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a)
C2H4 + Br2 --> C2H4Br2
C2H2 + 2Br2 --> C2H2Br4
b) Gọi số mol C2H4, C2H2 là a, b (mol)
=> \(a+b=\dfrac{11,2}{22,4}=0,5\) (1)
PTHH: C2H4 + Br2 --> C2H4Br2
a---->a
C2H2 + 2Br2 --> C2H2Br4
b---->2b
=> a + 2b = \(\dfrac{112}{160}=0,7\) (2)
(1)(2) => a = 0,3 (mol); b = 0,2 (mol)
\(\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,3}{0,5}.100\%=60\%\\\%V_{C_2H_2}=\dfrac{0,2}{0,5}.100\%=40\%\end{matrix}\right.\)
\(\left\{{}\begin{matrix}\%m_{C_2H_4}=\dfrac{0,3.28}{0,3.28+0,2.26}.100\%=61,765\%\\\%m_{C_2H_2}=\dfrac{0,2.26}{0,3.28+0,2.26}.100\%=38,235\%\end{matrix}\right.\)
\(n_{hh}=\dfrac{3,36}{22,4}=0,15mol\)
\(n_{Br_2}=\dfrac{2,4}{160}=0,015mol\)
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
0,0075 0,015 ( mol )
\(V_{C_2H_2}=0,0075.22,4=0,168l\)
\(V_{CH_4}=3,36-0,168=3,192l\)
\(\%V_{C_2H_2}=\dfrac{0,168}{3,36}.100=5\%\)
\(\%V_{CH_4}=100\%-5\%=95\%\)
\(n_{Br_2}=\dfrac{m_{Br_2}}{M_{Br_2}}=\dfrac{16}{160}=0,1mol\)
\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
0,1 0,1 ( mol )
\(\%V_{C_2H_4}=\dfrac{0,1.22,4}{16,8}.100=13,33\%\)
\(\%V_{CH_4}=100\%-13,33\%=86,67\%\)
PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
Ta có: \(n_{Br_2}=\dfrac{16}{160}=0,1\left(mol\right)\)
Theo PT: \(n_{C_2H_4}=n_{Br_2}=0,1\left(mol\right)\Rightarrow V_{C_2H_4}=0,1.22,4=2,24\left(l\right)\)
\(\Rightarrow V_{CH_4}=6,72-2,24=4,48\left(l\right)\)
a, \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
Ta có: \(n_{C_2H_4}+n_{C_2H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\left(1\right)\)
Theo PT: \(n_{Br_2}=n_{C_2H_4}+2n_{C_2H_2}=\dfrac{48}{160}=0,3\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,2\left(mol\right)\\y=0,05\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,2.22,4}{5,6}.100\%=80\%\\\%V_{C_2H_2}=20\%\end{matrix}\right.\)
b, \(V_{ddBr_2}=\dfrac{0,3}{0,25}=1,2\left(M\right)\)
PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
Gọi: \(\left\{{}\begin{matrix}n_{C_2H_4}=x\left(mol\right)\\n_{C_2H_2}=y\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow x+y=\dfrac{2,24}{22,4}=0,1\left(mol\right)\left(1\right)\)
\(n_{Br_2}=n_{C_2H_4}+2n_{C_2H_2}=x+2y=\dfrac{24}{160}=0,15\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow x=y=0,05\left(mol\right)\)
\(\Rightarrow\%V_{C_2H_4}=\%V_{C_2H_2}=\dfrac{0,05.22,4}{2,24}.100\%=50\%\)
a)
C2H4 + Br2 --> C2H4Br2
b) \(n_{Br_2}=\dfrac{32}{160}=0,2\left(mol\right)\)
PTHH: C2H4 + Br2 --> C2H4Br2
0,2<---0,2
=> \(\%V_{C_2H_4}=\dfrac{0,2.22,4}{8,96}.100\%=50\%\)
=> \(\%V_{CH_4}=100\%-50\%=50\%\)
\(m_{Br_2}=80g\Rightarrow n_{Br_2}=0,5mol\)
\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
0,5 0,5
\(n_{hh}=\dfrac{28}{22,4}=1,25mol\)
\(\Rightarrow n_{CH_4}=1,25-0,5=0,75mol\)
\(\%V_{CH_4}=\dfrac{0,75}{1,25}\cdot100\%=60\%\)
\(\%V_{C_2H_4}=100\%-60\%=40\%\)
\(n_{Br_2}=\dfrac{1,92}{160}=0,012\left(mol\right)\)
Gọi số mol C2H4, C2H2 là a, b (mol)
=> \(a+b=\dfrac{0,224}{22,4}=0,01\) (1)
PTHH: C2H4 + Br2 --> C2H4Br2
a---->a
C2H2 + 2Br2 --> C2H2Br4
b----->2b
=> a + 2b = 0,012 (2)
(1)(2) => a = 0,008 (mol); b = 0,002 (mol)
=> \(\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,008}{0,01}.100\%=80\%\\\%V_{C_2H_2}=100\%-80\%=20\%\end{matrix}\right.\)