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a) \(n_{CH_3COOH}=\dfrac{100.12\%}{60}=0,2\left(mol\right)\)
PTHH: CH3COOH + NaHCO3 --> CH3COONa + CO2 + H2O
0,2-------->0,2----------->0,2--------->0,2
=> mNaHCO3 = 0,2.84 = 16,8 (g)
=> \(m_{dd.NaHCO_3}=\dfrac{16,8.100}{8,4}=200\left(g\right)\)
b) mCH3COONa = 0,2.82 = 16,4 (g)
mdd sau pư = 100 + 200 - 0,2.44 = 291,2 (g)
=> \(C\%_{dd.muối}=\dfrac{16,4}{291,2}.100\%=5,632\%\)
\(m_{ct}=\dfrac{12.100}{100}=12\left(g\right)\)
\(n_{CH3COOH}=\dfrac{12}{60}=0,2\left(mol\right)\)
Pt : \(CH_3COOH+NaHCO_3\rightarrow CH_3COONa+CO_2+H_2O|\)
1 1 1 1 1
0,2 0,2 0,2 0,2
a) \(n_{NaHCO3}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)
⇒ \(m_{NaHCO3}=0,2.84=16,8\left(g\right)\)
\(m_{ddNaHCO3}=\dfrac{16,8.100}{8,4}=200\left(g\right)\)
b) \(n_{CH3COONa}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)
⇒ \(m_{CH3COONa}=0,2.82=16,4\left(g\right)\)
\(m_{ddspu}=100+200-\left(0,2.44\right)=291,2\left(g\right)\)
\(C_{CH3COONa}=\dfrac{16,4.100}{291,2}=5,63\)0/0
Chúc bạn học tốt
a) PTHH: \(Na_2SO_3+H_2SO_4\rightarrow Na_2SO_4+H_2O+SO_2\uparrow\)
Ta có: \(n_{Na_2SO_3}=\dfrac{12,6}{126}=0,1\left(mol\right)=n_{SO_2}\) \(\Rightarrow V_{SO_2}=0,1\cdot22,4=2,24\left(l\right)\)
b) Ta có: \(\left\{{}\begin{matrix}n_{SO_2}=0,1\left(mol\right)\\n_{Ca\left(OH\right)_2}=1,4\cdot0,1=0,14\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) Tạo muối trung hòa
PTHH: \(Ca\left(OH\right)_2+SO_2\rightarrow CaSO_3\downarrow+H_2O\)
Ta có: \(\left\{{}\begin{matrix}n_{CaSO_3}=0,1\left(mol\right)=n_{Ns_2SO_4}\\n_{Ca\left(OH\right)_2\left(dư\right)}=0,04\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{CaSO_3}=0,1\cdot120=12\left(g\right)\\m_{Na_2SO_4}=0,1\cdot142=14,2\left(g\right)\\m_{Ca\left(OH\right)_2\left(dư\right)}=0,04\cdot74=2,96\left(g\right)\end{matrix}\right.\)
\(n_{Na_2SO_3}=0,1\left(mol\right)\\ PTHH:Na_2SO_3+H_2SO_4\rightarrow Na_2SO_4+H_2O+SO_2\)
(mol) 0,1 0,1 0,1 0,1
\(a.V_{SO_2}=0,1.22,4=2,24\left(l\right)\)
\(b.n_{Ca\left(OH\right)_2}=0,14\left(mol\right)\)
Do \(\dfrac{n_{OH}}{n_{SO_2}}=\dfrac{0,28}{0,1}=2.8>2\rightarrow\) Tạo muối trung hòa và Ca(OH)2 dư 0,04(mol)
\(PTHH:Ca\left(OH\right)_2+SO_2\rightarrow CaSO_3+H_2O\)
(mol) 0,1 0,1 0,1 0,1
\(m_{Ca\left(OH\right)_2\left(du\right)}=0,04.74=2,96\left(g\right)\\ m_{CaSO_3}=12\left(g\right)\\ m_{H_2O}=0,1.18=1,8\left(g\right)\)
\(a,n_{AlCl_3}=1\cdot0,2=0,2\left(mol\right)\\ m_{Na_2CO_3}=\dfrac{200\cdot6\%}{100\%}=12\left(g\right)\\ \Rightarrow n_{Na_2CO_3}=\dfrac{12}{106}\approx0,1\left(mol\right)\\ PTHH:3AlCl_3+2Na_2CO_3+H_2O\rightarrow2Al\left(OH\right)_3\downarrow+6NaCl+3CO_2\uparrow\)
Vì \(\dfrac{n_{AlCl_3}}{3}>\dfrac{n_{Na_2CO_3}}{2}\) nên sau phản ứng \(AlCl_3\) dư
\(\Rightarrow n_{Al\left(OH\right)_3}=n_{Na_2CO_3}=0,1\left(mol\right)\\ \Rightarrow m_{Al\left(OH\right)_3}=0,1\cdot78=7,8\left(g\right)\\ b,n_{NaCl}=3n_{Na_2CO_3}=0,3\left(mol\right)\\ \Rightarrow m_{NaCl}=0,3\cdot58,5=17,55\left(g\right)\)
Ta có ptpu
MgCO3+ 2HCl ----> MgCl2 + H2O+ CO2
\(n_{MgCO3}\)= \(\frac{9,6}{84}\)= \(\frac{0,8}{7}\) ( mol)
\(m_{HCl}\)= \(\frac{14,6}{100}.100\)= 14,6(g)
=> \(n_{HCl}\)= \(\frac{14,6}{36,5}=0,4\left(mol\right)\)
Theopt ta thấy sau phản ứng HCl dư và dư \(\frac{1,2}{7}\) mol==> m dư= 6,26 (g)
=> \(n_{CO2}\)= \(n_{MgCO3}\)= \(\frac{0,8}{7}\) mol
=> \(V_{CO2}\)= \(\frac{0,8}{7}.22,4=2,56\left(l\right)\)
b)
Ta có \(m_{CO2}\)= \(\frac{0,8}{7}.44=\frac{35,2}{7}\left(g\right)\)
\(m_{H2O}\)= \(\frac{0,8}{7}.18=\frac{14,4}{7}\)( g)
\(m_{MgCl2}\)= \(\frac{0,8}{7}.95=\frac{76}{7}\)(g)
=> \(m_{dd_{MgCl2}}\)= (9,6+100)-( \(\frac{49,6}{7}\))= 102,5(g)
=> \(C\%_{MgCl2}\)= \(\frac{\frac{76}{7}}{102,5}\). 100%= 10,6 ( %)
\(C\%_{HCl_{dư}}\)= \(\frac{6,26}{102,5}.100\)=6,107 ( %)
đề có hơi vô lý một tý nha: hỗn hợp thì phải 2 chất trở lên, nhưng trong đề chỉ có mỗi MgCO3....Đề ghi vậy thì anh làm theo đề nha
mHCl=(14.6*100)/100=14.6g=>nHCl=0.4 mol
nMgCO3=9.6/84=4/35\(\approx\) 0.114mol
theo pthh,HCl dư 2/7 mol=>mHCl dư=73/7g
MgCO3+2HCl --> MgCl2 + CO2+H2O
4/35 0.4 4/35 4/35
a)Vco2=(4/35)*22.4=2.56l
b)C%HCl dư=(73/7)/100*100=76/7\(\approx\) 10.42%
mMgCl2=4/35*95=76.7g
C%MgCl2=(76.7)/100*100=76/7\(\approx\) 10.85%
Chúc em học tốt!!1
nFe=0,2(mol)
pt: Fe + 2HCl -> FeCl2 + H2
vậy : 0,2-->0,4------>0,2---->0,2 (mol)
=> mHCl=0,4.36,5=14,6(g)
\(\Rightarrow m_{ddHCl}=\dfrac{m_{HCl}.100\%}{C\%}=\dfrac{14,6.100}{10}=146\left(g\right)\)
b) md d sau phản ung=mFe + md d HCl - mH2=11,2 +146-0,2.2=156,8(g)
mFeCl2=n.M=0,2.127=25,4 (g)
\(\Rightarrow C\%_{FeCl_2}=\dfrac{m_{FeCl_2}.100\%}{m_{ddsauphanung}}=\dfrac{25,4.100}{156,8}\approx16,2\left(\%\right)\)