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Coi : B gồm : Fe ( x mol) , O ( y mol)
\(m_B=56x+16y=12\left(h\right)\left(1\right)\)
\(n_{SO_2}=\dfrac{3.36}{22.4}=0.15\left(mol\right)\)
Bảo toàn e :
\(3x=2y+0.15\cdot2\left(2\right)\)
\(\left(1\right),\left(2\right):x=0.18,y=0.12\)
\(m_{Fe}=0.18\cdot56=10.08\left(g\right)\)
Quy đổi hỗn hợp về Fe và O.
Giả sử: \(\left\{{}\begin{matrix}n_{Fe}=x\left(mol\right)\\n_O=y\left(mol\right)\end{matrix}\right.\)
⇒ 56x + 16y = 12 (1)
Ta có: \(n_{SO_2}=0,15\left(mol\right)\)
Theo ĐLBT mol e, có: 3x - 2y = 0,15.2 (2)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,18\left(mol\right)\\y=0,12\left(mol\right)\end{matrix}\right.\)
⇒ mFe = 0,18.56 = 10,08 (g)
Bạn tham khảo nhé!
a) \(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
PTHH: 2Al + 3H2SO4 --> Al2(SO4)3 + 3H2
0,1<----------------------------0,15
=> \(\%m_{Al}=\dfrac{0,1.27}{7,5}.100\%=36\%\)
\(\%m_{Cu}=100\%-36\%=64\%\)
b) \(n_{Cu}=\dfrac{7,5-0,1.27}{64}=0,075\left(mol\right)\)
PTHH: Cu + 2H2SO4 --> CuSO4 + SO2 + 2H2O
0,075------------------------>0,075
2Al + 6H2SO4 --> Al2(SO4)3 + 3SO2 + 6H2O
0,1----------------------------->0,15
=> VSO2 = (0,075 + 0,15).22,4 = 5,04 (l)
Gọi số mol Cu, Fe là a, b (mol)
=> 64a + 56b = 17,6 (1)
\(n_{SO_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)
PTHH: 2Fe + 6H2SO4 --> Fe2(SO4)3 + 3SO2 + 6H2O
b-------------------------------->1,5b
Cu + 2H2SO4 --> CuSO4 + SO2 + 2H2O
a--------------------------->a
=> a + 1,5b = 0,4 (2)
(1)(2) => a = 0,1 (mol); b = 0,2 (mol)
=> \(\left\{{}\begin{matrix}\%m_{Cu}=\dfrac{0,1.64}{17,6}.100\%=36,36\%\\\%m_{Fe}=\dfrac{0,2.56}{17,6}.100\%=63,64\%\end{matrix}\right.\)
a.b.
\(n_{Al}=\dfrac{4,05}{27}=0,15mol\)
\(2Al+6H_2SO_4\left(đ\right)\rightarrow\left(t^o\right)Al_2\left(SO_4\right)_3+3SO_2+6H_2O\)
0,15 0,225 ( mol )
\(V_{SO_2}=0,225.22,4=5,04l\)
c.
\(Ba\left(OH\right)_2+SO_2\rightarrow BaSO_3+H_2O\)
\(Ba\left(OH\right)_2+2SO_2\rightarrow Ba\left(HSO_3\right)_2\)
Gọi \(\left\{{}\begin{matrix}n_{BaSO_3}=x\\n_{Ba\left(HSO_3\right)_2}=y\end{matrix}\right.\)
\(\rightarrow\left\{{}\begin{matrix}217x+299y=38,7\\x+2y=0,225\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}x=0,075\\y=0,075\end{matrix}\right.\)
\(n_{Ba\left(OH\right)_2}=0,075+0,075=0,15mol\)
\(V_{Ba\left(OH\right)_2}=\dfrac{0,15}{1}=0,15l\)
a.b.
nAl=4,0527=0,15molnAl=4,0527=0,15mol
2Al+6H2SO4(đ)→(to)Al2(SO4)3+3SO2+6H2O2Al+6H2SO4(đ)→(to)Al2(SO4)3+3SO2+6H2O
0,15 0,225 ( mol )
VSO2=0,225.22,4=5,04lVSO2=0,225.22,4=5,04l
c.
Ba(OH)2+SO2→BaSO3+H2OBa(OH)2+SO2→BaSO3+H2O
Ba(OH)2+2SO2→Ba(HSO3)2Ba(OH)2+2SO2→Ba(HSO3)2
Gọi {nBaSO3=xnBa(HSO3)2=y{nBaSO3=xnBa(HSO3)2=y
→{217x+299y=38,7x+2y=0,225→{217x+299y=38,7x+2y=0,225 ⇔{x=0,075y=0,075⇔{x=0,075y=0,075
nBa(OH)2=0,075+0,075=0,15molnBa(OH)2=0,075+0,075=0,15mol
VBa(OH)2=0,151=0,15l
a) Gọi số mol Al, Zn là a, b (mol)
=> 27a + 65b = 11,9 (1)
\(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)
PTHH: 2Al + 3H2SO4 --> Al2(SO4)3 + 3H2
a----->1,5a----------------->1,5a
Zn + H2SO4 --> ZnSO4 + H2
b------>b------------------>b
=> 1,5a + b = 0,4 (2)
(1)(2) => a = 0,2 (mol); b = 0,1 (mol)
\(\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,2.27}{11,9}.100\%=45,378\%\\\%m_{Zn}=\dfrac{0,1.65}{11,9}.100\%=54,622\%\end{matrix}\right.\)
b) nH2SO4 = 1,5a + b = 0,4 (mol)
=> mH2SO4 = 0,4.98 = 39,2 (g)
=> \(C\%_{dd.H_2SO_4}=\dfrac{39,2}{150}.100\%=26,133\%\)
