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\(2CO + O_2 \xrightarrow{t^o} 2CO_2\\ 2H_2 + O_2 \xrightarrow{t^o} 2H_2O\\ n_{CO} = n_{CO_2} = \dfrac{8,8}{44} = 0,2(mol)\\ n_{O_2} = \dfrac{n_{CO} + n_{H_2}}{2}=\dfrac{0,2+n_{H_2}}{2} = \dfrac{9,6}{32} = 0,3(mol)\\ \Rightarrow n_{H_2} = 0,4(mol)\\ \%V_{CO} = \dfrac{0,2}{0,2 + 0,4}.100\% = 33,33\%\\ \%V_{H_2} = 100\% - 33,33\% = 66,67\%\\ \%m_{CO} = \dfrac{0,2.28}{0,2.28+0,4.2}.100\%=87,5\%\\ \%m_{H_2} = 100\% - 87,5\% = 12,5\%\)
\(n_C=\dfrac{14,4}{44}=\dfrac{18}{55}\left(mol\right)\\ C+O_2\rightarrow\left(t^o\right)CO_2\\ n_{O_2}=n_C=n_{CO_2}=\dfrac{18}{55}\left(mol\right)\\ a,V_{O_2\left(đktc\right)}=\dfrac{18}{55}.22,4=\dfrac{2016}{275}\left(lít\right)\\ b,V_{kk}=\dfrac{100}{21}.\dfrac{2016}{275}=\dfrac{381}{11}\left(lít\right)\\ c,2KClO_3\rightarrow\left(t^o\right)2KCl+3O_2\\ n_{KClO_3\left(LT\right)}=\dfrac{2}{3}.n_{O_2}=\dfrac{2}{3}.\dfrac{18}{55}=\dfrac{12}{55}\left(mol\right)\\ \Rightarrow n_{KClO_3\left(TT\right)}=120\%.\dfrac{12}{55}=\dfrac{72}{275}\left(mol\right)\\ \Rightarrow m_{KClO_3}=122,5.\dfrac{72}{275}=\dfrac{1764}{55}\left(g\right)\)
PTHH: 2CO+O2to→2CO2 (1)
4H2+O2to→2H2O (2)
b) Ta có:
ΣnO2=\(\dfrac{9,6}{32}\)=0,3(mol)
nCO2=\(\dfrac{8,8}{44}\)=0,2(mol)
⇒{nO2(1)=0,1mol
nO2(2)=0,2mol
⇒{mCO=0,1⋅28=2,8(g)
mH2=0,2⋅2=0,4(g)
⇒%mCO=\(\dfrac{2,8}{2,8+0,4}\)⋅100%=87,5%
%mH2=12,5%
\(nO_2=\dfrac{9,6}{32}=0,3\left(mol\right)\)
\(nCO_2=\dfrac{8,8}{44}=0,2\left(mol\right)\)
\(2CO+O_2\underrightarrow{t^o}2CO_2\)
2 1 2 (mol)
0,2 0,1 0,2 (mol)
\(4H_2+O_2\underrightarrow{t^o}2H_2O\)
4 1 2 (mol)
0,8 0,2 0,4 (mol)
\(mCO=0,2.28=5,6\left(g\right)\)
\(mH_2=0,8.2=0,16\left(g\right)\)
\(\%mCO=\dfrac{5,6.100}{5,6+0,16}=97,22\%\)
\(\%mH_2=100-97,22=2,78\%\)
16 nCO2=0,2mol
PTHH: 2CO+O2=>2CO2
0,2<--0,1<---0,2
=> mO2=0,2.32=6,4g
=> khối lượng Oxi phản ứng với H2 là :
9,6-6,4=3,2g
=> nH2O=3,2:32=0,1mol
PTHH: 2H+O2=>H2O
b)
0,2<-0,1<-0,2
=> mH2=2.0,2=0,4g
mCO =0,2.28=5,6g
=> m hh=5,6+0,4=6g
CuO+H2-to--->Cu+H2O
0,6----0,6
nCuO =48/80=0,6 (mol)
==>VH2 =0,6×22,4=13.44(l)
17.
\(n_{Fe}=\dfrac{5,6}{56}=0,1mol\)
\(m_{H_2SO_4}=200.19,6\%=39,2g\)
\(n_{H_2SO_4}=\dfrac{39,2}{98}=0,4mol\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
0,1 < 0,4 ( mol )
0,1 0,1 0,1 0,1 ( mol )
\(V_{H_2}=0,1.22,4=2,24l\)
Chất còn dư là H2SO4
\(m_{H_2SO_4\left(dư\right)}=\left(0,4-0,1\right).98=29,4g\)
\(\left\{{}\begin{matrix}m_{FeSO_4}=0,1.152=15,2g\\m_{H_2}=0,1.2=0,2g\end{matrix}\right.\)
\(m_{ddspứ}=5,6+200-0,1.2=205,4g\)
\(\left\{{}\begin{matrix}C\%_{FeSO_4}=\dfrac{15,2}{205,4}.100=7,4\%\\C\%_{H_2}=\dfrac{0,2}{205,4}.100=0,09\%\\C\%_{H_2SO_4\left(dư\right)}=\dfrac{29,4}{205,4}.100=14,31\%\end{matrix}\right.\)
a) PTHH: \(2CO+O_2\underrightarrow{t^o}2CO_2\) (1)
\(4H_2+O_2\underrightarrow{t^o}2H_2O\) (2)
b) Ta có: \(\left\{{}\begin{matrix}\Sigma n_{O_2}=\dfrac{9,6}{32}=0,3\left(mol\right)\\n_{CO_2}=\dfrac{8,8}{44}=0,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}n_{O_2\left(1\right)}=0,1mol\\n_{O_2\left(2\right)}=0,2mol\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{CO}=0,1\cdot28=2,8\left(g\right)\\m_{H_2}=0,2\cdot2=0,4\left(g\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}\%m_{CO}=\dfrac{2,8}{2,8+0,4}\cdot100\%=87,5\%\\\%m_{H_2}=12,5\%\end{matrix}\right.\)
c) PTHH: \(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\uparrow\)
Theo PTHH: \(n_{KMnO_4}=2n_{O_2}=0,6mol\)
\(\Rightarrow m_{KMnO_4}=0,6\cdot158=94,8\left(g\right)\)
\(1) n_{KMnO_4}= \dfrac{31,6}{158} = 0,2(mol)\\ 2KMnO_4 \xrightarrow{t^o} K_2MnO_4 + MnO_2 + O_2\\ n_{O_2} = \dfrac{1}{2}n_{KMnO_4} = 0,1(mol)\\ V_{O_2} = 0,1.22,4 = 2,24(lít)\\ 2) CH_4 + 2O_2 \xrightarrow{t^o} CO_2 + 2H_2O\\ V_{CH_4} = \dfrac{1}{2}V_{O_2} = 1,12(lít)\\ 3)n_{CH_4} = \dfrac{1,12}{22,4} = 0,05(mol)\\ \text{Nhiệt lượng tỏa ra = } = 0,05.880 = 44(KJ)\)
a) CH4 + 2O2 --to--> CO2 + 2H2O
b) \(V_{O_2}=\dfrac{56}{5}=11,2\left(l\right)\)
=> \(n_{O_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
PTHH: CH4 + 2O2 --to--> CO2 + 2H2O
_____0,25<--0,5-------->0,25
=> VCH4 = 0,25.22,4 = 5,6 (l)
c)
mCO2 = 0,25.44 = 11 (g)
a)
\(n_{KClO_3}=\dfrac{14,7}{122,5}=0,12\left(mol\right)\)
PTHH: 2KClO3 --to--> 2KCl + 3O2
0,12---------------->0,18
=> VO2 = 0,18.22,4 = 4,032 (l)
b)
PTHH: 4R + nO2 --to--> 2R2On
\(\dfrac{0,72}{n}\)<--0,18
=> \(M_R=\dfrac{14,4}{\dfrac{0,72}{n}}=20n\left(g/mol\right)\)
Chọn n = 2 => MR= 40 (g/mol)
=> R là Ca
c)
Gọi số mol CH4, H2 là a, b (mol)
PTHH: CH4 + 2O2 --to--> CO2 + 2H2O
a--->2a
2H2 + O2 --to--> 2H2O
b-->0,5b
=> \(\left\{{}\begin{matrix}2a+0,5b=0,18\\16a+2b=1,12\end{matrix}\right.\)
=> a = 0,05 (mol); b = 0,16 (mol)
\(\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,05}{0,05+0,16}.100\%=23,81\%\\\%V_{H_2}=\dfrac{0,16}{0,05+0,16}.100\%=76,19\%\end{matrix}\right.\)
cảm ơnnn