:4P+5O_2\underrightarrow{t}2P_2O_5\)
\(n_{O_2}=1,5\left(mol\right)\Rightarrow n_P=1,2\left(mol\right)\Rightarrow m_P=37,2\left(g\right)\)
\(7,n_{O_2}=5\left(mol\right)\Rightarrow V_{O_2}=112\left(l\right)\left(đktc\right)\);\(V_{O_2}=120\left(l\right)\left(đkt\right)\)
\(8,PTHH:C+O_2\underrightarrow{t}CO_2\)
\(m_C=0,96\left(kg\right)\Rightarrow n_C=0,08\left(kmol\right)=80\left(mol\right)\Rightarrow n_{O_2}=80\left(mol\right)\Rightarrow V_{O_2}=1792\left(l\right)\)
\(9,n_p=0,2\left(mol\right);n_{O_2}=0,3\left(mol\right)\)
\(PTHH:4P+5O_2\underrightarrow{t}2P_2O_5\)
Vì\(\frac{0,2}{4}< \frac{0,3}{5}\)nên P hết O2 dư, bài toán tính theo P.
\(a,n_{O_2}\left(dư\right)=0,05\left(mol\right)\Rightarrow m_{O_2}\left(dư\right)=1,6\left(g\right)\)
\(b,n_{P_2O_5}=0,1\left(mol\right)\Rightarrow m_{P_2O_5}=14,2\left(g\right)\)
a) \(n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\)
PTHH: \(3Fe+2O_2\xrightarrow[]{t^o}Fe_3O_4\)
0,3--->0,2----->0,1
\(\Rightarrow m_{Fe_3O_4}=0,1.232=23,2\left(g\right)\)
b) \(V_{O_2}=0,2.22,4=4,48\left(l\right)\Rightarrow V_{kk}=4,48.5=22,4\left(l\right)\)
c) \(n_{O_2\left(hao,h\text{ụt}\right)}=0,2.10\%=0,02\left(mol\right)\)
\(\Rightarrow n_{O_2\left(t\text{ổng}\right)}=0,2+0,02=0,22\left(mol\right)\)
PTHH: \(2KMnO_4\xrightarrow[]{t^o}K_2MnO_4+MnO_2+O_2\)
0,44<------------------------------------0,22
\(\Rightarrow m_{KMnO_4}=0,44.158=69,52\left(g\right)\)
