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a) \(n_{Mg}=\dfrac{7,2}{24}=0,3\left(mol\right)\)
PTHH: Mg + 2HCl --> MgCl2 + H2
0,3--------------->0,3--->0,3
=> \(m_{MgCl_2}=0,3.95=28,5\left(g\right)\)
b)
\(V_{H_2}=0,3.22,4=6,72\left(l\right)\)
c)
\(n_{CuO}=\dfrac{32}{80}=0,4\left(mol\right)\)
PTHH: CuO + H2 --to--> Cu + H2O
Xét tỉ lệ: \(\dfrac{0,4}{1}>\dfrac{0,3}{1}\) => CuO dư, H2 hết
PTHH: CuO + H2 --to--> Cu + H2O
0,3<--0,3------->0,3
=> mchất rắn = 32 - 0,3.80 + 0,3.64 = 27,2 (g)
\(n_{Mg}=\dfrac{7,2}{24}=0,3\left(mol\right)\\
pthh:Mg+2HCl\rightarrow MgCl_2+H_2\)
0,3 0,3 0,3
\(m_{MgCl_2}=0,3.95=28,5g\\
V_{H_2}=0,3.22,4=6,72l\\
n_{CuO}=\dfrac{3}{80}=0,0375\left(mol\right)\\
pthh:CuO+H_2\underrightarrow{t^o}Cu+H_2O\\
LTL:\dfrac{0,0375}{1}>\dfrac{0,3}{1}\)
=>Hidro dư
\(n_{Cu}=n_{CuO}=0,0375\left(mol\right)\\
m_{Cu}=0,0375.64=2,4\left(g\right)\)
\(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\\
pthh:Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,1 0,2 0,1 0,1
\(m_{HCl}=0,2.36,5=7,3\left(g\right)\\
V_{H_2}=0,1.22,4=2,24l\\
m_{\text{dd}}=6,5+200-\left(0,1.2\right)=206,3g\)
bài 2 :
\(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\\
pthh:Mg+2HCl\rightarrow MgCl_2+H_2\)
0,2 0,4 0,2 0,2
\(m_{HCl}=0,4.36,5=14,6g\\
V_{H_2}=0,2.22,4=4,48l\\
m\text{dd}=4,8+200-0,4=204,4g\\
C\%=\dfrac{0,2.136}{204,4}.100\%=13,3\%\)
a. \(n_{Zn}=\dfrac{19.5}{65}=0,3\left(mol\right)\)
\(n_{HCl}=\dfrac{14.6}{36.5}=0,4\left(mol\right)\)
PTHH : Zn + 2HCl -> ZnCl2 + H2
0,4 0,2 0,2
Ta thấy : \(\dfrac{0.3}{1}>\dfrac{0.4}{2}\) => Zn dư , HCl đủ
b. \(V_{H_2}=0,2.22,4=4,48\left(l\right)\)
c. \(m_{ZnCl_2}=0,2.136=27,2\left(g\right)\)
a) Zn + 2HCl --> ZnCl2 + H2 ↑ (1)
0,3 -->0,15 -->0,15 (mol)
nZn= 19,5/65 = 0,3 mol
nHCl= 14,5/37,5 = 0,3 mol
Ta có : nZn bài ra / nZn phương trình=0,3/1=0,3 (mol)
nHCl bài ra / nHCl phương trình=0,3/2=0,15 (mol)
=> HCl đủ,Zn dư
b) Theo PT(1) => nH2=0,15(mol)
=>VH2=0,15 x 22,4 = 3,36(l)
c) Theo PT(1) => nZnCl2=0,15(mol)
=>mZnCl2=0,15 x 136 = 20,4(g)
\(a,Zn+2HCl\rightarrow ZnCl_2+H_2\\ n_{ZnCl_2}=n_{H_2}=n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\\ b,m_{ZnCl_2}=136.0,1=13,6\left(g\right);V_{H_2\left(đktc\right)}=0,1.22,4=2,24\left(l\right)\\ c,Vì:\dfrac{0,1}{1}>\dfrac{0,2}{1}\Rightarrow n_{Zn\left(TT\right)}=0,1\left(mol\right);n_{Zn\left(LT\right)}=n_{ZnCl_2}=0,2\left(mol\right)\\ H=\dfrac{0,1}{0,2}.100\%=50\%\)
\(n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\\ pthh:2Al+6HCl\rightarrow2AlCl_3+3H_2\)
Mol : 0,4 0,4 0,6
\(m_{AlCl_3}=133,5.0,4=53,4\left(g\right)\\ V_{H_2}=0,6.22,4=13,44\left(l\right)\)
\(n_{CuO}=\dfrac{8}{80}=0,8\left(mol\right)\\
pthh:CuO+H_2\underrightarrow{t^o}Cu+H_2O\\
LTL:\dfrac{0,8}{1}>\dfrac{0,6}{1}\)
=> CuO dư
\(n_{CuO\left(p\text{ư}\right)}=n_{Cu}=n_{H_2}=0,6\left(mol\right)\\
m_{CuO\left(d\right)}=\left(0,8-0,6\right).80=16\left(g\right)\\
m_{Cu}=0,6.64=38,4\left(g\right)\\
m_{cr}=16+38,4=54,4\left(g\right)\)
Câu 3:
c, Từ phần trên, có nH2 = nFe = 0,1 (mol)
\(n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\)
\(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
Xét tỉ lệ: \(\dfrac{0,1}{1}>\dfrac{0,1}{3}\), ta được Fe2O3 dư.
Theo PT: \(n_{Fe}=\dfrac{2}{3}n_{H_2}=\dfrac{1}{15}\left(mol\right)\Rightarrow m_{Fe}=\dfrac{1}{15}.56=\dfrac{56}{15}\left(g\right)\)
a) \(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
PTHH: `Fe + 2HCl -> FeCl_2 + H_2`
0,1-->0,2----->0,1------>0,1
`=> m_{FeCl_2} = 0,1.127 = 12,7 (g)`
b) `V_{H_2} = 0,1.22,4 = 2,24 (l)`
c) `n_{Fe_2O_3} = (16)/(160) = 0,1 (mol)`
PTHH: \(Fe_2O_3+3H_2\xrightarrow[]{t^o}2Fe+3H_2O\)
Xét tỉ lệ: \(0,1>\dfrac{0,1}{3}\Rightarrow\) Fe2O3
Theo PT: \(n_{Fe}=\dfrac{2}{3}.n_{H_2}=\dfrac{1}{15}\left(mol\right)\)
\(\Rightarrow m_{Fe}=\dfrac{1}{15}.56=\dfrac{56}{15}\left(g\right)\)
\(n_{H_2}=\dfrac{4.48}{22.4}=0.2\left(mol\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(0.2.......0.4.......................0.2\)
\(m_{Zn}=0.2\cdot65=13\left(g\right)\)
\(C\%_{HCl}=\dfrac{0.4\cdot36.5}{200}\cdot100\%=7.3\%\)
\(n_{CuO}=\dfrac{24}{80}=0.3\left(mol\right)\)
\(CuO+H_2\underrightarrow{^{t^0}}Cu+H_2O\)
\(1..........1\)
\(0.3.........0.2\)
\(LTL:\dfrac{0.3}{1}>\dfrac{0.2}{1}\Rightarrow CuOdư\)
\(m_{CuO\left(dư\right)}=\left(0.3-0.2\right)\cdot64=6.4\left(g\right)\)
D
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