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1.
\(nOH^-=2nBa\left(OH\right)_2+nKOH=2.0,25.0,01+0,25.0,02=0,01mol\)\(nH^+=2nH_2SO_4=0,5a\left(mol\right)\)
Dung dịch sau phản ứng là môi trường axit.
\(pH=2\Rightarrow\left[H^+\right]=10^{-2}M\)
\(\frac{nH^+-nOH^-}{V}=\left[H^+\right]\)
\(\Leftrightarrow\frac{0,5a-0,01}{0,5}=10^{-2}\)
\(\Leftrightarrow a=0,03M\)
\(nBa^{2+}=2,5.10^{-3}mol\)
\(nSO_4^{2-}=7,5.10^{-3}mol\)
\(Ba^{2+}+SO_4^{2-}\rightarrow BaSO_4\)
Chất sản phẩm tính theo nBa2+
\(b=2,5.10^{-3}.233=0,5825g\)
đang cần gấp ai lm đc gúp em trong chiều nay đc ko ạ cảm ơn nhìu nhìu
Ta có: \(\left\{{}\begin{matrix}n_{Ba^{2+}}=n_{Ba\left(OH\right)_2}=0,1.0,01=0,001\left(mol\right)\\n_{OH^-}=2n_{Ba\left(OH\right)_2}=2.0,1.0,01=0,002\left(mol\right)\end{matrix}\right.\)
\(\left\{{}\begin{matrix}\Sigma n_{H^+}=0,2.0,01+2.0,2.0,02=0,01\left(mol\right)\\n_{SO_4^{2-}}=n_{H_2SO_4}=0,2.0,02=0,004\left(mol\right)\end{matrix}\right.\)
PT ion: \(H^++OH^-\rightarrow H_2O\)
_____ 0,01___0,002_________ (mol)
⇒ H+ dư. \(\Rightarrow n_{H^+\left(dư\right)}=0,008\left(mol\right)\)
\(\Rightarrow\left[H^+\right]=\frac{0,008}{0,3}=\frac{2}{75}M\Rightarrow pH\approx1,57\)
PT ion: \(Ba^{2+}+SO_4^{2-}\rightarrow BaSO_{4\downarrow}\)
______ 0,001__0,004__ → 0,001 (mol)
\(\Rightarrow m_{\downarrow}=m_{BaSO_4}=0,001.233=0,233\left(g\right)\)
Bạn tham khảo nhé!
\(n_{HCl}=0.1\cdot0.03=0.003\left(mol\right)\)
\(n_{NaOH}=0.1\cdot0.01=0.001\left(mol\right)\)
\(NaOH+HCl\rightarrow NaCl+H_2O\)
Lập tỉ lệ :
\(\dfrac{0.003}{1}>\dfrac{0.001}{1}\Rightarrow HCldư\)
\(n_{HCl\left(dư\right)}=0.003-0.001=0.002\left(mol\right)\)
\(\left[H^+\right]=\dfrac{0.002}{0.1+0.1}=0.01\)
\(pH=-log\left(0.01\right)=2\)
\(b.\)
\(Ba\left(OH\right)_2+2HCl\rightarrow BaCl_2+2H_2O\)
\(0.001..........0.002\)
\(V_{Ba\left(OH\right)_2}=\dfrac{0.001}{1}=0.001\left(l\right)\)
\(n_{K_2CO_3}=0.1\cdot0.5=0.05\left(mol\right)\)
\(n_{CaCl_2}=0.1\cdot0.1=0.01\left(mol\right)\)
\(K_2CO_3+CaCl_2\rightarrow CaCO_3+2KCl\)
Lập tỉ lệ :
\(\dfrac{0.05}{1}>\dfrac{0.01}{1}\) \(\Rightarrow K_2CO_3dư\)
\(n_{CaCO_3}=n_{CaCl_2}=0.01\left(mol\right)\)
\(m=0.01\cdot100=1\left(g\right)\)
\(b.\)
Các chất có trong dung dịch :
\(K_2CO_3\left(dư\right):0.04\left(mol\right),KCl:0.02\left(mol\right)\)
\(V=0.1+0.1=0.2\left(l\right)\)
\(\left[K^+\right]=\dfrac{0.04\cdot2+0.02}{0.2}=0.5\left(M\right)\)
\(\left[CO_3^{2-}\right]=\dfrac{0.04}{0.2}=0.2\left(M\right)\)
\(\left[Cl^-\right]=\dfrac{0.02}{0.2}=0.1\left(M\right)\)
Al2(SO4)3 +6NaOH---->2Al(OH)3 +3Na2SO4(1)
Al(OH)3 +NaOH----->NaAlO2 +2H2O(2)
Ta có
n\(_{Al2\left(SO4\right)3}=0,05.0,1=0,005\left(mol\right)\)
Theo pthh1
n\(_{Al\left(OH\right)3}=2n_{Al2\left(SO4\right)3}=0,01\left(mol\right)\)
Mà n\(_{Al\left(OH\right)3}=\frac{0,78}{78}=0,01\left(mol\right)\)
=> NaOH dư
Theo pthh
n\(_{NaOH}=6n_{Al2\left(SO4\right)3}=0,06\left(mol\right)\)
V\(_{NaOH}=\frac{0,06}{0,2}=0,3\left(M\right)\)
Chúc bạn học tốt
$n_{NaOH} = 0,001(mol)$
$n_{Ba(OH)_2} = 0,01.0,15 = 0,0015(mol)$
$NaOH \to Na^+ + OH^-$
$Ba(OH)_2 \to Ba^{2+} + 2OH^-$
Ta có :
$n_{OH^-}= 0,001 + 0,0015.2 = 0,004(mol)$
$V_{dd} = 0,1 + 0,15 = 0,25(mol)$
$[OH^-] = \dfrac{0,004}{0,25} = 0,016M$
$pOH = -log(0,016) = 1,795 \Rightarrow pH = 14 - 1,795 = 12,205$
Sửa đề H2SO2 thành H2SO4
\(n_{Ba^{2+}}=n_{Ba\left(OH\right)2}=0,01.0,1=0,001\left(mol\right)\)
\(\Rightarrow n_{OH^-}=2n_{Ba\left(OH\right)2}=2.0,001=0,002\left(mol\right)\)
\(n_{SO_4^{2-}}=n_{H2SO4}=0,1.0,05=0,005\left(mol\right)\)
\(\Rightarrow n_{H^+}=2n_{H2SO4}=2.0,005=0,01\left(mol\right)\)
\(Ba^{2+}+SO_4^{2-}\rightarrow BaSO_4\)
0,001 0,01 0,01
Xét tỉ lệ : \(0,001< 0,01\Rightarrow SO_4^{2-}dư\)
\(n_{Ba^{2+}\left(pư\right)}=n_{BaSO4}=0,001\left(mol\right)\Rightarrow m_{BaSO4}=0,001.233=0,233\left(g\right)\)
\(H^++OH^-\rightarrow H_2O\)
0,01 0,002
Xét tỉ lệ : \(0,01>0,002\Rightarrow H^+dư\)
\(n_{H^+dư}=0,01-0,002=0,008\left(mol\right)\Rightarrow\left[H^+\right]=\dfrac{0,008}{0,1+0,1}=0,04M\)
\(\Rightarrow pH=-log\left(0,04\right)\approx1,4\)